Flux-O-Links

The US Nuclear Regulatory Commission website offers a downloadable set of documents pertaining to Fire Dynamics along with a few spreadsheets and loads of worked problems. The set of documents is quite well done in my estimation and is entirely suitable for we industrial chemists. My operating principle is that it never hurts to keep learning about fire phenomena when you work around flammable materials.

Gotten a little rusty in your welding theory?

An affordable spectrum analyzer is just what a fellow needs for the radio observatory.

Need pure Astatine, see p 19.  Light up the accelerator and dial up the proton current.

Empty Seat on the Carbon Bandwagon

Sometimes it is best to simply shut up and link to a superior post. This is such a time. In a recent posting, one writer, Harold Ambler, comes out against Al Gore in the global warming debate. While I am skeptical about his assertions on the effect of the solar flux on the earths geomagnetic dynamo, I think Ambler otherwise brings together quite a few good points I have seen elsewhere.

The ticket to my seat on the carbon bandwagon will soon post on Ebay.

Motoring on the Chao Phraya

Th’ Gaussling had the occasion visit Bangkok a while back. Like any large city, Bangkok is bustling with tourist operators anxious to provide carriage to any point of interest. Along the river you can see long boats fitted with automobile engines and long propeller shafts. The engine is attached to a swivel and a tiller arm with throttle controls. The engine fan blades spin without any kind of guard to protect the operator.

Muscle boat for Tourists

Muscle boat for Tourists

To steer, the operator simply pivots the power train and adjusts the throttle. These narrow craft shuttle their perspiring payload up and down the river from stop to stop at bridges and the finer hotels.

Spoolhenge

Unlike many of my colleagues in the Chemical Industry, say in New Jersey for instance, Th’ Gaussling is able to enjoy a pleasant country drive to and from work every day. Among the many sights to enjoy is Spoolhenge. This curious archeological artifact is thought to have been constructed by ancient electricians in the early Cupracene Age of the Sparkezoic Era.

Who were these people? What strange rituals did they perform in this maze of paleospools? Only a few crude wirenuts fashioned out of elk antler remain in the soil surrounding these ruins.

Writer and amateur paleophrenologist Anders van der Klopp suggests the ruins may have been part of a temple built by ancient astronauts who crash landed on earth in the distant past. Van der Klopp’s panspermia theory is not taken seriously by mainstream paleophrenologists who balk at the idea of electricians in space. Perhaps one day we will solve the mystery.

Spoolhenge

Spoolhenge

Microsoft finds new method to deposit eggs in host

A Microsoft patent application claiming pay-as-you-go computing has appeared. The claimed method will apparently allow you to pay for only the capacity and tools that you select. A commentary can be found on ars technica.

Imagine being a lab rat and watching the lab tech prepare a new type of surgical device for use on you. That’s about how I feel right now after hearing this news.

Pro-Stalin Sentiment Rising in Russia

The artless fools running our American federal government over the last 8 years have been substantially preoccupied with petropolitics and deconstruction of the goverment handed to them by the previous administration.  Leading up to the 8 Bush II years were 6 years of a conservative congress who paid more attention to the lurid and scandalous behaviour of Clinton/Lewinski than to the international scene.

Since the collapse of the Soviet Union in the early 1990’s, the USA has been internally preoccupied with: a pageant of neoconservative social engineering proposals; privatization of nearly everything; political consolidation of dominionist megachurches; impeachment of a president for lying about sex; a buildup of militarism following the 9/11 attack; attacking the wrong country (arguably) in response to 9/11;  the re-election of a president who has proven to be considerably less than useless; a global financial trainwreck; and, finally, the handoff of a platter of shit sandwiches to the next administration. What a time it has been.

And since the collapse of the Soviet Union, the USA has squandered its substantial goodwill and failed to summon international leadership by Presidents 42 & 43 in the constructive engagement of new Russia. Magic moments in history have come and gone, unused. In the mean time, Russia has experimented with capitalism in their unique way. But the experiment has not been much of a success.  So, Russia did what Russia tends to do- it has advanced strongmen into power. And they are KGB alumni as well. Golly, what a surprise. 

It could be that Russia might have been refractory to whatever help we might have offered. But we didn’t really try much beyond helping them decommission nuclear warheads.

So, now we see that Russian sentiment is falling back nostalgically towards Joseph Stalin- Uncle Joe. The government is actually confiscating materials archiving the atrocities of Stalin. The rationale is that Stalin made them a superpower, so his indiscretions and sins can be overlooked. Putin and Medvedev- king and rook- are gradually consolidating power the old fashioned way- they’re taking it under the blustering pretense of security. It’s like a game of chess. You advance enough pawns to get control of the middle of the board. Then you castle your king (Putin) and begin the projection of power across the board.

Chemical Art in the Public Domain

For the last few years I have been attempting to work with a full professor of chemistry who holds a named chair. He is fast approaching emeritus status and in addition to the other maladies of aging, he tends toward spontaneously bureaucratic demands and is rather hard of listening. His secretary types his correspondence which is written in the officious, pseudo-legalese tone remniscent of a 19th century divorce decree.

Recently, while discussing chemistry with the “judge” by email, I suggested that he look at the patent literature for clues to synthetic procedure. Procedures found in patents may have a general utility and are not automatically claimed. Minimally, a dip in the patent literature broadens ones knowledge of the prior art. Certainly, art found in expired patents has a high likelihood of being up for grabs.

My clumsy and sophomoric attempt at helpfulness sparked a multiparagraph recitation in reply on the anticipatory nature of content in patents and how “such material” is unacceptable for “we in academe”.

Suit yourself, says I. But like any prospector knows, gold is where you find it. And this brings me to a point.

Every week some number of US patents expire or lapse. This continuous stream of expiration represents a situation much like the periodic deposit of placer gold after the spring runoff.  Gold veins in the walls of the canyon spall and fracture allowing gold nuggets and dust to tumble into the creek.  Prospectors who know what to look for can pick up the occasional nugget of art that has fallen into the public domain.

Granted, expired art may be 17 years out of date, but many kinds of compositions and transformations in chemistry are not subject to the expiration of utility. Many kinds of oxidations, reductions, alkylations, halogenations, functional group transformations, etc., remain quite useful over time. What changes over time are the economic and regulatory compliance issues. It is possible to make C-C bonds without a platinum group metal, triflate, and boron.

The value of expired patent art is well known by the pharmaceutical industry. Pharma companies will fight like wounded bears to get extra days added to their patents or otherwise attempt to extend claimed art as far into the future as possible with formulation or other schemes. They know that the day after a cash cow drug goes off patent, there will be generic versions on sale by opportunistic producers.

Prior to June 8, 1995, utility and plant patents were allowed for a period of 17 years with the 17 year clock starting from the application date and the period of enforceability beginning on the issuance date. From June 8, 1995 onward, utility and plant patents are valid for 20 years.

It is in the nature of scientifically minded folk to be forward looking and lavish extra attention on the latest techniques.  In our enthusiasm for the new and exciting, we may forget the vast storehouse of knowledge accumulated over the last 100 years of chemical research.

There is an ever increasing store of public domain art at the patent office waiting to be extracted by those who have the interest to do so. If you do decide to adopt some expired art, it is worth paying attorneys fees to make sure your judgement is sound and to look for related patents that may be problematic. Due diligence is money well spent.

It is true that patents are written by lawyers with little interest in providing too much enablement to the public. But these lawyers also know that playing games with enablement is contrary to the intent of the sworn statements in the application and may ultimately weaken a patent during litigation. A patent isn’t a peer reviewed paper. But, to Phosita, it can be a rich source of clues on how to perform some particular expired art that may serve as the basis of a product or process.

Pushing Tin

While browsing MetaFilter I ran into a really nice Air Traffic Control simulator called ATC-SIM. This is a web-based simulator that requires no download to use. It captures the basics of ATC work. The amateur controller must maintain 3 mile horizontal and 1000 ft vertical separation at all times as well as coordinate the timely arrival and departure of aircraft thorugh the terminal airspace.  The controller must coordinate inbound traffic onto an intercept of the ILS glideslope beacon for the active runway in order for the landing clearance to result in a landing.

The default airport is O’Hare. It doesn’t take long to get a glimpse of the challenges associated with that airspace.  Traffic piles in and out rapidly and every aircraft is in motion.

Another ATC related website is ATC Monitor. This is apparently a feed from Atlanta. It is possible to view Atlanta Center radar as well as TRACON.  It is well worth visiting.

Th’ Gaussling’s home town is ~ 8,000 ft beneath an airway leading to Denver Int’l Airport. While driving home at night I frequently see bright cones of airliner landing lights stabbing through the clouds aloft. These light projections have a faintly cometary appearance.