WordPress offers this really cool polling feature. Now if I could only formulate some intelligent questions … hmmm.
The Gaussling is on the road, getting further educated in the non-linear ways of chemicals.
Scooter Labs claims to offer tutorials on building a 2-wheel, self balancing scooter, or a self-balancing propulsion unit. This is a homebrew version of the Segway. Another site, Suicidebots, conducted an interview of the founder. Oh, to be a fly on the wall the day the injunction arrives from Segway.
Note: The following has been determined to be a diatribe and not a screed. A screed would be several times longer.
This period in US history contains enough meat on the bone to keep both scholars and crackpots gnawing for decades. Collectively, we are in the overlap space of a sociological Venn diagram. The overlapping domains of economic calamity, political paranoia, shrinking international stature, and withering military expense combine like cyan, magenta, and yellow to form a white hot zone of malcontent.
It is no overstatement to say that many if not most Americans have chosen a part of the political pool they want to swim in. Listen to the voices at McCain/Palin rallys. Listen to people being interviewed upon leaving a McCain/Palin rally. They’re invariably angry and fearful. They distrust the “Liberal Media”. Do they mean to include Rupert Murdoch’s media empire? Do they also include most of the AM band talk radio programs? Is this the deep end of the pool or the shallow end?
I cannot help but conclude that conservatives are a fearful bunch. Study the McCain/Palin campaign advertising. Go back to any recent presidential campaign and recall Willie Horton or the Swift Boat attack on the democrats. Fear is the unifying ingredient in conservatism and the people who run the GOP machine know how to swing this stick. Democrats do the Fear theme poorly and as a result, cannot summon the same kind of existential panic that the GOP can pull from their bag of tricks.
McCain is starting to see some of the visceral response to the possibility of Obama as president from underneath all of the rocks and behind all of the tarpaper shacks in the political back-40 acres. He has been openly challenged by angry citizens about the viability of his campaign.
That cartoon figurehead of the GOP, Rush Limbaugh, was practically apoplectic in his frustration with McCain. Strangely, this political freakshow impressario is now towing the line on McCain and has focused his leagions of ditto-zombies on bringing down the reputation of Obama with a mezmerising whisper campaign of slander.
I’m beginning to think that McCain wouldn’t be the worst kind of GOP president to have, especially if the conservatives of the land are this uncertain of him. But Palin as runner-up to the Whitehouse leaves me speechless. A country so brain-addled as to put Palin in national office is perhaps a country that needs to have its nose rubbed in it for a taste of its own collective stupidity. McCain/Palin in Washington may be what it takes for the complete implosion of the GOP.
Having watched the rise of Bush II and the conduct of the 2008 campaign, I have begun to understand what it might have been like to have lived in the period leading up to the American Civil War. This was a period intense division between citizens regarding deeply held beliefs. Civil and religous laws were invoked by both sides to justify their actions. Both Lee and Sherman believed that they marched in righteousness. It was brother fighting brother with a kind of hostility that is startling to people even today.
I sense a widespread and internal hostility along with a rigid adherence to doctrine that marks a divided country. I believe that America is in a type of cold civil war. There is a fulmination of anger and frustration out there that is beginning to partition the meaning of America into distinct translations that suit the adherents.
Countries that experience economic and political upset are prone to the surfacing of latent fascism. Fascism is a kind of fever that spreads through the vectors of blame and jingoism. Anti-intellectualism and ethnic hatred are common manifestations of a country having a bout of fascism fever.
Witness the accusations of “elitism” and the whisper campaign questioning the citizenship and religious affiliation of Obama. We have elite military forces, elite police forces, and elite athletes- why not elite chief executives? Why would we demand that politicians be just like the down-home folks like you see, say, running the Tilt-O-Whirl at the carnival? Don’t we want the chief executive to be someone who has honed his skills for public life? The Army has its War College. Why can’t the executive branch have its Administration school?
I think we have a civil cold war brewing in the USA right now and if 20-25 % of the workforce loses its paycheck because of the banking fiasco, I think there’ll be trouble. But no doubt, the DHS has thought of this and has soldiers and Darkwater contractors ready to deal with the sh**storm.
Savoir faire is one of those ethereal attributes that a lucky few are born with and something that most of the rest of us have to constantly work on. The world of sales and business development folk very often involves a business dinner in a fine dining establishment. Very often dinner is a prelude to the next days work, so dining is a great opportunity to get to know the customer.
It is important to realize when taking a potential client out for dinner, one is very much under inspection. A client can be put off in many ways. Poor table manners, boorish behavior, poor listening skills, and shabby taste in restaurants can turn the dinner from a plus plus into a minus minus.
Here is how you make a big impression on a client. I learned this from a professor at Denver University’s hotel & hospitality school. Go to the restaurant the day before and meet the maitre d’. You introduce yourself and explain that you have an important engagement the next night. Give him/her a business card and a several $100 bills. Explain that you want to be addressed by name as you enter the restaurant.
Next, you find the waiter and repeat the instructions. You want to be greeted by name as you are seated. You don’t want their life story, you just want them to be efficient and scarce. Finally, you go into the kitchen and greet the chef. Explain that the next evening is important and ask if he/she has any items that are not on the menu. Thank the chef profusely and go about your business.
The next evening after dinner, overtip the staff. Throwing around a few hundred dollars will get peoples attention and should get you a better table and better service. Doing it ahead of time invests the staff in the gig and will be gratefully appreciated.
I couldn’t help but reprint this list of Tips on Tipping from Bruce Feiler at Gourmet.com. His 3 page essay on learning how to get a table in a posh restaurant and how to tip in advance is quite well written and should encourage the socially inept to give it a try. Remember, don’t fumble with your wallet fishing for a crumpled note. Have the note neatly folded and ready for a discrete handoff. Show a little style for cryin’ out loud.
The rhyme of history is ringing in my ears. An obscure, slender figure (sans stove pipe hat) has arrived from Illinois amidst the shattered remains of the Whig party. Alright, that’s an exaggeration.
Our do-nothing, know-nothing warrier prince is nowhere to be seen. The Republican Paradigm, under the leadership of its very own cartoon character- Dubya- has had the misfortune of leaving its greasy fingerprints all over the collapsing financial system. And it’s not just politicians who have left their grubby smudges all over the shards of Grandma’s bone china. It includes the rank & file junior plutocrat-wannabe’s and MBA greedheads under the cloak of the GOP who have gamed the system with zero regard for its stability.
The great benefit of Laissez Faire as a moral philosophy is that one is excused from moral culpability. Nobody expects you to behave honorably because morality is orthogonal to the market. There is no overlap. You are expected to be self-centered and greed is just the normal operating condition. It’s all good, baby.
Mr Bush has not stepped forward to offer advice or reassurance to the citizenry. Bush is brave when he can order the Army to march in somewhere. But if the problem involves math, lookout. And where is Mr Rove, Bush’s brain? I suppose he is absent because he is a specialist in election, not governance. He just delivers these disasters to the Whitehouse. He evidently holds little or no indemnity for his work.
Instead, this ideological weasel, this scoundrel-in-chief, is hunkered down out of sight during the election so as to avoid contaminating McCain/Palin with the foetid stink of GOP incompetence.
The framers of the constitution apparently never anticipated that the republic could be run aground by a frat-boy imbecile egged on by a pack of greedy, morally vacuous, shady characters from the military-industrial-finance-fundamentalist “sector”.
The US constitution needs a provision for mid-term ejection of incompetent fools.
One of my great enthusiasms is the topic of small scale continuous synthesis. There has been some new thinking in this area recently. I don’t mean the use of robots to move material around- I mean continuous flow reactions. Our refinery friends have been doing this for a long time. It’s the reason gasoline isn’t $25/gallon.
Many, if not most, supplies of bulk raw materials come from continuous process equipment. The economies of large scale may require custom reaction equipment dedicated to a given product. The problem for small scale production is the cost of custom designed equipmet is often large compared to the value of the production run. It is usually best to develop processes to operate in conventional, off-the-shelf pots & pans.
The availability of stirred tank reactors and their ease of use for small scale production has dominated the mode of specialty chemical process technology to the present day. Generations of chemists and engineers in fine and specialty chemicals know nothing other than batch reactor chemistry.
Easy, inexpensive continuous processing isn’t automaticaly suitable for every process. Transformations that are suitable for continuous flow processing may still be disqualitied by virtue of upstream or downstream processes that feed from or into transformations that must be done batchwise. There is the question of feed rates to and from the continuous transformative step and the extent to which non-continuous operations are compatible.
But back to basics. Why have continuous synthesizers at all in the small scale? Why not just run the semi-batch process as may times as you need at the largest scale possible? Well, there is no reason not to. This is a tried and true business plan. But what small scale continuous processing allows is the possibility of multiple parallel operations run by fewer staff. At the small scale, batch chemical production typically has a larger labor component than bulk or commodity scale production. Improvements to small scale process economics rests to a large extent on reducing the labor cost contribution.
By it’s nature, continuous processing is an intensified activity. The idea is to construct a minimum reactive volume and flow materials through the reaction or processing zone under intensified conditions for as short of a residence time as possible. At any given moment, there is a minimum mass of hazardous materials undergoing a potentially hazardous transformation. Or, intensification may mean the use of smaller ancillary equipment continuously, as in the case of continuous filtration vs batch filtration.
There are those who are making progress in this field. Recently I ran into a number of websites and files of Ashe Morris in the UK. These folks are operating a productive engine of development in regard to reactor design and innovative process chemistry improvemets. They have focused on process efficency and intensification. The question is, what shape will the IP take? Will users pay a royalty on their production or will it be limited to the purchase cost ofthe equipmet. How they do this will make all of the difference to the extent and rate of acceptance in the market.
Everyone should have a chance to use a fire extinguisher on a real fire. The trouble with this idea is that the annual discharge of fire extinguishers is expensive, training fires can be problematic, and the discharge from the extinguishers can leave a big mess.
I had the chance recently to undergo annual training with a new controlled fire training system made by BullEx. I’ll admit to being skeptical at first. It seemed awfully contrived and … safe. But watching the tenderfoot office staff line up with their backup buddies to use pressurized water to put down a controlled and “adjustable” fire, I finally came around and had to agree that the system has considerable merit. For us, the system pays for itself in 1 year of training in terms of retiring dry chemical recharge costs.
Most would agree that a fire extinguisher is fairly simple to use. What seems to be the hard part for many is overcoming the uncertainty about whether they should use the extinguisher and under what circumstances. While the simulator does not produce smoke, obnoxious fumes, and there is no dust cloud from a dry chemical extinguisher discharge, the system does a good job of building confidence in people who may be a bit timid.
Reports have been circulating that the US Mint has suspended the sales of gold coins. The mint has been experiencing unprecedented demand for gold and silver coins. A short list of favored dealers has been drawn up for distribution of the limited supply.
What is curious about this is that the US Mint has “suspended” sales rather than simply announcing that it has a backlog. Only the govenrment would respond to demand in this way. I understand that minting gold coins is not nearly as automated and fast as base metal coins. But by their manner of responding to the demand, they can only accelerate the rise in price for these coins.
I have captured a snapshot of PGM pricing from the BASF EIB website. I hope BASF isn’t too hacked off.

The Canadian Maple and South African Krugerrand gold coins are available, as far as I can tell from internet sources.
Of interest to the catalyst world is the falling price of Palladium. The chart below is scaled to show the price of bullion for the last 12 months. This is surely a kind of economic indicator affording a clue as to the vitality of some particular and narrow market sector.

I wonder where the opportunities are in this difficult time? Now is a good time to keep your head on a swivel for unique opportunity.
Could it be that we Americans are over reacting to the problems in the market? The market is very much a collaborative structure resting heavily on trust in the power of the vast American economic engine. What we are witnessing right now is the multichannel, speed-of-light, propagation of panic through the miracle of electronic communication. Wagging tongues and chin music from our esteemed news commentators as well as we, the blogging community, are only fanning the fire of panic. The USA is on the verge of freaking itself into an economic collapse.
We don’t need additional and more concise descriptions of the foolishness of the players. That’s been done. I participated in this too. Ascerbic wit and biting rhetoric needs to be turned to constructive service. The first thing that we can do as bloggers citizens is to tone down the negative buzz and quit getting each other twittered. It serves no purpose and is counter-productive.
Citizens need to start asking constructive questions and make suggestions to all who will listen on how best to minimize panic and the damage it will cause to our economy. We need to take some time from blogging to focus on communicating with our friends and colleagues and members of congress to keep a steady hand in the coming months.
We also need to start asking about the details of the financial mess. Of the “bad mortgages” we hear about, how many are actually in default vs how many are just in the category of subprime? Are the banks possibly exaggerating the size of the losses? If banks are over extended in their loans, what fraction of their subprime loans are still in good graces? In other words, exactly how is the bad debt manifested? What is the true magnitude of the thing? How many mechanisms are available to bring this thing to a survivable landing?
It is not unheard of for a company to write off as much loss as it can if it is inevitable that it must report losses. An MBA friend pointed this out to me. He worked for a semiconductor firm whose habit was to maximize the losses if it could not avoid reporting a loss. They’d throw some of the ugly furniture overboard with the trash to clean house. To what extent is this happening now?
Maybe we can raise the bar a bit by helping to ask better questions. The best questions get the best answers.
There are many ways to live a scientific life in chemistry. The obvious examples are the lives of chemistry faculty. A chemistry prof’s time is split between teaching, managing a research group, grant writing, committees, giving seminars, academic advising and, oh yes, a home life.
In industry, the life of a scientist can be split between several layers of applied research, management of a budget and directly reporting staff, occasional patent work, meetings, writing reports, and if there is a spare minute, leafing through a journal.
I could have never anticipated the job description that I now hold. The specifics aren’t important for the purpose of this essay. What I want to describe is the extent to which I am constantly juggling numerous diverse, often intractable, open-ended tasks. It dawned on me recently that my job description sets me up for a career of dealing with thorny problems that few want and could or would handle.
Is this shameless self-admiration? No, it’s really a kind of lamentation. It would be nice to do something straightforward now and then. I used to do the advertising. Then we got back the C&EN survey results. I don’t do the advertising anymore. I’d like to meet a few of those rotten commenters … \;-)
Because I share office space with the accounting group, I have the chance to lunch and banter with the bean counters. It doesn’t take long to realize that theirs is a life of well defined tasks with built in cross-checks and monthly cycles. These accountants have their work cut to size and funneled to them by highly formalized and structured norms. Their job is to enforce consistency and eliminate surprises. They express discomfort and fear near the boundaries of their knowledge.
In contrast, scientists are people who seek out the boundary waters of knowledge and actually set up camp there. A scientist is someone who finds a way to acclimate to a life of uncertainty. A scientist knows that ignorance and uncertainty can be ground down with hard work and a bit of luck. Luckily for me, dogged persistance can partially make up for the lack of genius.
But despite the high minded platitudes about the endeavor of science, I’ve come to appreciate washing glassware and cobbling together a plumbing solution to a problem with an apparatus exactly because it is so concrete. Unlike molecules, I can actually see the results of my plumbing handiwork of compression fittings, steel tubes, and rubber hose. Sometimes it is nice to leave the abstract behind and make something simple but sturdy.