Author Archives: gaussling

About gaussling

Gaussling is a senior scientist in the chemical business. He occasionally breaks glassware, spreads confusion and has been known to generate new forms of hazardous waste. Gaussling also digs aerospace, geology, and community theatre.

Lamentations on Dribbling Coffee Pots

Here we are 25 years into the 21st century already. One might have supposed that by four hundred years beyond the start of the Enlightenment, someone might have devised a coffee pot that does not dribble. Some pots approach this asymptote, however, but not ours. For myself the bigger problem shows up when I pour water into the reservoir of the coffee maker.

After considerable experimentation I have observed that dribbling will happen when the flow rate is either too slow or too fast. The problem for the coffee pot user is that while a dribble-free flow is occurring, the liquid level and flow rate drop and the water begins to dribble again. The angle of the pot can be raised to increase the water flow rate, but it is very easy overcompensate and slip onto the dribbling flow regime once more. So, filling the coffee maker can turn into a series of back and forth corrections trying to keep the water flow in the “sweet spot.”

As the flow rate rises the liquid flow begins to crawl up along the sides where there is no spout, thus adding to the dribbling. Too slow (lacking momentum) and capillarity pulls the stream around the curve of the spout causing it to run down the sides of the pot.

Applying beeswax to the spout of a dribbly coffee pot. Source: Instructables.

A cure for this can be found on the Instructables website. The author of this article found 2 possible causes- a mold seam in the plastic spout and capillary action of water. The author reports that after carefully filing down the ridge of the plastic molding seam and coating the spout with a light layer of beeswax, the problem has disappeared.

Every time I make coffee at work, I check my pockets only to find that I left my beeswax at home. I have a hoard of beeswax for use in the event of the apocalypse. After all of the “goody-two-shoes” have been raptured, those of us ground-pounding leftovers on earth will need candle wax.

It turns out that this pouring issue has been fixed at the commercial level for some time. I have seen plastic lips around the opening of syrup bottles that are actually dribble-free. In the laboratory I found plastic rings that fit on the opening of numerous chemical jugs. Off-hand I have seen this on 4 L jugs of concentrated nitric, sulfuric, chlorosulfonic and triflic acids. Dribbles of these acids are especially problematic. The purpose was obvious on inspection- make the spout hydrophobic to suppress capillary action attracting the liquid to follow the surface. Evidently, I failed to remember this trick.

The spout on our Cuisinart coffee maker is plastic, as is the spout in the Instructables article, so you’d think that in itself would prevent the dribbling due to its hydrophobicity. But apparently it is appreciably wetted by water. The dielectric constant of the beeswax then must be lower than the plastic, making the beeswax surface energy lower, thus the attractive forces lower.

Ok. I’m done with this.

Call for Papers for the 2025 Conference on Pelagic Rag Layers of the Prebiotic Era

Poltroon University, Guapo, Arizona, Department of Chemical Numerology. Saturday, August 23, 2025.

On-campus single accommodations available in Convent dorms: Contact Biff Stephens, biffbiff@poltroon.org. Parking permit required, $41.00 per day. Contact Harry Bisby, harryharry@poltroon.org. Airport shuttle available.

8:00 AM Plenary Session: The William ‘Billy’ Ghote Pavilion, Suess Lecture Hall A0001.6B, Coffee & Cookies, Fermented Beverages.

9:15 AM – 5:00 PM Poster Session: Suess Lecture Hall A0001.6C. Fermented beverages.

Plenary speaker: Rufus “Keto” McGumbo PhD, Visiting Scholar, The Northern Starkrakk Institute, Goblin City, Lapland. Rag Layers for the 21st Century and Beyond.

Afternoon Session, 1:00 PM, Suess Lecture Hall A0001B, Coffee & Cookies, Fermented Beverages.

Session Topic: Flotsam, Jetsam and Pelagic Rag Layers. Did Life begin in a Terrestrial Rag Layer?

5:30 PM Dinner at the Desert Waffle House, 63546 Cupric Avenue, Guapo. Electric scooters available.

7:00 PM Dessert, Gin & Tonic, Suess Lecture Hall A0001.6G

7:30 PM Evening Session, Suess Lecture Hall A0001B, Topic: Pelagic Rag Layers: Latest Research. Open bar.

After party, Gentlemen’s Club, $20 bills suggested for tips.

End

[Some Actual Truth: After writing this I learned that rag layers have actually been the subject of considerable research. Fancy that.]

Russia, WTF??

Getting credible news and commentary from Ukraine can be problematic. I’ve been receiving a newsletter from Ukraine called Kyiv Independent. I also view a Polish Public Television program found on YouTube, Telewizja Polska S.A.(PVT), that has up-to-date military news coverage and action video from the anti-Russian perspective, of course. Poland has a much better understanding of Russia than most of us in the West. During WWII, Poland was savagely occupied first by the Nazis only to be liberated and savaged by Stalin’s brutal Red Army.

Another seemingly straight news and opinion source is called “Inside Russia“. This is found on YouTube and is updated at least weekly. The host evacuated Russia around the time of the invasion of Ukraine and broadcasts his channel from abroad. He speaks excellent English and went to college studying economics in the USA. He combs through news and events in Russia and gives context and interpretation. He seems quite credible.

Usually, TVP military content is dripping with the irony around Russia’s once-feared conventional military collapsing in on itself. Poland has everything to fear from Putin’s imperialism so they are following the Putin-Ukraine war closely. So are the Baltic states and perhaps a few former Soviet states to the south as well.

Much of Putin’s propaganda is anchored in allegations of Western buggery and provocations, spying or otherwise contamination of Russian sovereignty by Western culture which they see as morally corrupt. The former USSR and present-day North Korea built their nations on the fear of America and NATO preparing to invade. The illegal annexing of territory, theft of money and denial of basic human rights is more easily justified if the threat of 10 ft tall foreign soldiers is predicted.

I am unaware of any previous or future attempts by the West to invade Russian territory for any reason. What in the hell would you do with it if you won? Ok, they have minerals and lots of timber which are valuable. Still, the country is crawling with Russian citizens who are, by the way, just as smart as we are and would be highly motivated for self-defense just like the Ukrainians have been. There is no future in a Russia-vs-West major war. The threat of it, however, has value to people like Putin as it did in the bygone days of the USSR.

Putin has done a bit of nuclear saber rattling since his invasion of Ukraine but Western states know that cooler heads in the Kremlin are aware of the consequences of releasing a nuclear war shot even as a demonstration. Everyone knows about Mutual Assured Destruction (MAD) but a few on either side have always doubted MAD. Obviously, the ominous warnings of “nuclear weapons” were meant to frighten the citizens of the EU and USA with the hope of weakening anti-Russian sentiment abroad.

In the West we can ask the questions “Why is Russia so paranoid all of the time?” “Why is authoritarian rule so prevalent in Russian history?” Putin has publicly stated that the West wants what they have and he is determined to keep western invaders out. Well, yes this is true as far as market access. Many businesses around the world would love oil & gas or other concessions like Platinum Group Metals (PGMs) or titanium. Russia’s internal markets are underserved and represent opportunities for both Russian citizens and international trade.

I sense there is a fear in Russia that if another country uses Russian raw materials to make a profit elsewhere, that it constitutes a theft directly from them. You know, the zero-sum of “their gain is our loss”. It may be a residue of their long-term dalliance with Marxist-Leninism and Communism.

Wouldn’t it be wonderful if only Russia could relax just a bit and join the international community of nations and trading partners. Too idealistic by half? Yes, for now.

Tyranny is Pulling up the Driveway

Roughly half of the American electorate sits immobilized while watching the American version of democracy slowly crossfade into some lesser form. We can lament in the (n + 1)th essay about #45/47’s inauguration and how that very day they begin deconstructing the federal government. But, by now whining about Trump and the GOP is nothing more than preaching to the choir.

As a practical matter in opposition, liberals are left to make phone calls to our representatives or slap a bumper sticker on our Subarus. The real power lies in the ability to donate cash to the party or the candidate. Even a heartfelt protest in front of a building or an assembly of the faithful listening to the other side’s politico is rarely effective in any measurable way.

Tyranny is a word often used by 2nd Amendment gun enthusiasts as a euphemism for government. Libertarians and Republicans are fond of it in particular. But if the mandate is to prevent tyranny, will they recognize it from Trump?

The words “Competitive Democracy” is appearing more frequently in the Googlesphere. A decent explanation is found below-

This whole Trump takeover of the federal government seems to have a libertarian flavor. No social safety nets, low taxes, expanded freedoms, diminished regulatory oversight and privatization of everything. Every service we get from the government would be privatized. Our every need or problem should be viewed as profit opportunity by a capitalist. Our present form of health care is like this.

My sarcastic definition of Libertarianism: it is the theoretical foundation of a Dickensian world where upward mobility of the lower class is near impossible, with the upper class comfortably nested across a yawning gap of wealth.

All of the open talk of upcoming fascism and authoritarianism makes me wonder if tyranny isn’t already pulling up the driveway to stay for a while. Isn’t tyranny what the 2nd Amendment gun crowd was always going on about? Will they notice that tyranny is presently being installed in the USA? Or is it the flavor of tyranny they prefer?

Trump is quickly placing loyalists into every part the federal government that uses power. He has the DOJ, CIA, FBI, Department of Defense, Department of Homeland Security, the US House & Senate, Inspectors General and more. He is consolidating power for himself. He has even started on the military.

Loyalty to Trump is demanded. But, isn’t loyalty to Trump just political loyalty? He often replies to criticism saying that his critics are “just being political.” He is placing political loyalists into positions of power to “fix” a condition that he previously called the swamp. The swamp was a federal workforce that were supposedly loyal to liberalism, according to him. He is replacing one allegedly unloyal group with his own loyalists. He is filling the offices with his own weaponized staff.

Typical Trump- he makes accusations of impropriety while he is doing it himself.

Trump’s adoring cult followers can somehow see around his wide load of character flaws and felonies to steal a view of a fabulous future he dangles before them. Is this a new dawn of a great America or just another America under a cult of personality?

China Restricts Exports of Critical Metals to the US

Trump’s ill-tempered brinksmanship and his coarse criticism of both long-term allies and old adversaries has begun to cost the US access to strategic materials. In particular, China has announced that it has banned the export of a group of metals and non-metals to the US. Specifically, China had previously imposed export controls on Rare Earth Elements (REE), gallium (Ga), germanium (Ge), antimony (Sb) and graphite (C). More recently it has included tungsten (W), tellurium (Te), bismuth (Bi), indium (In) and molybdenum (Mo) products.

In case the reader is unfamiliar with the uses of the above elements, a list of them with a short description is given below.

Many of the elements listed above are by-products from the refining of other metals like aluminum, copper, lead and zinc. Reduced production of aluminum, copper, lead and zinc will also reduce output of their accessory metals as well.

  • Gallium– Primarily used in semiconductors; is used to produce the denser, stabilized δ allotrope of plutonium for use in nuclear weapons.
  • Germanium– Primarily used in semiconductors; a by-product found in copper-lead-zinc ores.
  • Indium– Primarily used in semiconductors or other electronic applications; it is a by-product found in sulfidic zinc (Sphalerite) and copper ores (Chalcopyrite). Indium tin oxide (ITO) forms a thin, transparent and electrically conductive layer on glass for touch-screen applications such as smart phones.
  • Tellurium– A scarce element at an average occurrence 1 ppb in the crust and never the primary ore in mining. It is mostly found combined with gold as Calaverite (AuTe), Sylvanite (AgAuTe) or Krennerite (AuTe2 Orthorhombic gold telluride.) Tellurium has use in a large variety of applications. Unfortunately for gold miners, calaverite ore is not susceptible to cyanide extraction for gold recovery. Calaverite can be roasted and tellurium volatiles removed from the gold residues. However, commercial scale roasting of minerals is problematic in the US.
  • BismuthBismuth is never the primary ore in mining. It is found with lead, copper and tungsten. Broad applications across many domains. No longer produced in US. Bismuth is the highest atomic number element that is not naturally radioactive. Well, it’s half-life has been determined to be 1.9 × 1019  years which is still “pretty stable”.
  • Antimony– The largest antimony mine in the world is the Xikuangshan mine in Lengshuijiang Hunan, China. This mine produces 50 % of the world’s antimony. The mine produces antimony from 2 different minerals, stibiconite (Sb3O6(OH)) and stibnite (Sb2S3).
  • Molybdenum– Mined as the primary metal ore. About 86 % of molybdenum is used in metallurgy with the rest used in chemical applications. An important molybdenum mineral is molybdenite, MoS2. Important US mines are the now-defunct Henderson Mine and the now operating Climax Mine, both in Colorado and both operated by Freeport-McMoRan. The Climax Mine resides at the summit of Freemont Pass at 11,360 ft altitude and to the north of Leadville, Colorado. Molybdenite deposits can be found as far away as Questa, New Mexico, with the Chevron Questa Molybdenum mine which is now closed and undergoing reclamation as a superfund site.
  • Graphite– Natural graphite arises from metamorphization of carbonaceous sediment. It can mined or produced synthetically. Graphite is the most chemically stable allotrope of carbon at standard pressure and temperature.
  • Tungsten– Also known as wolfram (W), tungsten has the highest melting point and lowest vapor pressure of the elements. As a refractory metal, tungsten us often used in high temperature applications such as welding and for its relative chemical inertness affording high resistance to corrosion. In military applications tungsten is exploited for its combination of high density, hardness and refractory properties in projectiles and other applications. In chemical form, it is often found as a polyoxometallate anion such as WO4−2, “orthotungstate”. These polyoxometallate anions can form higher order cage structures.

All of the above elements are well established in diverse products and are a part of numerous leading-edge technologies in use today. All ores are subject to the market price of their mined and milled products. All of the elements listed above are produced in various simple but purified forms that customers will plug into their own production lines. The economics of their mine operation has a high reliance on the margins offered by their raw material costs. If the raw material supplier goes a step further and captures value-added profit margins by offering an advanced intermediate or even the final product, then the customer faces having to use the more costly value-added materials. The effect can be that they must raise prices on their product or step away from the market. This is just the old familiar path of competition.

As luck would have it, early in geologic history China won the mineral lottery when many ore-forming processes valuable ores in its present territory. We have all heard of China’s supremacy in rare earth element (REE) reserves. China eventually made the choice of halting exports of rare earth minerals as the oxides in favor of offering value added finished products instead. Business-wise, this was a smart and inevitable choice for China, but users who manufactured REE products from their imported REE raw materials were suddenly facing stiff competition from abroad.

Since this policy of China metering closely the export of REE minerals, western countries have made considerable progress locating REE deposits elsewhere. Incidentally, the same holds true for lithium deposits.

From Google Maps. An aerial view (supposedly) of part of the large Xikuangshan mine in Hunan, China.

Restrictions on exports of the above elements will have a large impact on many industries in the US. My question is this: Could a better diplomatic approach to imports from China have been made?

It isn’t all bad news. Difficulties with raw material prices and availability frequently motivate users to invent a way around problematic raw materials. There is nothing like the motivation to fire up the inventive juices than to seek a work-around for a raw material supplier problem.

Our Pouty President Announced US withdrawal from World Health Organization

Manhattan real estate magnate DJ Trump, US President and amateur epidemiologist, has announced that the US will exit the World Health Organization (WHO), according to Reuters.

MAGA’s spiritual hero and standard bearer also said that his administration would cease negotiations on the WHO pandemic treaty during the withdrawal process. He still seethes over WHO from his previous administration and claims that they mishandled the COVID-19 pandemic. Trumps words read as pouty and not powerful.

This kerfuffle does not appear to be a bluff. Trump has a long history of refusing to pay contractors who have completed projects for him, claiming that they were attempting to rip him off. This move casts a similar shadow. Even if he personally benefits by the work of others, he has had no trouble stiffing them on their bills. This history of nonpayment blended with his spectacular ignorance of everything technical adds up to this stupid move. His transactional mind is only one dimensional, apparently, and is blind to the importance of WHO. Infectious disease can move beyond national borders and into the US at 500 miles per hour via jet aircraft as was the case of HIV/AIDS. An international entity is needed to intervene, especially in the spread of infectious disease.

One would suppose that the US, as the largest donor to WHO, would have had more leverage in renegotiation on payments or other objectionable issues.

#45-47 is a guy who commuted sentences and pardoned 1500 people who participated in the January 6th, 2021 riot and destructive and illegal entry into the US capitol building. This despite complete video evidence and guilty verdicts. Below is a quote by the QAnon, the horned shaman-

So, let the idiot gets his guns. This was his reflex after getting out of prison. Make yer momma proud, bucko.

Thus, a truly ugly chapter continues in the history of our country.

A Cold Wind Blowing

Somebody mentioned that the fellow who wants to take over Greenland moved the inauguration indoors due to the cold. Perhaps it should always have been indoors due to January weather, but the inauguration belongs to the people who elected the new POTUS and VPOTUS. They (we) should get to witness it directly. Some wag has suggested that the move was really to prevent low public attendance from being visible.

The ceremony will be limited to the upper crust of politicians and big wheels. In the confined space of the Capitol Rotunda the turnout is guaranteed to look packed, which will please the ratings-conscious Felon in Chief.

I’ll miss out on the proceedings this time. Too painful to watch.

Sustainability? Can We Reinforce the House of Cards that Civilization has Become?

Ask yourself this- will your descendants in the year 2125 share in the creature comforts coming from the extravagant consumption of resources that we presently enjoy? Shouldn’t the concept of “sustainability” include the needs of 4-5 generations down the line?

The word ‘sustainability’ is used in several contexts and in contemporary use remains a fuzzy concept with few sharp edges. In this post I will refer to the sustainability of raw materials, fully recognizing that it covers numerous aspects of civilization.

There are wants and there are needs. For the lucky among us in 21st century developed nations, our needs are more than satisfied leaving surplus income to satisfy many of our wants. Will our descendants a century from now even have enough resources to meet their needs after our historical wanton and extravagant consumption of resources dating to the beginning of the industrial age? Our technology stemming from the earth’s economically attainable resources has done much to soften the jagged edges of nature’s continual attempts to kill us. After each wave of nature’s threats to life itself, survivors get back up only to face yet more natural disasters, starvation and disease. This is where someone usually offers the phrase “survival of the fittest”, though I would add ” … and the luckiest”.

What will descendants in 100 or 200 years require to fend off the harshness of nature and our fellow man? Pharmaceuticals? Medical science? Fuels for heat and transportation? Will citizens in the 22nd century have enough helium for the operation of magnetic resonance imagers or quantum computers? Will there be enough economic raw materials for batteries? Will there be operable infrastructure for electric power generation and distribution? Lots of questions that are easy to ask but hard to answer because it requires predicting the future.

Come to think about it, does anyone worry this far in advance? The tiny piece of the future called “next year” is as much as most of us can manage.

Humans would do well to remember that a great many of the articles that we rely on are manufactured goods, such as: automobiles, aerospace-anything, pharmaceuticals, oil & gas, metals, glass, synthetic polymers (i.e., polyethylene, polypropylene, PVC, polystyrene etc.), medical technology and electrical devices of all sorts. Each of these categories split off into subcategories all the way back to a farm or a mine. And let’s remember that both mining and farming are both reliant on big, expensive machinery and lots of water.

Each of the contributing technologies holding up any given apex technology were new and wondrous at one time. Think of a modern multicore microprocessor chip. Follow the chip’s raw materials back to the mines and oil & gas wells where the raw materials originated. Once you’ve done that, consider all of the people and inputs necessary in each step getting from the mine to the assembly of a working microprocessor. Each device, intermediate component or refined substance is at or near the apex of some other technology pyramid. To keep moving forward, people need to connect each apex technology input in a way to get to their own apex endpoint.

We mustn’t forget all of the machinery and components, energy to power them, transportation and trained personnel needed to manufacture any given widget. Skilled hands must be found to make everything work.

A given technology using manufactured goods is a house of cards kept upright by constant attention, maintenance, quality control and assurance, continuous improvement and hard work by sometimes educated and trained people. Then, there is a stable society with institutions, regulations and a justice system that must support the population. The technology driving our lifestyles does not derive from sole proprietor workshops in a corrugated iron Quonset building along the rail spur east of town. The highly advanced technology that is driving economic growth and the comfortable lives we enjoy comes from investors and factories and international commerce. A great many products we are dependent on like cell phones are affordable only because of the economies of large-scale production.

So, what is the point of this? Sustainability must also include some level of throttle back in consumption without upsetting the apple cart.

A plug for climate change

For a moment, let’s step away from the notion that the atmosphere is so vast that we cannot possibly budge it into a runaway warming trend. The atmosphere covers the entire surface of the planet with all of its nooks and crannies, but its depth is not correspondingly large. In fact, the earth’s atmosphere is rather thin.

At 18,000 feet the atmospheric pressure drops to half that at sea level. The 500 millibar level varies a bit but is generally near this altitude. This means that half of the molecules in the atmosphere are at or below 18,000 feet. This altitude, the 500 millibar line, isn’t so far away from the surface. From the summits if the 58 Fourteeners in Colorado, it is only 4000 ft up. That is less than a mile. The Andes and the Himalayan mountains easily pierce the 500 millibar line.

Our breathable, inhabitable atmosphere is actually quite thin. The Earth’s atmosphere tapers off into the vacuum of space over say 100 km, the Kármán line. Kármán calculated that 100 km is the altitude at which an aircraft could no longer achieve enough lift to remain flying. While this is more of an aerodynamics based altitude than a physical boundary between the atmosphere and space, the bulk of the atmosphere is well below this altitude. With the shallow depth of the atmosphere in mind, perhaps it seems more plausible that humans could adversely affect the atmosphere.

The lowest distinct layer of the atmosphere is the troposphere beginning as the planetary boundary layer. This is where most weather happens. In the lower troposphere, the atmospheric temperature begins to drop by 9.8 °C per kilometer or 5.8 oF per 1000 ft of altitude. This is called the dry adiabatic lapse rate. (With increasing altitude the temperature gradient decreases to about 2 oC per kilometer at ~30,000 ft in the mid-latitudes where the tropopause is found. The tropopause is where the lapse rate reaches a minimum then the temperature remains relatively constant with altitude. This is the stratosphere.)

Over the last 200 years in some parts of the world, advances in medicine, electrical devices, motor vehicles, aerospace, nuclear energy, agriculture and warfare have contributed to what we both enjoy and despise in contemporary civilization. The evolving mastery of energy, chemistry and machines has replaced a great deal of sudden death, suffering and drudgery that was “normal” affording a longer, healthier lives free of many of the harmful and selective pressures of nature. Let’s be clear though, continuous progress relieving people of drudgery can also mean that they may be involuntarily removed from their livelihoods.

It is quintessentially American to sing high praises to capitalism. It is even regarded as an essential element of patriotism by many. On the interwebs capitalism is defined as below-

As I began this post I was going to cynically suggest that capitalism is like a penis- has no brain. It only knows that it wants more. Well, wanting and acquiring more are brain functions, after all. Many questions stand out, but I’m asking this one today. How fully should essential resources be subject to raw capital markets? It has been said half in jest that capitalism is the worst economic system around, except for all of the others.

I begin with the assumption that it is wise that certain resources should be conserved. Should it necessarily be that a laissez faire approach be the highest and only path available? Must it necessarily be that, for the greater good, access to essential resources be controlled by those with the greatest wealth? And, who says that “the greater good” is everybody’s problem? People are naturally acquisitive- some much more than others. People naturally seek control of what they perceive as valuable. These attributes are part of what makes up greed.

Obvious stuff, right?

The narrow point I’d like to suggest is that laissez faire may not be fundamentally equipped to plan for the conservation and wise allocation of certain resources, at least as it is currently practiced in the US. Businesses can conserve scarce resources if they want by choosing and staying with high prices, thereby reducing demand and consumption. However, conservation is not in the DNA of business leaders in general. The long-held metrics of good business leadership rest on the pillars of growth in market share and margins. Profitable growth is an important indicator of successful management and a key performance indicator for management.

First, a broader adoption of resource conservation ideals is necessary. Previous generations have indeed practiced it, with the U.S. national park system serving as a notable example. However, the scarcity of elements like Helium, Neodymium, Dysprosium, Antimony and Indium, which are vital to industry and modern life, this raises concerns. The reliance of Magnetic Resonance Imaging (MRI) operations on liquid helium for their superconducting magnets poses the question of whether such critical resources should be subject to the whims of unregulated laissez-faire capitalism. While some MRI operators utilize helium recovery systems, not all do, leading to further debate on whether the use of helium for frivolity should continue, given its wasteful nature.

Ever since the European settlement of North America began, settlers have been staking off claims for all sorts of natural resources. Crop farmland, minerals, land for grazing, rights to water, oil and gas, patents, etc. Farmers in America as a rule care about conserving the viability of their topsoil and have in the past acted to stabilize it. But, agribusiness keeps making products available to maximize crop yields, forcing farmers to walk a narrower line with soil conservation. Soil amendments can be precisely formulated with micronutrients, nitrogen and phosphate fertilizers to reconstitute the soil to provide for higher yields. Herbicides and pesticides are designed to control a wide variety of weeds, insect and nematode pests. Equipment manufacturers have pitched in with efficient, though expensive, machinery to help extract the last possible dollars’ worth of yield. Still other improvements are in the form of genetically modified organism (GMO) crops that have desirable traits allowing them to withstand herbicides (e.g., Roundup), drought or a variety of insect, bacterial, or fungal blights. The wrench in the gears here is that the merits of GMO crops have not been universally accepted.

Livestock production is an advanced technology using detailed knowledge of animal biology. It includes animal husbandry, nutrition, medicines, meat production, wool, dairy, gelatin, fats and oils, and pet food production. There has been no small amount of pushback on GMO-based foods in these areas, though. I don’t follow this in detail, so I won’t comment on GMO.

The point of the above paragraphs is to highlight a particular trait of modern humans- we are demons for maximizing profits. It comes to us as naturally as falling down. And maximizing profits usually means that we maximize throughput and sales with ever greater economies of scale. Industry not only scales to meet current demand, but scales to meet projected future demand.

Essentially everyone will likely have descendants living 100 years from now. Won’t they want the rich spread of comforts and consumer goods that we enjoy today? Today we are producing consumer goods that are not made for efficient economic resource recovery. Batteries of all sorts are complex in their construction and composition. Spent batteries may have residual energy left in them and have chemically hazardous components like lithium metal. New sources of lithium are opening up in various places in the world, but it is still a nonrenewable and scarce resource. This applies to cobalt as well.

Helium is another nonrenewable and scarce resource that in the US comes from a select few enriched natural gas wells. At present we have an ever-increasing volume of liquid helium consumption in superconducting magnets across the country that need to remain topped off. This helium is used in all of the many superconducting magnetic resonance imagers (MRI) and nuclear magnetic resonance (NMR) spectrometers in operation worldwide. Quantum computing will also consume considerable liquid helium as it scales up since temperatures below the helium boiling point of 4.22 Kelvin are required.

As suggested above, today’s MR imagers can be equipped with helium boil off recovery devices that recondense helium venting out of the cryostat and direct it back into a reservoir. One company claims that their cold head condensers are so efficient that users do not even have to top off with helium for 7-10 years. That seems a bit fantastic, but that has been claimed. Helium recovery is a good thing. Hopefully it is affordable for most consumers of MRI liquid helium.

In the history of mining in the US and elsewhere, it has been the practice of mine owners to maximize the “recovery” of run-of-mill product when prices are high. Recovery always proceeds to the exhaustion of the economical ore or the exhaustion of financial backing of the mining company. Uneconomical ore will remain in the ground, possibly for recovery when prices are more favorable. It is much the same for oil and gas. As with everything, investors want to get in and get out quickly with the maximum return and minimum risk. They don’t want their investment dollars to sit in the ground waiting for the distant future in order to satisfy some pointy headed futurist and their concern for future generations.

What is needed in today’s world is the ability to conserve resources for our descendants. It requires caring for the future along with a good deal of self-control. Conservation means recycling and reduced consumption of goods. But it also means tempering expectations for extreme wealth generation, especially for those who aim for large scale production. While large scale production yields the economies of scale, it nevertheless means large scale consumption as well. In reality, this is contrary to the way most capitalism is currently practiced around the world.

Sustainability

The libertarian ideal of applying market control to everything is alleged to be sustainable because in appealing to everyone’s self-interest, future economic security is in everyone’s interest. If high consumption of scarce resources is not in our long-term self-interest, then will the market find a way to prolong it? As prices rise in response to scarcity, consumption should drop. ECON-101 right? Well, what isn’t mentioned is that it’s today’s self-interest. What about the availability of scarce resources for future generations? Will the market provide for that?

Is the goal of energy sustainability to maintain the present cost of consumption but through alternative means? Reduced consumption will occur when prices get high enough. As the cost of necessities rises, the cash available for the discretionary articles will dry up. How much of the economy is built on non-essential, discretionary goods and services? The question is, does diminished consumption have to be an economic hard landing or can it be softened a bit?

Where does technological triumphalism take us?

The generation and mastery of electric current has been one of the most consequential triumphs of human ingenuity of all time. It is hard to find manufactured goods that have not been touched by electric power somewhere in the long path from raw materials to finished article. As of the date of this writing, we are already down the timeline by many decades as far as the R&D into alternative electrification. What we are faced with is the need to continue rapid and large scaling-up of renewable electric power generation, transmission and storage for the anticipated growth in renewable electric power consumption for electric vehicles.

Our technological triumphalism has taken us to where we are today. The conveniences of contemporary life are noticed by every succeeding generation who, naturally, want it to continue. This necessitates that the whole production and transportation apparatus for goods and services already in place must continue. We have both efficient and inefficient processes in operation, so there is still room for more triumph. But eventually resources will become thin and scarcity of strategic minerals becomes rate limiting. Economies may or may not shift to bypass all scarcity of particular articles.

Perhaps a transition from technological triumphalism to minimalist triumphalism could take place. The main barrier there is to figure out how to make reduced consumption profitable. Yes, operate by a low volume, high margin business model. That already works for Rolls Royce, but what about cell phones and sofas?

Something else that stymies attempts at reduced consumption is price elasticity. This is where an increase in price fails to result in a drop in demand. Necessary or highly desirable goods and services may not drop in demand if the price increases at least to some level. As with the price of gasoline, people will grumble endlessly about gas prices as they stand there filling their tanks with expensive gasoline or diesel. Conservation of resources has to overcome the phenomenon of price elasticity in order to make a dent without shortages.

A meaningful and greater conservation of resources will require that people be satisfied with lesser quantities of many things. In history, people have faced a greatly diminished supply of many things, but not by choice. Economic depression, war and famine have imposed reduced consumption on whole populations and often for decades. When the restriction is released, people naturally return to consumption as high as they can afford.

The technological triumph reflex of civilization has allowed us to paint ourselves into a resource scarcity corner.

I’d like to believe that humanity could stave off the enviable conflict that would spark from numerous critical resource shortages, but I doubt the people and nations of the world can do it.

Them Texicans

Question: What’s the deal with the government of Texas?

Reply: We don’t have enough time for that.

Governor Greg Abbott, aka by some as “Wheelie”, has ordered all flags be raised to full staff in honor of Inauguration Day, pursuant to federal statute.

At first this doesn’t seem to be much of an event, but it is plainly and uniquely a petty act of defiance against the nation’s honoring of the life and death of 39th US President Jimmie Carter, a Democrat btw, taking less priority than the Trump’s inauguration. It is so … Texas.

As a coworker from South Carolina used to say, “You can always tell a Texan, but you can’t tell ’em much”. I repeat this saying only out of love. I have great respect for the citizens and land of Texas. I made many life-long friends and colleagues there. But the GOP government is regressing the state and softening the populace for increasing theocracy.

Texas state politics has a very strong Republican and evangelical protestant conservative bent to it. That is no secret. The state also has a very strong independent streak and many brag that they can choose to become independent again at any time. I don’t care enough to dedicate heartbeats to validate this, but I heard it many times. MAGA Texas Governor Abbott is a true populist to conservative voters and Democrats can go suck eggs. The state government is ultraconservative and will likely remain that way for decades.

Happier Texas Anecdotes

I did time in Texas- 22 months to be exact. I was a post-doctoral fellow there for that stretch of time in the early 1990s. It was in San Antonio. I’ve always said that if you absolutely must live in Texas, San Antone is a good place to do it. When I was there, SA was very much a military town with Army and Air Force bases and a lot of military retirees. Today the 4 bases are part of what is called Joint Base San Antonio comprised of Randolph Air Force Base, Fort Sam Houston, Lackland Air Force Base and Camp Bullis. A building at Randolph was called the Taj Mahal. It stood out.

Taj Mahal or Building 100 at Randolph AFB in San Antonio, TX. Photo Source: Wikipedia.

A friend who was retired from USAF as a bird colonel flew the delta-wing Corvair B-58 Hustler supersonic nuclear bomber for the Strategic Air Command (SAC) early in his service. As a military retiree he worked as a “Mr. Fixit” for the chemistry and physics departments at our university. One day, he took me to a Lackland AFB hangar to see a B-58 under restoration. My photos are lost to the sands of time, but they had made a good bit of progress by then. Pictures do not really convey the size of this beast.

Corsair B-58 Hustler. Source: Wikipedia. The external tank holding fuel and a nuclear weapon is visible below the fuselage.

The B-58 had no internal bomb bay so the early version had an external pod partitioned to carry both fuel and a nuclear weapon. Later versions had 4 hardpoints under the wing enabling it to carry up to 5 weapons. The Mach 2 aircraft could sustain supersonic flight and altitudes up to 50,000 to 70,000 feet with a crew of 3. The delta wing offered more storage volume for internal systems and fuel.

The downsides of the aircraft were serious. Reportedly it was difficult to fly and imposed a high workload on the crew. To sustain supersonic flight, high fuel consumption required frequent midair refueling. The aircraft was designed for high altitude, supersonic penetration of enemy airspace. But when the Soviets came up with high altitude surface-to-air missiles, the mission altitude had to be lowered, resulting in lower range. It was also expensive, costing more than the B-52 Stratofortress. Due to cost and obsolescence the aircraft was retired in 1970 after a short 10-year service and was replaced by the F-111.

We left that hangar at Lackland and went into another that had a WWI vintage Thomas-Morse biplane stored there. The engine was of the fixed crankshaft, rotating engine block rotary engine variety. It had no throttle in the modern sense by feeding a fuel/air mixture with a single adjustment. Power was regulated by cutting the ignition with the “blip switch” occasionally, especially on approach to landing, or by adjusting the fuel valve back to a preset position, then adjusting the air flow. Using the blip switch was faster but resulted in fuel and engine oil building up in the cylinders. Somehow this leads to gas and oil leakage and serious engine fires. Because the larger piston block was spinning rather than the crankshaft, engineering a normally carbureted fuel/air mixture was not possible at the time. To adjust the power, a predetermined fuel flow was chosen and then the air was adjusted through a flap valve to vary the power. It wasn’t a beginner’s aircraft.

Thomas-Morse S-4C. The aircraft I saw looked similar to this photo but the model number is long lost in the mists of time. Source: Wikipedia

Top Tips for Choosing a Graduate School in Chemistry

Everyone who has been through graduate chemistry has views on how to do it. I’m no different.

Here is my view: Advancement in academic chemistry requires a number of sequential situations that are advantageous to be a part of. First, your advanced chemistry degree should be done in the “right” subdiscipline. Everybody wants to attend a highly prestigious school where the faculty consult with the Gods of chemistry on Thursday afternoons. However, these schools are very competitive in their selection processes, and you may be denied admission for reasons that never become clear.

There is no doubt that if you want to become a professor at a major PhD granting institution, it’s best to have an ivy league pedigree in terms of schools and mentors. Having won a named fellowship as a grad student or postdoc is a good endorsement and always helpful. JACS publications are helpful as well.

Of course, there is more to it than that, but a top shelf pedigree can certainly help get an interview. A cutting-edge research proposal in 1 or 2 or 3 “hot” areas of science will be expected. Aim high for the big challenges in your field. Before any interviews, it is well worth reviewing the areas of research and general interest of the chemistry faculty at a prospective school. Examine the department for overall research productivity and balance. Is there a major player in or near your area of interest? Most chemistry departments are looking to staff up with specialists in up-and-coming areas of interest.

To stay alive a graduate chemistry program needs a constant flow of talented students parachuting in to fill the research groups and as TAs to teach undergraduate labs, proctor and grade exams, lead recitation sections between lecture sessions and hold office hours. Some schools will require at least 1 year of TA work and if your graduate mentor has money, he/she will hire you as a research assistant or RA.

Next, find a mentor/prof who is research-active in your area. How do you find them? In my opinion, a good way is to choose a graduate school with a prof/mentor who is well funded, tenured preferably, and has published numerous papers very recently. Put more emphasis on the profs available than the school. Such an individual situated thus has likely found a gold vein of opportunity that is fundable and at the leading edge of fundable science.

An important consequence of a well-funded mentor/prof is that you will likely be paid as a research assistant (RA) rather than as a teaching assistant (TA). A prof in this situation has a good chance of being well connected in academic space which will be very valuable in securing a plum industry, post-doc or academic position after graduation. Some chemistry profs consult for industry which may provide a valuable advantage for a good industrial job after graduation.

Your first job may not relate to your graduate work. Don’t worry, you’ll soon learn that your PhD is a union card that opens many doors. But never forget, there is a good bit of luck involved too. In an interview you never know what kind of faculty research a given school is looking for if any. Chemistry departments often want to swerve to a new area of expertise, or they may want to add to their present strengths. Coming from a renowned professor’s group may be the tipping point for you. Or they are looking for a good replacement candidate who they can also live with day to day. It’s good to know ahead of time.

I once interviewed at a public university chemistry department that was planning 22 contact hours from day 1 and required a healthy, fundable research program, but with not even a square foot of bench space and no NMR. They had a large pharmacy program and needed warm bodies to teach organic chemistry and labs. Two organic faculty members advised independently behind closed doors that I should not take the job. I thanked the department for the interview and declined the offer.

In general, throw your shyness overboard and be more outgoing and sociable. Dress and groom respectably. Be quick to laugh with others but know when to be serious. Always be honest and kind with people. Advancement in the chemical science world is more than knowledge of reaction mechanisms. There is a large social component that may not get you a job but will make your career more fun. Enjoy it.