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Thus Begins Cold War II

Russia celebrated a holiday recently with a large scale military parade on Red Square. Just like the bad old days. Putins sock puppet, President Dmitri Medvedev, smiled while Putin stood stern-faced at his side at the annual Parade of Hardware.  Insiders claim that Russia’s effort to modernize its military forces is anemic and plagued with corruption. Putin and followers are plainly appealing to that voice in the Russian soul that longs for strongman leadership.

China, on the other hand, is quietly constructing a secret underground nuclear submarine base on Hainan. Hmmm. A secret underground lair. Sounds like Dr. No.  I doubt there are miniskirted nubiles with machine guns. Bummer.

Whereas Russia is fighting infrastructural inertia in its return to the platform, China is methodically ramping up its military with an economy flush with cash. With funding from its exports of Wal-Mart inventory and other Cheap Plastic Crap (CPC) marketed through its many outlets in the USA, China is moving closer to a blue water Navy and an SSBN fleet.

In the next 20 years, we are likely to see China flexing its muscle by positioning naval (carrier ?) groups and hints of Chinese submarine fleets prowling the continental shelves of the world.  Just like us.

While the USA shadow boxes with multiple terrorist threats around the world, China plods forward minding its own business and funding its own growth.

Four US presidential terms were squandered following the fall of the Soviet Union- 2 x Clinton and 2 x Bush.  US efforts to engage Russia in economic cooperation were weak at best. The highlight was perhaps the downgrading of Soviet era nuclear materials.  Instead of building friendships and trade cooperation, US presidents were distracted by faulty nation building exercises and dubious foreign adventures. Mikhail Gorbachev himself recently lamented that “… every US president has to have a war…”. 

US government needs to spend a 4 year term focused inwards. We must address US infrastructure as eagerly and aggressively as we land troops on the sandy reaches of the earth. The US needs an upgrade in electrical power distribution, bridges, its rail “system”, and its ports.

Collectively, we must find ways to keep factories and businesses in the USA. We need to reconsider the structure of the Code of Federal Regulations. Our regulatory structure is now so complex and extensive that we face the real risk of killing innovation. Our tax code is too complex and too burdensome on citizens and businesses. The government is funding far too many activities.

In short, the USA must get back to basics. The country is in a existential crisis and we need to get grounded again. We need fewer rules in our lives, not more. We need fewer people telling us how to live an authentic life. More of us need to spend a bit more time in the pursuit of happiness.

Limbaugh Promoting Civil Dishonesty

If most of us had a dog that behaved in the unwholesome manner that radio entertainer Rush Limbaugh does, we would have it euthanized at the humane society. Limbaugh of course is the GOP’s grotesque and doctrinaire cartoon character and resident mad dog.  Limbaugh has been promoting the idea that conservative voters slyly vote for Hillary Clinton in the primaries so as to aid her delivery to the electorate for the general election as the Democratic candidate. As the thinking goes, this will polarize voters and drive panicked undecided or inactive voters to the polls like nails to a magnet to vote for whomever the opposing party offers.

Voting is one of the most important acts we commit as citizens. To soil it with cunning and subterfuge in this manner is to disfigure ones standing as a citizen. It is simply wrong and Limbaugh should be widely condemned for his part in it.  I’m thinking tar and feathers. Or, tar and packing peanuts.

On Industrial Lab Procedures

I often find myself performing synthetic preps written by others. Some literature preps are useful and efficient. More than a few are not. Many preps thoughtfully convey important issues for the operator to make note of. But very often, writers of synthetic preparations assume that users in the future will be as knowledgeable of the handling issues as they are when the paper goes to press.

The writing style used in American chemical journals is usually a past tense, passive voice style where an exuberant first person voice is frowned upon. Writers of papers in the peer reviewed literature write in a tight, condensed form that favors efficient use of space.

In industry, lab preparations are very often extracted from the literature and applied to the preparation of research or commercial products. The common style used in published procedures is such that some level of skill is assumed by the writer for the reader.  This is fair. If one is combing the literature for preps, it is usually the case that the browser has a significant level of lab skills.

But in industry, or at least in the brackish waters I splash around in, a tight literature-style preparation may not be sufficient. In order to satisfy the needs of the company as a whole, health and safety data may have to be front and center on the writeup. Proper personal protective equipment requirements must be posted, and HMIS, MSDS, and labeling data is included.  

To satisfy the cost accountants, a time and materials list might have to be tabulated in a way that makes sense to accountants. The regulatory folks need to know about air permits and TSCA status. To satisfy the Quality Assurance/Quality Control folks, lot traceability for raw materials, intermediates, and products must be defined and immortalized with a firm paper trail. This is done in the form of part numbers, certification data, inventory locations, lot numbers, and order numbers. 

A prep document itself can be a permanent record of what was done. It can be used to document the management of change. A prep document itself can be used to provide documentation in place of a lab notebook.

But most importantly, a prep document will be used by other chemists. Possibly those of a lower skill level. So it is crucial that key information is immortalized. Ambiguity must be wrung out like rinse water from a towel. Key art must be set forth, but non-critical actions must be written in such a way as to allow discretion by the operator. Overly rigid instructions restraining trivial aspects are merely burdensome and unduly constrain the operator.

Writing a procedure is a kind of brain dump. It is a disclosure of all of the art necessary and sufficient to perform an operation. For a company, a procedure is company treasure and should be jealously maintained as such.

The business of bringing a new product to market is a lot like putting in a new town along the frontier rail line. You have to build the tracks to get there. You have to haul all of your materials and skeptical people to this promised land. Once there you have to decide what goes where and who will do what. Always you must have buy-in from the settlers. Much time, energy, and acrimony goes into the progress toward the finished good. At any given moment funding can be pulled, sending everyone home and leaving you with a ghost town. A mere memory of what was and what could have been.

A well written lab prep contributes to this settlement in the new land of opportunity by providing structure and a foundation from which to build.

 

 

Scalia Speaks

There was an interesting interview of SCOTUS Associate Justice Antonin Scalia on MSNBC by Tim Russert. The normally reclusive Scalia is on a media circus tour touting his new book Making Your Case: The Art of Persuading a Judge.  Like Lao Tzu or Machiavelli, Scalia is revealing his innermost thoughts on how to behave.  The comments submitted on the Law Blog are interesting. Snarky, perhaps, but revealing.

Scalia said an interesting thing in the interview. He opined that too many of America’s best and brightest are drawn to the legal profession. He conceded that the field of law is fundamentally unproductive and that to have so many bright people drawn to it was a waste of talent that could be applied more industriously.

Regarding the Bush v. Gore matter, we’re advised to “get over it”.

A Fly in the Ointment. A Chemist Among the Astronomers.

This is a re-post of a 2008 seminar I attended by speaker Dr. Carolyn Porco.

28 April, 2008. University of Colorado at BoulderDr. Carolyn Porco of the Space Science Institute gave a public lecture at CU Boulder on the highlights of the Cassini Mission to Saturn. Porco gives a lively presentation and- dare I say it- is mildly charismatic. The website of the imaging group, ciclops.org, is quite well done and even includes downloads of many of the papers from the team. The paper on Enceladus is particularly interesting.

As a chemist sitting anonymously in a crowd of space science enthusiasts and professionals, I cannot help but compare the tenor of the experience to my own field of chemistry.

Space science people are funded in proportion to the general public enthusiasm for space.  The universe is big. Really, really big. And it is full of breathtaking scenery and wondrous objects. Space science almost always causes people to experience a deeply emotional sense of awe and wonder. This has not been lost on the space science community. The display of majestic photos with a bit of space music in the background goes a long way to rally public support.

Chemistry on the other hand, rarely induces this kind of raw response from the limbic system.  Whereas chemistry induces shock, astronomy induces awe.

The most common exhortation made on exposure to the chemical sciences is “How in the hell am I going to pass this course?”

Students take intro to astronomy classes as an enjoyable way to get their science credits. Students take chemistry because they have to. We all know this. Science aversion is even more extreme for the poor sots in physics.

The SI unit for humility is the “sagan”.  Public astronomy talks usually have a high sagan factor. I would estimate last nights talk was 8.5 out of 10 sagans.

Of particular interest to Porco was the Saturnian moon Enceladus. This moon has substantial water on it with evidence of “tectonic” activity on the uncratered surface. On closer inspection, it is apparent that this body is spewing water into space with fair vigor. Indeed, a vapor torus of water tracing the orbit can be seen on some of the images. The suggestion is that there may be liquid water under a water ice crust. IR images show hot spots that coincide with surface fissures on Enceladus.  This moon would be a good place to land some drilling equipment.

Porco spoke of the hope of eventually finding life on Enceladus or on Jupiter’s Europa. She suggested that this would finally “break the spell” and allow the assumption that life may be relatively common on worlds with liquid water.

What this kind of planetary exploration affords are insights into the evolution of planets and ultimately, what circumstances are likely and necessary for the ignition of life.  But the circumstances that promote life formation are chemical in nature. The origin of life is not an astronomical problem. It is a chemical network problem and for that we need the involvement of chemists.

Oligarch Council of the United States

As if further proof of my true tediousness was really necessary, Th’ Gaussling will disclose to the world that I log a fair amount of odd-hour time watching C-Span 1 & 2.

Saturday morning’s broadcast bonanza was a re-airing of an earlier awards gala put on by the Atlantic Council.  Among the illuminati doling out awards was “Henry the K”. Yes, the venerable Henry Kissinger- Dr. Shuttle Diplomacy.

Arguably, among President Nixon’s gang of operatives, Henry Kissinger was a towering and intimidating intellect. In the management of the Viet Nam “conflict” and the diplomatic opening of China, Kissinger was extremely influential in the Nixon Whitehouse. But unfortunately for Kissinger, he continues to be unpopular in some circles. Chile has invited him to answer some difficult questions. In his characteristic 20 Hz basso profundo voice, Henry has declined to visit.

Not a tall fellow, Kissinger stood on a stool behind the podium and read a glowing and heartfelt introduction for one of the Awardees- Mr. Rupert Murdoch. Mr. Murdoch was held out to the world by the Atlantic Council as an example of shining excellence in international business.  I can only guess that the poobahs and grandees on the awards committee, through the refractive lenses of their world view, somehow missed the profound global bastardization of broadcast news under the wing of News Corp. More likely, they do not see it as a perversion but rather a turnabout to right thinking.

As a compulsive channel surfer, I switched to the other C-Span channel just in time for proceedings of the House Judiciary Committee, chaired by the Honorable Representitive Conyers (D-MI).  Conyers was reading the riot act to the Director of the FBI regarding due process for members of the house during FBI raids.

After a few minutes of roasting the Director, the chair yielded to the Honorable Representative Smith (R-TX). Rep. Smith began by figuratively Kowtowing to the Director and then prefaced his comments by referring to a report from Fox News, that fountain of information plumbed by Mr. Rupert Murdoch.

That a senior member of congress would preface his comments by citing Fox News as a primary reference is surely telling of the reach of Rupert Murdoch into the political machinery of the USA. Of course, citing Fox News is not a new rhetorical habit of neo-conservatives. But the simultaneity of the Murdoch pageantry on C-Span 2 and endorsement of Murdoch’s Fox News as the Republican “Van Nostrand’s Encyclopedia” on C-Span 1 was at once fascinating and faintly anticholinergic in effect. Though certainly random, this overlap of Murdoch mania only brings into focus the influence this man.

Murdoch went on to opine on the stability of NATO, stating

“We must face up to a painful truth: Europe no longer has either the political will or social culture to support military engagements in defense of itself and its allies. However strong NATO may be on paper, this fact makes NATO weak in practice. And it means that reform will not come from within.”

Murdoch has turned his attention to the expansion of NATO. A member of the merchant nobility, Murdoch has said aloud what is perhaps already on the minds of policy makers. Expansionism. Western exceptionalism. Democracy through superior firepower. 

The spread of democracy is a good thing. And western culture has much to offer. But a US government with insufficient checks and balances is a dangerous thing. Especially when our petro-president is on a security binge and is driven by an autistic military /petroleum fixation.

 

Reality Check. Always Certain But Frequently Wrong.

One of the benefits of being a student is that there is always someone standing over your shoulder, watching the choices you make. In school you choices result in a score of some sort. Out in the world, your choices have bigger consequences than letter grades.

As in school, the Big Big World is always under time pressure. Better, Faster, Cheaper. There isn’t always time to deliberate on the global optimum solution. In industry, sometimes the choice you make is the first one that shows any promise. Experienced business people know that everything takes longer and costs more than you first realize. There is no substitute for an early start.

What results from this need to jumpstart a project is the failure to question your basic assumptions.  In chemistry, a person may slide into the seductive notion that you are an expert in a process and, of course, you know that your process will work on a particular analog. But, do you really?

Non-linear phenomena are particularly troublesome.  Or phenomena that are polynomial in description.  It is hard to intuit outcomes when terms that were previously small become dominant in the equation. There is no substitute for measurement. If you want to truly understand a thing, eventually you are going to have to make measurements and plot a curve.

Like a lot of people fresh from Grad School, I was sometimes an arrogant turd. Just ask around. Today I am much more cautious about my abilities and knowledge. Periodically I am reminded that intuition can fail. Like a 2×4 between the eyes.

While I can’t give details, I have had to drastically recalibrate my intuition about some things that I believed I had a handle on. It involved mass transport concepts. The separation of substances can be subject to constraints that aren’t so obvious to someone who has only been through the ACS-approved chemistry curriculum. An engineer might have looked at my circumstance and solved the problem in a New York minute.

But Th’ Gaussling had to learn the hard way. What else is new?

Panem et circenses

Why did the Democratic Party stretch the primary season over such a long period? What is the strategic value in this? Why does election season have to last so long? Don’t people ever tire of the relentless microanalysis? What will anyone really learn from the n+1th debate between Clinton and Obama?

The Romans had this figured out centuries ago- Panem et circenses (bread and circuses).  

In Police Custody- 416 CHildren.

I find myself conflicted about certain aspects of the recent raid on the Fundamentalist Mormon  compound in Texas.  The news reports say that 416 children have been taken into police custody.  Parents and lawyers have been matched up to deal with the gigantic mess that this has caused.

I am not an advocate of polygamy and I am certainly no supporter of Mormonism.  It seems to me that in all of the bizarre theology of Mormonism, the idea of Mormon polygamy isn’t a very large leap of strangeness from its core concepts.  But I digress.

What is outrageous about this event is that 416 children were taken from their home and parents and are being kept by the state of Texas, all on an anonymous phone call.  The accuracy and veracity of the caller may be spot on. But there is such a thing as due process.  The spectacle of a massive police raid resulting in the detention of children, even on clannish wingnuts like this group, should give a chill to all citizens.  The state is exceeding its bounds unreasonably. Strike that. I think that the State officials just do not know what they are doing.

Never attribute to malice what you can first explain by incompetence.

There may very well be a complete absence of resources or protocol for this circumstance. So, the Texas state legislature needs to meet to contrive some sort of consensus and policy in regard to response to the welfare of children in communal living. Some advanced thinking is needed here.  Remember Waco? 

The state turns its head the other way in regard to the plural marriage of old men to minor girls. It needs to look straight at this circumstance and deal with it. This is a conflict between the two magisteria that oversee marriage- religion and the state.  The Texas legislature needs to set clear policy that relieves law inforcement from having to interpret how existing law is to be enforced.

 

Filthy Lucre

As usual, Th’ Gaussling’s most interesting observations of the ACS meeting are of a proprietary nature and will have to go with me to the grave. Our student and professorly friends can expound openly on what lights their fires. The lusty satisfaction of compelling oratory in the darkened halls of convention centers is part of the reward for the cardinals of the academy.  Members of the merchant class have to be satisfied with better dining.

People who are involved in personnel issues often speak of an employees “deliverables” as their work product. For those lucky enough to be in the academy, the work product includes teaching young minds, conducting research, and participating in the dissemination of the results in the form of papers and conferences.

For we chemists who did the deal with the devil in exchange for filthy lucre, our performance is rated somewhat differently.  Our performance metric only includes some understanding of science. Once it is possible to begin understanding a thing, the task of transforming a process or material property into an item of value begins. An industrial scientist’s deliverables includes many tasks that guide the company toward its goal of profitability and reward for the shareholders.

The part of the brain that sees a stick on the forest floor that resembles a tool is the same part of the brain that scans a molecule and sees latent functionality. The extraction of value from a composition or a process is a complex anthropological activity. Product development is anthropological because it involves the use of tools and organizational structure to provide products or services that are exchanged between groups.  

An industrial science group has to isolate value in some material property and contrive to bring some product or service into being.  But to get it to market, the science tribe has to cooperate with those with other skills. Organizations often resemble a confederation of tribes who cooperate with complex rituals and methods of exchange.