Monthly Archives: April 2007

Chemical Plant Production Managers

I have known a few plant production managers at several facilities in my career and they seem to share particular attributes. No doubt they fall into a particular Myers-Briggs type.  I can say without a doubt that I am personally disqualified from such activity because I tend to be more of the absentminded professor type.   It takes a certain breed of cat to manage any kind of production facility.  Indeed, your average construction site superintendant is probably better suited to manage a chemical plant than is a chemist. 

Well, OK. That was a bit harsh.  Many chemists could do it if they had to. But if you owned a chemical company and were looking for a new plant manager, you’d probably find that the pool of candidates didn’t include many chemists. There, that is more polite.  Chemists are often tweakers by nature and a chemical plant is not a place for experiments. Plant managers live by the production schedule. They are both masters of and slaves to this schedule.  Their whole careers are about the coordination of material flows- the arrival of raw materials, processing, and the logistics of shipping.

A chemical plant is a big machine through which flows a large stream of money.  Money flows in one side of this machine and out the other side.  Jets of cash flow outward to payroll and raw material vendors. The production manager never forgets that the inflowing stream must always be bigger than the outflowing stream.  Customers insist on just-in-time delivery of products, but they also want 60 days net with a lot of other strings.  The relationship between the controller and the plant manager may be chronically strained.

People who run production plants are really engineers, irrespective of whether or not they hold a diploma in engineering.  Scientists find the thread between cause and effect.  Engineers take that thread and figure out how to use it for fun and profit. Sure, some scientists have engineering sense and some engineers have scientific sense.  But a plant manager is all about running the plant at full speed. When they make tweaks, it is usually on the engineering side.  Usually they are loath to alter chemistry.

In the Navy they have a saying- Fight the Ship.  Use every part of the boat to your advantage.  Slap ’em with the rudder if it comes to that.  A good production manager is crafty, thrifty, and when needed, a brutal task master.  He knows his crew and can and will push them to the edge when needed. 

A really smart plant manager will find and keep the best maintenance people he/she can find.  In fact, a savvy plant manager will always vote to throw a chemist overboard rather than let a maintenance person go.  One of the least acknowledged groups at a chemical plant is the maintenance crew.  To keep the plant up and running you need the skill sets of plumbers, welders, pipefitters, machinists, electricians, iron workers, carpenters, tinners, and a bunch of general handymen and gofers.  Usually you hire people with multiple skill sets.

The best plant managers are steely-eyed SOB’s who speak softly and command respect and maybe a little fear. A plant manager must be able to work effectively with arrogant executives, stubborn accountants, egghead scientists, angry admin staff, defensive production people, and sly construction contractors.  The people skills are as important as the technical skills.

If I were going to hire people for key management positions in a plant, I would hire people from the nuclear Navy. As a group, they have already been screened for many attributes useful to a chemical plant. They tend to be high achievers, have good quantitative skills, have been highly trained for work in hazardous environments, and they understand the importance of following protocol.

Wear the Fox Hat

Ever been to the Royal Burgh of Auchtermuchty? Neither have I.  It’s north of Edinburgh on the A91 on the way to St. Andrews, between the Firth of Forth and the Firth of Tay.  According to Undiscovered Scotland, the name comes from the Scottish Gaelic phrase uachdar muc garadh, meaning “upper pig enclosure”. 

Hey, I really dig Scotland. 

Here is a grab bag of surprise links.  X  Y  Z.  

Yet another mass shooting in our USA

The news of the mass shooting at Virginia Tech just seems to get worse as the day wears on.  There aren’t words to describe it. 

After the grisly scene in Blacksburg is cleaned up and the bodies are buried, we’ll once again switch on the TV and watch programming glamorizing gun-toting tough guys and violence. Not a night goes by on television where some plot isn’t based on the menacing of women by crazed or angry men, most with guns.  Some people will solve problems with guns and others will cause problems with guns.  The message is that guns bring satisfaction and command respect. Just look at the very title of the series The Sopranos and listen to the lyrics.  “Woke up this mornin’ and got myself a gun …”

Maybe there is no causal connection between entertainment and what this shooter did.  But I cannot help but believe that the more or less constant exposure to violence in our entertainment doesn’t dull our sensibilities and lower our threshold for what constitutes acceptable behaviour.  Regardless, we have to start somewhere and cleaning up our tastes in entertainment is relatively painless.  We need to create less demand for this crude stuff.

Obviously, the shooter is responsible for the murders, not the inanimate steel mechanism.  But the common fascination we have with the gun and it’s stylized, even mythical, application means that this mechanical device has some kind of hold on us.  Its ease of use and its ability to deliver death from a great distance makes it possible for anyone to deem themselves a “warrier” for a few minutes.

We are horrified by such violence when it is real. But we entertain ourselves with painstakingly elaborate dramatizations of it.  We are gratified to watch fictional characters engage in gunplay with bad guys.  We cheer as fictional cops rough up suspects because, as we all know, bad guys really shouldn’t have rights. 

There is no mysterious or complex phenomenon to sort out here. Our American culture has a form of fragmented personality disorder with respect to gun violence.  I don’t know if it’ll do a damned bit of good, but we need to come down from the saturation level of violence in our entertainment and recreation. The first thing we must do is to remove a bit of the glamor of gunplay. 

We don’t have to give up our guns.  But we do need to develop a new viewpoint or an advanced ethos about them. We need new icons and archetypes.  It is time to retire CSI and The Sopranos as popular iconography.  We must find better ways to fulfill our self image and need for power besides being handy with a gun.  How do other societies do it?  Any suggestions??

Here is an interesting link to a rebuttal in the Daily Kos written by someone said to be from VT.

GD vs ICP Mass Spec

I wonder if there are any mass spec jockeys out there who can comment on the relative accuracy of Glow Discharge Mass Spec (GDMS) with ICP Mass Spec (ICPMS)  at the ppm level?  In other words, if one has data taken from each and compares them side by side, which should one side with? I have results from both analyses on a metal oxide and I’m puzzled as to which I should stand behind. 

If you have one clock, you know what time it is. If you have two, you’re never sure.

One lab breathlessly proclaims that GDMS is linear over 9 orders of magnitude, but is subject to 20 to 30 % error owing to a lack of a valid standard (??!@#?). The same fellow says that ICPMS is accurate to 5 % at 100 ppm, but the error is considerably higher at 1 ppm. Good gravy.

No doubt, the answer will contain the words “it depends”.  But I wonder what the issues are. 

Plasma Songs From Space

The radio telescope project has begun. Today I ordered a 20 MHz receiver from Radio Jove.  While we wait for that to arrive we have to source an 8 channel Analog to Digital Converter (ADC) for the data feed into RadioSky-Pipe.  RadioSky has run out of ADC’s, but they recommend Kitsrus out of Hawii.  

We have three surplus computers I bought from work.  Have to pick one and get an operating system (Windows 2000, probably, though Linux is a possibility), a monitor, and a keyboard. 

The biggest issue is the recommended dipole antenna. The kit specifies an East/West 23′ 3″ ft dipole with a 32 ft footprint, is ca 10 ft high, and uses guy wires to stabilize it. Sounds like a trip hazard and a target for vandalism to me.  In that vein, I have been looking at alternative antenna configurations. The folks at Radio Jove are reticent to recommend one, presumably because it is a step away from simplicity for classroom use.  That’s fine. I’m an experimentalist.

One problem with moving away from the dipole antenna design is the unwieldy half-wavelength dimensions. While the dipole eats up real estate, it is structurally simple.  One interesting design is the Moxon antenna.  This antenna uses a bent driven element with a bent reflector element.  Most people use it with the elements in the horizontal plane, thus picking up horizontally polarized signals.  While this makes sense for communications, I’m guessing that the 20 MHz signals from the sun and Jupiter are probably not significantly polarized.  

The Moxon is significantly more directional than a dipole with a front to back ratio 15 to 20 db.  This means that it must be pointed at the radio source for maximum gain.  But its directionality also confers some rejection of terrestrial signals from other directions. From what I can tell, the gain from this design with its reflector element is on the order of 5 db.  This is higher than a dipole but lower than a multi-element Yagi.

We’ll get some baseline experience with the recommended antenna and then begin to look at other configurations.

In my view, one can never know too much about electronics.  This site has some interesting circuit animations.  Cheers!

The Zen of Hazardous Materials

My first experience with truly hazardous materials was in 1981.  It was a sophomore organic lab and we were making sulfanilamide.  Using chlorosulfonic acid, we attached a ClSO2 group in the para position of acetanilide.  Pedagogically, it was a very rich experience because it validated the idea of O,P-directors, protecting groups, medicinal chemistry, and offered real experience in the handling of hazardous materials.  And, at least as corrosive materials go, they don’t get much more obnoxious than chlorosulfonic acid.

The preparation of sulfanilamide was an excellent lab experience because it brought home some fundamental truths about nature.  Namely, that physical and chemical properties of matter can be “tuned” and tweaked by people to give a desired outcome.  For students, this lab experience connects the inorganic, inanimate world of the periodic table to something closer and more personal.  It gets to the very nanomachinery of life itself.  It is a glimse of how drugs work. It gets right to the pointy end of the stick- Drugs are about selective toxicity. 

Once you have taken the time to gain some understanding of how drugs work at the molecular level, you are forever changed.  One begins to realize that biochemical “mistakes” can happen naturally and are part of the game.  Suddenly, the world is full of rogue “isosteres” and “pharmacophores“.  You can no longer accept blithe generalizations about toxicity and chemical hazards.  There is truth in the First Law of Toxicology- Dose makes the poison.  Your working definition of toxicity takes on new forms, like the notion of endocrine disrupters

As time goes on and my view of the natural world becomes increasingly molecular in scope, I find that my working definition of what constitutes “hazardous” has skewed a bit as well. Hazardous does not automatically equal “bad”. The modern material world is now a swirl of substances synthetic and substances natural.  Industry has given us dioxin and nature has given us aflatoxin.  But at worst nature is indifferent; human activity can be negligent or even malevolent. 

A mature view of hazardous materials must simultaneously accomodate physical/chemical reality with certain norms of conduct, with prompt and delayed biological effects of hazardous materials, and with consequences to the biosphere.  In truth, modern society must use hazardous materials to produce goods and services vital for healthy living.  But we chemists must find ways to limit the number of moles of hazardous waste we generate. Especially the persistant substances- metal salts, halogenated hydrocarbons, etc.

Synthetic chemistry relies on reactive materials in order to do bond making and bond breaking.  There really is no getting around the need for reactive materials. But we can find ways to generate reactive materials in situ.  Reactive intermediates are generated in a catalytic cycle and used on the spot.  More pervasive use of catalysis could be a contributor to lower generation of haz waste or a greener chemistry.  This is just a corollary to Trost’s Atom Efficiency concept.

Hazardous materials have a utility that is similar to a knife.  A knife is a tool that does a very useful thing- it cuts. Every single time you pick it up you have to be wary of the edge and the point.  It is a persistant hazard.  But we continue to use it because of it’s utility.  In a way, chemicals are the just like that.

Professors and Their Patents

I had the occasion to have a conversation with a very prominent chemistry professor this week.  He has many hundreds of publications and many, many patents.  The fellow’s name would be familiar to many.  As such characters tend to be, he was overflowing with ideas and enthusiasm. His energy was evident from the precocious stream of insights and commentary that flowed from his gurgling fountain of knowledge.  

But something he said in passing caught my attention and for a moment halted my petit mal seizures resulting from overexposure to his relentless rhapsody of intellection and hypercogency.  He chimed that not so long ago his University had been passively collecting a stack of patents generated by its faculty. They had been in no particular hurry to do anything with the IP and had only recently started to take an interest in it. He made a furtive attempt to strike a spark of interest in his patents and when met with silence, quickly retracted it back into its sheath.

In my travels I have encountered professors who have made faint reference to their patents, say, during a poster session, in the manner of weary gentry casually mentioning an obscure parcel of prairie in Oklahoma.  Interesting, but yesterday’s news.  Sort of a publication, but … not really. Not all profs have such a casual view of patents, however. 

<<<<<< A snarky sentence was removed>>>>>>> …  Apparently he was patenting most everything that spewed from his labs.  Every permutation- methyl, ethyl, butyl, … futyl- was carefully covered by complex Markush claims so as to anticipate even the most clever work-around.  It makes one wonder how such research groups are properly managed. Do you have an IP group and a public domain group? Should people doing the IP work be paid more?

What raises my hackles about university patents is this: As a result of the Bayh-Dole act, universities can be assigned patents to inventions that were funded by federal tax money.  Superficially, it sounds like a decent idea.  It sounds like it might facilitate technology transfer. What’s wrong with that?

Well, let’s see.  A patent confers 20 year monopoly rights to the assignee (rarely the inventor) for a process and/or composition of matter.  One obtains a patent in order to enjoy protection from infringement, or unauthorized use. In the case of a university, just who do they need protection from?? The public who paid for the research leading to the invention? 

What kind of public policy is this?  Public monies are disbursed competitively in the form of research grants which funds the research.  The public pays for the bricks and mortar to keep the wind and rain off that new 600 MHz NMR in the new wing and for the journal subscriptions in the library.  The public has to pay for the patent prosecution and the trips to ACS meetings to give a talk about the work (though rarely is there a mention that a patent is pending).

The public has to pay Chemical Abstracts Service for access to bibliographic information and copy fees or journal subscriptions or download fees to access the information.  For a business to use the invention, a license agreement has to be negotiated and in all likelihood, will have to pay a fee upfront, well in advance of the first dollar of sales, and submit to annual audits.  With any given patent, the University Tech Transfer Office may have already issued an exclusive license to someone else. In that case, tough luck.

Granted, some of the more IP savvy schools reap decent royalties from some fraction of their patents, i.e., MIT & CalTech.  But I would say that they are in the minority. Most patents just consume money, not generate it.  These unexploited patents merely serve as a barrier to the public who are trying to get product to market.  It is quite easy for a chemist to reinvent a compound or process that has been claimed by someone else already.  It is bad enough when it is your competition. It really stings when you are barred from practicing art that you unwittingly helped to pay for.

Let me sponge up the bile and make room for others to comment. What do you think about this issue?  I’m probably just full of hot air.

Note: This is a revised post, with minor content editing. 

Chemists and Chemical Engineers

What an awkard pair, these chemists and chemical engineers.  To strangers from a distance they might appear almost interchangeable.  Someone from another field might assume that the differences could be as inconsequential as minor variations in accent or hair style are between neighbors.  A simple matter of preference for the practical or the arcane. But that someone would be wrong.

Chemists and Chem E’s are really quite different by training and by disposition.  We chemists think of our field as resting upon the three pillars- Theory, Synthesis, and Analysis.  Chem E’s will agree, but they’ll point out that there is a 4th pillar- Economics. 

Here is an act of convulsive reductionism:  Atomic and Molecular Chemistry (as opposed to Nuclear Chemistry), the science we normally think of when we use the word “Chemistry”, really concerns itself with the behavior of electrons near positive point charges. When we cause a chemical change we are perturbing the disposition of electrons somewhere. In doing so, ensembles of nuclei and their electrons connect, disconnect, or otherwise alter the disposition of the electrons.  Chemists make and break bonds, transfer electrons, or promote electrons to particular energy states.  This work is limited to the outermost layers of the onion. We rarely ever have to consider the inner layers of electrons and we never monkey with the nucleus.

Chemistry is very much an electronic activity. It is the realm of electronic quantum mechanical formalism and machinations at the Angstrom scale. Virtually every chemical change we do involves the twiddling of electrons somewhere.

Chem E’s, on the other hand, practice applied classical physical chemistry.  Unlike organikkers such as myself, they took a serious fancy to P-chem. Their quantum unit is the dollar. These folks can actually put thermo to use for fun and profit. They understand the sacred and profane applications of the gas laws. Chem E’s can specify what sort of pump you need to move whatever variety of hellbroth you care to convey and they can probably estimate the Reynolds number of the rainwater running off your nose.  A Chem E can tell you what kind of materials of construction and seals you need to reflux thionyl chloride in your reactor and what kind of chiller capacity you need to condense it. 

And as engineers, they can plan a construction schedule, work up a cost estimate, and supervise the construction of whatever kind of process equipment you care to specify from the dirt up.  A chemist could probably do it as well, but it would look like a chemist did it.  I have personal experience here.

You probably wouldn’t ask a Chem E to synthesize vitamin B-12.  But they wouldn’t ask a chemist to design a continuous fractional distillation column either.

Assorted Links

This Wine Enthusiast link offers a small distillation unit for distilling the volatiles from wine or beer.  Your next shot of brandy is only minutes away.  Of course, the distillate may be flammable, so I’d be careful with that burner.

Check out the Museum of Lost Wonder. Pretty wild.  Then, there is the day that they foamed the fountain of the Kazan Cathedral in St. Petersburg, Russia.  If you’re keen on learning the top 10 prejudices Germans have about the USA, check out this blog.  Hard to argue with it’s accuracy.  Had a nagging urge to hop in a submarine and go for a dive?  Check out U-Boat Worx. The specs say that it is limited to 50 meters depth.  I wonder what the crush depth is- 150 meters? I’d imagine that the seals would fail first and the thing would flood before it imploded.

Chemical Blogometrics

I see that according to Chemical Blogspace, my Gunning-Fog index has gone up a notch- from Al Gore to Thomas Pynchon.  Oh, good gawd.  Now I have to worry about that as well…?

Forty thousand years ago all you had to worry about was a sabre tooth tiger dropping out of a tree on you, or those nasty Neanderthals up the river raiding your camp, killing your women and raping the men. Today we have secretive organizations applying these odd metrics from the dark recesses of the blogosphere. Who are these people? And, what do they want? 

Actually, what they are doing is quite interesting. It provides good feedback for bloggers. Once we wipe away the tears we can improve our “product”.

All this talk coming from a guy who writes under a pseudonym \;-)