Author Archives: gaussling

About gaussling

Gaussling is a senior scientist in the chemical business. He occasionally breaks glassware, spreads confusion and has been known to generate new forms of hazardous waste. Gaussling also digs aerospace, geology, and community theatre.

Chemical Art in the Public Domain

For the last few years I have been attempting to work with a full professor of chemistry who holds a named chair. He is fast approaching emeritus status and in addition to the other maladies of aging, he tends toward spontaneously bureaucratic demands and is rather hard of listening. His secretary types his correspondence which is written in the officious, pseudo-legalese tone remniscent of a 19th century divorce decree.

Recently, while discussing chemistry with the “judge” by email, I suggested that he look at the patent literature for clues to synthetic procedure. Procedures found in patents may have a general utility and are not automatically claimed. Minimally, a dip in the patent literature broadens ones knowledge of the prior art. Certainly, art found in expired patents has a high likelihood of being up for grabs.

My clumsy and sophomoric attempt at helpfulness sparked a multiparagraph recitation in reply on the anticipatory nature of content in patents and how “such material” is unacceptable for “we in academe”.

Suit yourself, says I. But like any prospector knows, gold is where you find it. And this brings me to a point.

Every week some number of US patents expire or lapse. This continuous stream of expiration represents a situation much like the periodic deposit of placer gold after the spring runoff.  Gold veins in the walls of the canyon spall and fracture allowing gold nuggets and dust to tumble into the creek.  Prospectors who know what to look for can pick up the occasional nugget of art that has fallen into the public domain.

Granted, expired art may be 17 years out of date, but many kinds of compositions and transformations in chemistry are not subject to the expiration of utility. Many kinds of oxidations, reductions, alkylations, halogenations, functional group transformations, etc., remain quite useful over time. What changes over time are the economic and regulatory compliance issues. It is possible to make C-C bonds without a platinum group metal, triflate, and boron.

The value of expired patent art is well known by the pharmaceutical industry. Pharma companies will fight like wounded bears to get extra days added to their patents or otherwise attempt to extend claimed art as far into the future as possible with formulation or other schemes. They know that the day after a cash cow drug goes off patent, there will be generic versions on sale by opportunistic producers.

Prior to June 8, 1995, utility and plant patents were allowed for a period of 17 years with the 17 year clock starting from the application date and the period of enforceability beginning on the issuance date. From June 8, 1995 onward, utility and plant patents are valid for 20 years.

It is in the nature of scientifically minded folk to be forward looking and lavish extra attention on the latest techniques.  In our enthusiasm for the new and exciting, we may forget the vast storehouse of knowledge accumulated over the last 100 years of chemical research.

There is an ever increasing store of public domain art at the patent office waiting to be extracted by those who have the interest to do so. If you do decide to adopt some expired art, it is worth paying attorneys fees to make sure your judgement is sound and to look for related patents that may be problematic. Due diligence is money well spent.

It is true that patents are written by lawyers with little interest in providing too much enablement to the public. But these lawyers also know that playing games with enablement is contrary to the intent of the sworn statements in the application and may ultimately weaken a patent during litigation. A patent isn’t a peer reviewed paper. But, to Phosita, it can be a rich source of clues on how to perform some particular expired art that may serve as the basis of a product or process.

Pushing Tin

While browsing MetaFilter I ran into a really nice Air Traffic Control simulator called ATC-SIM. This is a web-based simulator that requires no download to use. It captures the basics of ATC work. The amateur controller must maintain 3 mile horizontal and 1000 ft vertical separation at all times as well as coordinate the timely arrival and departure of aircraft thorugh the terminal airspace.  The controller must coordinate inbound traffic onto an intercept of the ILS glideslope beacon for the active runway in order for the landing clearance to result in a landing.

The default airport is O’Hare. It doesn’t take long to get a glimpse of the challenges associated with that airspace.  Traffic piles in and out rapidly and every aircraft is in motion.

Another ATC related website is ATC Monitor. This is apparently a feed from Atlanta. It is possible to view Atlanta Center radar as well as TRACON.  It is well worth visiting.

Th’ Gaussling’s home town is ~ 8,000 ft beneath an airway leading to Denver Int’l Airport. While driving home at night I frequently see bright cones of airliner landing lights stabbing through the clouds aloft. These light projections have a faintly cometary appearance.

More than the Earth Stood Still

Having sat through the remake of the classic SciFi movie The Day the Earth Stood Still, I am compelled to set up a warning beacon for those who have yet to see this movie.

Here is the warning- While it may be worth seeing on a big screen, it is definitely not worth the full price of admission. If your local cineplex offers discount tickets for afternoon shows, take the opportunity to see it then. Also, be sure to sneak in as many concession snacks as possible. You want to keep your financial investment in this movie to a bare minimum.

First, a few words about Keanu Reeves. Much like John Wayne, Reeves seems to have a single character that he portrays in every film. In this movie, it’s “Reeves plays Klaatu”.  I will say that Reeves portrayal of Klaatu is fine- his trademark deadpan delivery works well for the part. 

Jennifer Connelly plays Dr. Helen Benson, an astrobiologist who is swept into action by mysterious people with Chinook helicopters. Her part is poorly written and suffers from excessive cliche. Character development is weak as is emotional buy-in. 

Stepchild  Jacob Benson, played by Jaden Smith, is an impish, totally gratuitous angry stepchild trapped in a love-less domestic truce with stepmom Connelly. Smith’s part was poorly written and directed as well. There is little or no opportunity to emotionally connect with his character.

The blackboard scene with John Cleese was conducted like a checkers match rather than a brainstorming session. It was lifeless and unconvincing.  This is one of the few serious roles played by Cleese and I believe it is a step down from Basil Fawlty.

Emotional connection is the lost key to this movie. It is actually part of the plot construction. The movie demands the viewer to accept that Connelly and Smith emotionally connect with Klaatu, but the direction and writing of the movie fails to bridge that gap convincingly or even connect the viewer to the characters.

This movie is written like a class project in preparation for midterm exams in a Cinema 205 course. Cliche parts and story telling devices were taken off the shelf and snapped together.  While I will give a passing grade on cinematography and effects, it is a sophomoric exercise in movie writing.

Infrastructure

I often feel badly for people who join large organizations. They miss out on so much excitement.  The benefits of joining large organizations are many, so why question doing it? What is wrong with driving up to a large campus-like facility every day and pass through security with your card to your quiet work area?  Nothing, really.

Yes, there is infrastructure and funding to provide support for business activity. Yes, there is prestige in professional association with certain large organizations. And, yes, you do get to be involved with large scale projects.

But unless you participate in forming a new business division at your MegaCorp, you’ll miss the chance to construct infrastructure from scratch.  I don’t mean bricks and mortar.  I refer to the actual standard operating procedures, work instructions, job descriptions, accounting procedures, customer lists, databases, and other fundamental structure relating to the conduct of business.

It is messy, contentious, confusing, and exhausting. It happens in successive approximations. Careers can be spent trying to get an organization moving in the best direction.You’ll make lifelong friends and enemies. You will see both the best and the worst in people bloom before your eyes.

Not everyone likes to do this. In fact, you might even say that very few people are willing to do it. If you are a chemist, you probably prefer to do chemistry rather than monkey with chemical business structure. That’s fine.

Having participated in this kind of work, and, speaking only for myself, I must say that I have a better appreciation for the accomplishments of others. To a large extent, civilization is about the establishment of infrastructure in its many forms. Business isn’t “just business”, it is part of civilization. While few of us will be able to help construct a granite monument or edifice, we can more readily participate in the conduct of our institutions.

Nernstian Sunrise in the Cryosphere

WAWAwawa ..wawa..wawawa..waawaa..waaawaaa..wa..wa……wa……….wa.

The thermometer read -20 F this morning. It hasn’t been that cold for a few years.  As I sat in the Jeep listening to my battery die hard, my mind wandered fondly to the green meadows of P-Chem and the Nernst equation. This equation sets forth the relationship between temperature and cell potential.  The University of Arizona has this fantastic Nernst simulator (web version) that lets you dial in temperature and immediately see the effect on the voltage of the electrochemical cell.  It is plain to see that as the temperature drops, the EMF drops as well.

Knowing that nature wouldn’t let me summon sufficient wattage from my battery, I went back inside and switched on CNN.  After seeing multiple replays of an indignant journalist hurling a pair of shoes at our president, I was treated to an ad by the Central Intelligence Agency- the CIA. Yeah, the CIA is advertising on CNN!  Take a minute to get your arms around that.

Strangely, uncharacteristically perhaps, I experienced a synergistic swelling of sympathy after seeing the shots of Bush II being assaulted by Iraqi footwear followed by the patriotic CIA ad. For a moment- just a sparkle in time- a quorum of voices in my head agreed that somebody should kick that journalist’s ass. Bush II may be a buffoon, but he is OUR buffoon and nobody should treat him like that. There- I said it.

Halliburton to Take Over Management of NASA

December 12, 2008.  In an unexpected move the Bush administration has transferred management responsibility for NASA’s Constellation Project to Halliburton.  The no-bid contract was announced 10 pm Friday evening. Reportedly, Halliburton will also take over day to day management of NASA activities.

Halliburton will take immediate responsibility for project management of the new manned launch vehicle system and, eventually, lunar missions planned for the end of the next decade.

Major General (ret.) Garman Schlumpet, President of Halliburton Drilling and Space Services, declined to give details of the new arrangement, but did remark that he “looks forward to working with Mr. Cheney again” on the upcoming lunar mission.

Halliburton is expected to subcontract significant portions of project management to Blackwater Space Systems (BSS) based in Terlott, NC. Recently, the privately held BSS has denied having an ongoing development program in play to develop payload delivery systems for orbital and suborbital applications. 

However, a recently discovered shipping manifest disclosing large quantities of ammonium perchlorate being shipped into the remote North Carolina headquarters has been reported by the Mount Pilot Recorder.  A coalition of adjacent coal mine operators  claim they will file an injunction to halt the “private space program” from contaminating  their pristine mountain valley.

Reportedly, BSS is offering turnkey underground launch facilities as well as launch facility services from their  privately held volcanic island in the Caribbean Mauvaise Odeur Island chain.

Kar Tsar? Car Czar?

A Car Czar?  What?  Are they kidding? Pfffttt!! Industry people barely know how to run the car business. How is a civil servant or political appointee going to direct a bunch of cocky rust belt stiffs in pinstripe suits to drive us into a clean and happy motorized future? Is this a joke? HEY!!  Who’s idea is this?

The big three automotive companies need a blood purge. The executives who lead these venerable organizations onto this jeep trail to perdition need to have their heads skewered on a row of pikes planted outside corporate HQ for all to see. There must be a big show of public firings and some tearful, sobbing contrition by the survivors. People who become automobile executives captains of industry should be terrified every day they show up to work, fearing for their careers. If you get too relaxed, You’re Out!  Damn’d skippy.

Aqueous Enceladus

With the revelation that streams of water ejected from the Saturnian moon Enceladus may arise from subsurface liquid water, the space science crowd is abuzz with excitement about the possibility of life on this frosted novelty moon. It seems to me that if there is aqueous life under the surface of Enceladus, then some of it should have been blown ejected above the surface by these geysers. In fact, a few of the hapless critters may be lying about on the surface this very moment wearing an expression of shock and dismay on their frozen xenomorphic faces. How embarrassing for them.

The three cosmic damp spots- Earth, Europa, and Enceladus. I wonder how long it will take for a lander proposal to get serious evaluation? Life on Enceladus is as likely to resemble a microbial mat as anything.  A lander would have to consider microscopic examination of samples.