Category Archives: History

M.S. Kharasch, Merthiolate, and Autism

One of my most prized books is a tattered copy of Grignard Reactions of Nonmetallic Substances, by M.S. Kharasch and Otto Reinmuth, published in 1954 by Prentice-Hall.  It is a 1384 page tome containing a vast number of examples of Grignard reagent chemistry and reaction chemistry with extensive references through 1954.

Morris Selig Kharasch was a professor at the University of Chicago and is primarily known for his work with free radical chemistry.  To Kharasch is credited much of the early work in sorting out the mechanism of anti-Markovnikov addition of HBr to olefins. Reinmuth was the second Editor of the Journal of Chemical Education (1933-40).  Two coworkers, Frank Mayo and Cheves Walling, went on to make contributions toward the development of vinyl polymerization.

Later in his career Kharasch turned to the examination of the Grignard reagent and many of its reactions.  Among the list of his students and post-docs are H.C. Brown and George Buchi.  Kharasch was instrumental in the founding of the Journal of Organic Chemistry and served on the Editorial Board for many years.

It is interesting to note that Kharasch is credited with the patenting of Thimerosal in 1927, a product also known under the trade name Merthiolate which has been used as an antimicrobial additive in vaccines.

Wohler’s Urea

Over at A Synthetic Environment you can find an extensive collection of portraits of Friedrich Wohler. It’s pretty cool.  For you historians of chemistry, Wohler was a colleague of Justus von Liebig and a student of great Jons Jakob Berzelius.  After his inadvertant synthesis of urea in 1828 and subsequent realization of its significance, Wohler reportedly told Berzelius

 “I cannot, so to say, hold my chemical water and must tell you that I can make urea without thereby needing to have kidneys, or anyhow, an animal, be it human or dog“.

I do not have a primary reference for this quote, but true or not, it’s a great line.

Farewell, Cutty Sark!

Th’ Gaussling is still reeling from the news from London that the magnificent tea clipper, the Cutty Sark, has burned.  This great wooden vessel was dry-docked in or in the vicinity of Greenwich, England. 

Officials connected with the ship stated that “This is a significant blow and a major set back for the ship.”  Well, yeah.

Perhaps the ship can be reconstructed and the duplicate put in place.  Who knows? What a bummer.

Yet another mass shooting in our USA

The news of the mass shooting at Virginia Tech just seems to get worse as the day wears on.  There aren’t words to describe it. 

After the grisly scene in Blacksburg is cleaned up and the bodies are buried, we’ll once again switch on the TV and watch programming glamorizing gun-toting tough guys and violence. Not a night goes by on television where some plot isn’t based on the menacing of women by crazed or angry men, most with guns.  Some people will solve problems with guns and others will cause problems with guns.  The message is that guns bring satisfaction and command respect. Just look at the very title of the series The Sopranos and listen to the lyrics.  “Woke up this mornin’ and got myself a gun …”

Maybe there is no causal connection between entertainment and what this shooter did.  But I cannot help but believe that the more or less constant exposure to violence in our entertainment doesn’t dull our sensibilities and lower our threshold for what constitutes acceptable behaviour.  Regardless, we have to start somewhere and cleaning up our tastes in entertainment is relatively painless.  We need to create less demand for this crude stuff.

Obviously, the shooter is responsible for the murders, not the inanimate steel mechanism.  But the common fascination we have with the gun and it’s stylized, even mythical, application means that this mechanical device has some kind of hold on us.  Its ease of use and its ability to deliver death from a great distance makes it possible for anyone to deem themselves a “warrier” for a few minutes.

We are horrified by such violence when it is real. But we entertain ourselves with painstakingly elaborate dramatizations of it.  We are gratified to watch fictional characters engage in gunplay with bad guys.  We cheer as fictional cops rough up suspects because, as we all know, bad guys really shouldn’t have rights. 

There is no mysterious or complex phenomenon to sort out here. Our American culture has a form of fragmented personality disorder with respect to gun violence.  I don’t know if it’ll do a damned bit of good, but we need to come down from the saturation level of violence in our entertainment and recreation. The first thing we must do is to remove a bit of the glamor of gunplay. 

We don’t have to give up our guns.  But we do need to develop a new viewpoint or an advanced ethos about them. We need new icons and archetypes.  It is time to retire CSI and The Sopranos as popular iconography.  We must find better ways to fulfill our self image and need for power besides being handy with a gun.  How do other societies do it?  Any suggestions??

Here is an interesting link to a rebuttal in the Daily Kos written by someone said to be from VT.

Katzenklavier

There are many amazing but obscure characters in history. One of them is the German Jesuit scholar Athanasius Kircher (1601-1680). Wikipedia has a nice writeup on this guy.  Kircher was one of these intellectually insatiable fellows whose curiosity knew few boundaries.  While chemistry or alchemy was not a mania of his, he did publish works on geology, Egyptology, and music theory. Among many other acomplishments, he was an early proponent of hygienic practices to prevent the spread of infectious disease.

Curiously, Kirchner set forth what must have been an improved version of the Katzenklavier, or a Cat Piano.  This lamentable instrument was described as early as 1549.  Thankfully, he doesn’t appear to have actually built a working model. The cat piano was an apparatus wherein an “octave of cats” were selected by the timbre of their meow. They were thus arranged in a mechanical contrivance that would hammer or pull their tails to elicit a painful, though harmonious, yowl when the “artist” pressed a key. 

Kids, don’t try this at home.  It is an oddment that should remain in the remote past.  Though I am a cat fancier and the thing is obviously cruel, I can’t help but snicker a little at the thought of it. It is just so … Monty Python.

Civis Romanus Sum

I am a Roman Citizen- Civis Romanus Sum. A friend sent along a link to a NYTimes article by Robert Harris, drawing certain parallels between the attack on the Roman port of Ostia in 68 BC and the 9/11 attack-

“The incident, dramatic though it was, has not attracted much attention from modern historians. But history is mutable. An event that was merely a footnote five years ago has now, in our post-9/11 world, assumed a fresh and ominous significance. For in the panicky aftermath of the attack, the Roman people made decisions that set them on the path to the destruction of their Constitution, their democracy and their liberty. One cannot help wondering if history is repeating itself.

Consider the parallels. The perpetrators of this spectacular assault were not in the pay of any foreign power: no nation would have dared to attack Rome so provocatively. They were, rather, the disaffected of the earth: “The ruined men of all nations,” in the words of the great 19th-century German historian Theodor Mommsen, “a piratical state with a peculiar esprit de corps.”

The article goes on to detail how 38 year-old Gnaeus Pompeius Magnus (Pompey) contrived to obtain unprecedented and unchecked authority over the military and the treasury.  Harris goes on to describe what happened-

“By the oldest trick in the political book — the whipping up of a panic, in which any dissenting voice could be dismissed as “soft” or even “traitorous” — powers had been ceded by the people that would never be returned. Pompey stayed in the Middle East for six years, establishing puppet regimes throughout the region, and turning himself into the richest man in the empire.”

I don’t want to put too fine a point on the comparison, but the action by Pompey is considered by some to be the end of the Roman republic.  Harris goes on to say- 

“In truth, however, the Lex Gabinia was the beginning of the end of the Roman republic. It set a precedent. Less than a decade later, Julius Caesar — the only man, according to Plutarch, who spoke out in favor of Pompey’s special command during the Senate debate — was awarded similar, extended military sovereignty in Gaul. Previously, the state, through the Senate, largely had direction of its armed forces; now the armed forces began to assume direction of the state.

It also brought a flood of money into an electoral system that had been designed for a simpler, non-imperial era. Caesar, like Pompey, with all the resources of Gaul at his disposal, became immensely wealthy, and used his treasure to fund his own political faction. Henceforth, the result of elections was determined largely by which candidate had the most money to bribe the electorate. In 49 B.C., the system collapsed completely, Caesar crossed the Rubicon — and the rest, as they say, is ancient history.”

History does not repeat itself, but particular scenarios seem to recur.  Power, once granted to a leader, is seldom returned to those who abandoned it.  US Senate bill 3930 sets a bad precedent for our republic. I believe that too much authority is granted to the executive branch in the bill. Something as fundamental as habeas corpus should be treated like national treasure.