Category Archives: Whimsy

Pitstops along the bloggenbahn

In the mood for PC board snack? The folks at Evil Mad Scientist Laboratories can provide a component by component guide to constructing a confectionary circuit board.  Heavens, they’re tasty.

Can’t get enough of Leonard Nimoy?  Well, here ya go. Knock yerself out.

Some excellent posts on the mortgage industry and Live Earth can be found on Clusterf**k Nation

I’m convinced that all chemists are pyro’s at heart.  I didn’t say anarchists or criminals, I meant Pyro in the technical sense of the word.   By 10 years into their careers, most synthesis or process chemists have experienced the awesome spectacle of the Mighty Exotherm at least once.  Significantly, 4th of July demonstrations never recreate celebrated lab explosions or hood fires.

A good BLEVE is a real crowd pleaser and a sight to behold. However, professional pyros choose the more cosmetic displays, ignoring the really elegant deflagrating ether ketyl still or the fabulous ozonide conflagration. I guess we chemists will have to keep those delights for our own enjoyment.

Late Night Thoughts on Twisters

Now that we are well into tornado season in North America, I thought I’d dredge this old post up out of the cobwebs in the dungeon. As Uncle Al pointed out in the comments, Middle Easterners did have dust devils so a vortex of wind was not unknown there. These, however, are no match for a full-blown F4 tornado.

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One has to wonder what the original inhabitants of North America thought of the tornado (how do you say “WTF” in Lakota?). I have visited a few museums in my travels but have never seen any artifacts or heard of any references to Native American perceptions of the tornado phenomenon.  Without a doubt, Native Americans were visited by tornadoes. The experience must have certainly left an impression. It would be interesting to hear any stories that may be out there.  An internet search just offers a Mulligan stew of hits with tired references to Pecos Bill or to the odd disaster in Kansas.

North America is climatically privileged in that there is the possibility that overland southerly flows of cold dry air from the north can readily contact flows of warm moist air from the Pacific, Gulf of Mexico, or the Atlantic.   Vertical mixing of unstable humid air results in convection cells that are further driven by the latent heat of condensation.  These humid flows are spun up by the coriolis effect and wind shear to afford monster anvil storm cells that can tower to 50,000 ft or higher.

Like many places, here in Colorado we often see lines of isolated storm cells in the early evenings of summer, red in color at low altitude changing to a billowy yellow-white at altitude near sunset. Very often you can see mammatocumulous features signifying violent mixing activity. It’s no place for an airplane.

It is interesting to speculate as to how our modern mythologies and iconographies might have been different if the tornado phenomenon had been common in the Mediterranean and the middle east.  Would Charleton Heston have summoned a tornado to smite Yule Brynner’s Egyptians rather than parting the Red Sea and drowning the buggers?  Perhaps the Pharaohs might have built great stone helices rather than oblisks.  Aristotle might have written a treatise on the handedness of helical flows or whether the air flowed radially into or out of a tornado.

If the tornado had been a common phenomenon in the middle east during the iron age would the “Big Three” Abrahamic religions today feature tornadic themes in their texts and monuments? If so, perhaps the great cathedrals of Europe might today have relief sculptures or stained glass windows portraying the Israelites or Philistines being driven hither and thither by the swirling wrath of the Almighty’s cyclone.

Well, that’s enough of that.

B-24 Liberator in the Morning Sky

This morning while on a pleasant bike ride through the countryside I chanced to hear a familiar rumbling noise.  Not seeing anything immediately, I stopped to look at a pony and a mule that had gotten loose from a pasture.  Moments later, over the cottonwood trees there appeared a B-24 Liberator flying overhead not more than 1000 ft above ground.  This is something you don’t see every day. 

Turns out that the owners of this aircraft were flying out of a local airport over the holiday selling $400 rides in this lumbering relic of another age.  Hell, if I could justify it to my wife, I’d have taken a ride too.

Rhubarbarita Organoleptic Trials

Th’ Gaussling has been a lazy blogger lately.  Life has been intruding into my blogging time. 

This weekend I’m gonna try ginnin’ up a batch of Rhubarbarita’s. Rhubarb is a good natural source of oxalic acid (for the uninitiated, that was a joke).

Being from the Iowegian belt of middle earth, I have a fondness for porkchops and rhubarb pie.  I know- it’ll kill me eventually. 

Rhubarbarita Update.  I prepared ca 500 mL of rhubarb juice for formulation experiments. To a stainless steel 2 quart pot was added ~500 g of rhubarb stalks cut into chunks ~2 cm in length and taken to a reflx in a 2:1 mixture of water:Karo corn syrup with a lid on the pot to help retain volatile flavorants.  The chunks were boiled for 10 minutes whereupon they began to disintegrate.  The stalks were crushed and the resulting slurry was separated via metal strainer. The greenish solids were discarded and the resulting cloudy pink extract was charged into a sealable container and refrigerated. 

The purpose was to obtain a rhubarb syrup suitable for formulation with various liquors, Tequila in particular. Corn syrup was chosen for sweetness and viscosity. Some observations from the organoleptic trials-

  • Rhubarb juice prepared in the fashion described (vide supra) has a low flavor potency with only a small amount of tartness. It has a distinct flavor and agreeable color, but does not jump out at you.
  • Rhubarb juice has little natural sweetness, so a sweetner must be added to provide the expected mouthfeel and sweet aspect worthy of a drink fitted with an umbrella.
  • The 2:1 ratio of water to syrup is not satisfactory in regard to sweetenss or viscosity.  A 1:1 ratio should be tried.
  • As the sole flavorant, the rhubarb extract is not flavor-intense enough or exotic enough to expect repeat consumption from foo-foo umbrella drink consumers when used for Margharita formulation.
  • A properly formulated Margharita on the rocks should have good mouthfeel with sweet and tart attributes as well as a jab of citrus in addition to the exotic agave flavor of the Tequila. 
  • The addition of lime juice was found to markedly improve the organoleptic test. 

In summary, the experimental Rhubarbarita described above was judged to have an acceptable flavor, though hardly exciting or memorable.  It was found empirically that the addition of fresh lime juice contributed substantially to the overall impact of the formulation. The impact of a “bottom shelf” Tequila for the experiment is unclear at this time.