It’s Mardi Gras Baby! I’m wearing my Mardi Gras beads- Are you?
Category Archives: Whimsy
Beatles in Space
NASA has announced that it will broadcast a 4 minute digital data stream toward the direction of Polaris, the North Star. The broadcast will originate from the Deep Space Network and will feature the Beatles song “Across the Universe“.
Again, NASA has neglected to solicit my advice. I would have suggested “I am the Walrus“.
Imagine an you’re alien sitting in a remote antenna site with headphones over your ear stalks when all of a sudden Day Tripper appears over the background noise. [I like the dancers- it’s just so 60’s]
Of course, when the signal is received on planet Pffthklct-3 many centuries from now, someone some sentient mollusk will have to clean up the signal and reduce it to audio to get the full effect of music. Doppler effect arising from relative motions between earth and “them” would affect the tempo, perhaps in comical ways. It would be tragic if hopeful listeners in the depths of space mistook it as a kind of Encyclopedia Galactica and henceforth tried to decrypt it while looking for some kind of blueprint of advanced technology a la Carl Sagan’s fictional piece “Contact”.
Though an audience is a long shot, it seems a fitting tribute to the Beatles and to NASA.
A Plurality of Moieties
I caught myself writing like a patent lawyer today. It was a little unnerving.
In the instant example … blah blah … the preferred embodiment … blahty blah blah … a plurality of moieties … blah blah … the said R group … yawn … including, but not limited to …
It is surprising how easy it is to fall into the style of writing that characterizes patent applications. It is easy to poke fun at our lawyerly brethren for this. But the stylistic manner and the use of precise vocabulary with elaborate sentence construction is the result of generations of bitter experience in court. A long time ago, lawyers figured out that you have to say precisely what you mean to get what you want.
Judges and juries have to arrive at conclusions based on something, so if your fate rests on their interpretation of ambiguous language, you may be in for disappointment. Precise language is meant to prevent misunderstanding and place rewards and liabilities where they belong.
For chemists who are busy inventing things, it is useful to actually study the form and the language in a handful of patents. This will give a sense of how intellectual property is actually staked out and claimed. It is useful for the chemist to provide some guidance to the attorney in drafting claims and maximizing the value of the patent.
I deleted the “plurality of moieties” in the final draft. Just couldn’t do it.
Linkography
A friend sent this hilarious Bill Gates movie link. Thanks JT.
When it all comes tumbling down, these are the first 100 things to disappear.
Interested in the Taxonomy of Logical Fallacies? I guess I should actually read this.
Just wanna know how damned dangerous blogging really is? Satisfied??
Farewell to Bobby Fisher.
Lookin’ to get rid of some of that Radwaste you’ve got buried in the back yard? Lots of links here.
Th’ Gaussling Caught in Breaking Bad
I don’t know how it happened, but Walt from Breaking Bad has found out about Th’ Gaussling. We’re gonna need lawyers, guns, and money.
Gaussling’s Curio Shop of Links
Ever notice how the seats in the gate waiting areas at the airport usually have arm rests next to every position? There is a reason for that. The Blog Architectures of Control, Design with Intent is devoted to the design of artifacts in our public spaces that encourage or discourage certain kinds of use.
The use of the apostrophe is detailed in this site. According to author, yours truly could be an actual moron.
Concerned that the government isn’t adequately monitoring schizophrenics?
I knew that Leonard Euler had a number, but I didn’t know he had a disk too.
Looking for something new in the Vampire genre? Try “the Nymphos of Rocky Flats“. The adventures of Felix Gomez, Vampire and PI. So far, friends who spent their careers at the Rocky Flats nuclear weapons plant near Denver have been strangely neutral on the book. I smell conspiracy.
Bis, Tris, Tetrakis
For many seasons, Th’ Gaussling was the keeper of part numbers and nomenclature in his village. Fellow peasants would stumble out from the dark and dank mines to plead for new part numbers and names for the new products. As always, outsiders are surprised to learn that this is an actual “job”, but in fact it is. When you make new stuff, eventually you have to call it something. And what you call it has to be recognizable to the barbarian tribes outside the walls.
Peasants and grandees alike would take the names in gratitude for the everpresent fear was that they themselves would be called to toil in the muck of nomenclature as I have.
The dark world of nomenclature is split into two hemispheres- IUPAC and CAS. I don’t know what the deal is with Beilstein. It seems to be a sinking ship with a few deckhands polishing the brass knobs as the bow submerges. Arguably, CAS has become the default system for nomenclature and identification in much of the world. The CASRN is increasingly the standard for unambiguous substance identification. The US EPA relies upon CAS to keep track of the TSCA inventory. Chemical sellers all over the world rely on the CASRN system to identify products and as a search term to attract internet search engines to their websites.
The major problem that I have encountered is that nomenclature from the 9th collective index (9CI) is often incompatible with our accounting system. The system does not accomodate Greek letters (kappa and eta) and the numbering system leads to sorting and format problems with list generation and subsequent retrieval. The complex system of numbering schemes and nested hierarchies plays havoc with the system as well, if for no other reason than the character count exceeds what is permissable in the data field.
Even more troublesome, the complex names are largely inaccessable to non-chemists. It is very hard for administrative assistants and temps to comprehend accounting data when they are fundamentally unsure of what the identity of the product is and why various materials show up in the bill of materials. To non-technical folks on the business side, chemical names are often just a complicated character string that is prone to data entry errors.
I’ll have to admit that nomenclature from earlier indices (6CI to 8CI) is often more user friendly in this regard. So when it is time to choose a name, 9CI doesn’t always win. This is a propagation step in the retention of obsolete nomenclature and I am guilty as hell of keeping it going.
Unhappy Chemicals
We all have experiences with chemicals that stick in our memory. Experiences where we have witnessed just what chemical potential really means. Proton or electron transfer can be downright frightening sometimes. Rude and abrupt phase changes or angry exotherms. Sometimes nature rages back at our feeble attempts to take the dragon out for a walk on a short leash.
I can name many exciting materials, but I think that chlorosulfonic acid is one of the more exciting and obnoxious substances that isn’t explosive or neurotoxic. What are your favorites?
Wherein Gaussling Pontificates on Ridiculous Events
Th’ Gaussling holds a peculiar view of the theory of the universe. In addition to quantum physics and the big bang, I maintain that the universe will continue to exist until every ridiculous circumstance that can exist eventually does exist.
Accordingly, Th’ Gaussling is personally responsible for ratcheting the universe a few notches closer to its eventual doom. That is my frank admission. Here are a few examples:
Exhibit 1. Forklift-Boat Collision. As a young lad I spent a great deal of time at our family business. My father and grandfather had a metal fabricating company that specialized in the manufacture of farm implements. As a result, the precocious young Gaussling learned to use power tools at a very early age. By age 12 I could perform arc, gas and spot welding; operate a variety of brake presses and heavy duty shears; layout; a small amount of blacksmithing; and operate a fork lift.
One day inside the plant the 13-year old Gaussling was joy riding on the propane powered forklift. The rear wheel steering with its short wheel base assured that the machine could turn on a dime, but it could be prone to over-steer in the wrong hands.
This day, turning around a corner just a bit too fast in youthful zeal I over-steered the turn and promptly over-corrected my recovery.
Unfortunately, the Pauli Exclusion Principle puts strict limits on how particles can occupy a given space and, as a result, the boat that was sitting on its trailer in the space I intended to occupy underwent an elastic Newtonian collision with the forklift. The boat appeared as though it would tip over from this collision, but for some reason it rocked violently and returned to ground state. All was well, except for a meter long gash in the trim of the boat.
Exhibit 2. Airplane-Dog Near-Collision. The clouds were scattered and the winds were light and variable. Th’ Gaussling was shooting touch-and-goes solo at the local airstrip flying a left-hand pattern on runway 29. Abeam the numbers on the downwind leg about 800 ft AGL I pull on the carburetor heat, chop the power to 1600 rpm, drop 10 degrees of flaps, and trim the airplane for 60 kts. This is the transition from flying machine to sinking machine.
“Longmont Traffic, Cessna 714 Yankee Bravo turning base for two niner.”
As I rolled onto base, I drop another 10 degrees of flaps, cut the throttle to about 1200 rpm, and dial in a bit more nose down trim. Things happen fast in the landing phase of flight and as soon as you get onto base you have to prepare to roll out onto final approach.
My favorite part of flying is landing. It is like ballroom dancing. The airplane becomes a part of the pilot and the two must deftly and with fluid-like motion arrange to kiss the wheels onto the ground.
Coming over the fence I chop the power to idle, and rely on my peripheral vision to give clues as to altitude. Coming over the runway threshold, I bring the nose up to level flight attitude (flare) and allow the machine to sink as airspeed bleeds away maintaining directional control with the rudder.
Just as I flare I catch a glimse of something ahead that boggles my mind. I can’t believe it! A dog- a black Labrador, to be precise- has wandered onto the runway dead ahead! Somebody’s darling doggie is about to get sliced by the propeller.
Here were my choices- 1) Plow through the dog, 2) attempt to steer around the dog, and 3) attempt to hop over the dog. By the time these choices are in my head, the airplane has touched down and we’re in the landing roll.
Since I had slowed down to “full flaps” stall speed, I was reluctant to hop the plane into the air in ground effect for fear of the subsequent drop to the ground. The dog was too close for acceleration with added power, so option 3) was no good.
Option 1) was highly undesirable for obvious humane reasons. But option 2) could easily result in oversteer off the runway at high speed in a 3-wheel machine full of 110 octane gas. This was no good either.
Instead, I opted for a combination of 1) and 2). I applied heavy braking while turning off center only slightly. I was not about to get injured trying to avoid this airdale that had wandered my way. If I hit the dog I would just have to deal with it. At the last moment, a black streak to port told me what happened.
I missed the dog.
Exhibit 3. Mercury Shower. Whether in production or on the benchtop, filtration is a problematic operation. Against ambient pressure, vacuum pressure is limited to a pressure differential maximum of 1 atm. For a minimally equipped fume hood, pressure above can be supplied by carefully holding your finger on the nitrogen bubbler and carefully applying pressure to the Schlenk filter. This way, the filtration time can sometimes be minimized.
One day in grad school, leaning inside the fume hood I was attempting to apply pressure to my filter flask by holding my finger on the exit of my mercury bubbler. At some point, the seal of my skin yielded to the pressure and the high pressure N2 shot mercury up through the bubbler, past my finger, where its trajectory carried it to the top of the hood. As it is prone to do, the mercurial fluid broke into a zillion tiny beads, many of which rained down upon my head. I could feel the delicate tapping impacts on my prematurely grey locks and my shoulders.
After the ritual spewing of foul utterances, not over pain or distress, but over the hazardous mess, I set about cleaning up the mercury spill in my space. I removed my shirt for disposal and shook my head until I was dizzy.
Hours later, I visited the university health office for a visual inspection of my scalp and ears. No point in delivering mercury to my pillow. The nurse was at first reluctant to inspect me, but relented if only to hear the story of why I was there. Later I was pronounced free to go home where I would lather-rinse-repeat all evening.
These are stories of circumstances that have advanced the universe 3 clicks forward in the net cosmic ridiculousness. This very post could be a 4th.
