Mt. Kraznydang Climbers Perish in Avalanche

5 July, 2008. Boulder, Colorado. The climbing community mourns today as the recovery of six bodies continues from the 2008 Mt Kraznydang expedition.  A makeshift morgue was set up in the capital city of Bleeny, in the Zapore Islands off the Kamchatkan coast near Gnoyniechok, Siberia. The international climbing team was lead by Gon Anandachopbalmanchoda, well known Thai explorer, climbing apparel designer, and raconteur.

Mt Kraznydang is the tallest mountain in the Podguznik range in the volcanic Zapore island chain. Also known as Stalin’s Carbuncle, 33,459 ft Mt Kraznydang has resisted several attempts at its summit since its height was revised in 2005 by satellite radar, making it the second tallest peak on earth.

The Anandachopbalmanchoda team was reportedly near the summit when an earthquake loosened a bank of snow, bringing the team careening down to the 9000 ft level in the avalanche. The last radio transmission was from an unidentified climber who exclaimed ” … Oh, for Petes sake!! … Son of a(garbled) … refund! (static)….”.

Bleeny is the Sister City of Boulder, Colorado. Services will be held at the Podguznik Mountaineering Center on the Pearl Street mall. Donations are appreciated.

Dinner, a movie, and fireworks

It is our custom to view the fireworks show from a certain spot. It is not the best possible spot for viewing. It is a very convenient spot, however. Th’ Gaussling has a deep aversion to crowds. Near the local fairgrounds where the fireworks are launched is a movie theater. We park near a grassy spot and then go to the 7 pm showing so that, when the movie is over, we just stroll out to the grassy spot and wait 15 minutes for the fireworks to begin.  Last nights movie was “Hancock“. 

My subjective and after-the-fact test for the value of a movie is this binary criterion- is it worth a regular admission ticket, yes / no? In the case of Hancock, I would say yes to the ticket. I would caution that it may not be worth an additional US$14.75 worth of soda and popcorn.

On the other hand, I would say that Wall*e is worth both the price of a ticket and an obscenely priced coke from the snack bar. But continue to sneak in the Milk Duds.

From NIMBY to BANANA

The 2005 government report entitled Peaking of World Oil Production: Impacts, Mitigation and Risk Management, by Hirsch, Bezdek, and Wendling, is a sobering tally of the current picture of oil production and consumption in the world today. Often referred to as the Hirsch Report, the authors take a “now shot” of the global oil production scene and speak directly to the matter of mitigating the approaching economic disruption that must usher an unprepared nation into a future of peak and declining oil production.

If you read the Hirsch Report and pay attention to current events, you may be gripped by a kind of cognitve dissonance, or a haunting sense resembling a schizophrenic episode of contradictory voices in the collective consciousness.  While the global warming showboat is paddling up and down the Mississippi blowing steam and calliope music, nationalized oil producers are failing to answer calls for increased production in reply to a dramatic ramp-up in petroleum demand. Some call for increased exploration and others call for drop in replacements for petroleum. All the while, evidence accumulates that the ecosystem suffering from consumption and waste generation.

As with any discussion involving economics, it is possible for people to speak imprecisely when discussing supply and demand. Econobrowser takes Hirsch to task in this manner. It seems that many of us confuse demand with desire.

Supply equals demand today, supply will equal demand in 2025, and supply will equal demand in 2050. Whatever Hirsch means by “peaking of world conventional oil production,” it certainly isn’t the condition that “production will no longer satisfy demand.”

Our news media, now almost fully morphed into a perverse mix of gibbering Bill O’Reilly clones and entertainment news programming, prattles endlessly about the hurtful gasoline prices and truncated vacation plans. Government makes flatulent noises about more drilling, but hardly a peep about reduced consumption.  Where is the journalist corps? Who is asking the tough questions?

In isolation, either climate change or an exponential oil shock are more complex than nimrods leaders in the Bush administration can process. Together, these stresses add up to a major challenge to the way we live.  Maybe the situation is more complex than any nation can reasonably respond to. With global prosperity comes global demand for resources.  Western nations have built a house of cards based on cheap petroleum. Instead of wage growth in the past 20 years, we have been given easier access to credit. Instead of increased savings, we have found ways to burn up discretionary income.

A major part of what has to happen to adapt to the new reality of petroleum scarcity is a remodel of our infrastructure. We need more passenger rail lines and terminals with the necessary right-of-way issues taken care of. Workers need to live closer to their place of employment. The airlines have to figure out how to operate profitably with reduced passenger miles. We must upgrade our electric power distribution system to accommodate the increasing reliance on electrical energy. If wages do not change, we must adapt to having less discretionary income to spend. 

But a remodel of infrastructure will require that we adapt to living nearer to it. In the past, a proposal to build a power plant is met with a chorus of outrage or “concern”. It used to be called NIMBY- Not-In-My-Back-Yard.  The latest acronym is BANANA- Build-Absolutely-Nothing-Anywhere-Near-Anything. New power transmission lines and generating plants will have to go up and it will have to happen somewhere. People naturally fret about real estate prices and their view from the dining room window. I foresee more exercise of eminent domain in the future.

July 4th, National Explosives Day

The one day of the year when it is acceptable to discharge fireworks and openly show a fascination with all things pyrotechnical is July 4th, National Explosives Day.  This day of national deflagration and detonation comes only once per year outside of Disney themeparks.  For our pious environmentalist friends, there is even a green fire available for a more righteous, earthy, celebration.

How to pass organic chemistry

WordPress shows the blogger what search terms lead the searcher to your blog. One of the searches that lead a reader to this blog was “How to pass organic chemistry”.  Here is my answer-

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Flying Barn Door

There is an old saying in aviation that “with enough horsepower, you can make a barn door fly”.  A friend recently gave me a copy of Principles of Flying, McGraw-Hill Book Company, 1943, published under the authority of the Bureau of Aeronautics, US Navy. I couldn’t resist posting this graphic from p. 88.  [I hope this comes under fair use doctrine of Title 17 Section 107.]

Cartoon of a barn door taking flight.

The older aviation training manuals were often written in an avuncular voice that would appeal to farm boys. This Navy manual on flying takes the reader through the basics of Naval aircraft construction as well as aerodynamics. Floatplane construction and controls are particularly well illustrated.

My first airplane ride occured when I was 6. We went to a pancake flight breakfast in an airport hangar in Boone, Iowa. There, somebody was giving airplane rides for a penny-a-pound. This was a bargain price even then. I recall that the event was connected with the Flying Farmers.

My father had a pilots license and as did my cousin up the road. Cousin Verlyn had a Cessna 170 tail dragger that he flew from a pasture on his farm. One day on the rollout after landing he rolled into a pool of standing water, flipping it over and bending the main spar. It never flew again.

Though my mother worked on her license, somehow she didn’t take the flight test. This was in the early 60’s and manned space flight was all over the news. Americans were going places and to see my father riding with a friend in his Stearman doing aerobatics over our cornfield could only mean to a small boy that somehow, we could be a part of the big adventure.

My first and only ride in a Stearman during the Stearman fly-in in Galesburg, IL.

1950’s Chemistry

I recently spent some time listening to an acquaintance talk about his days as a student at MIT and as a grad student at Harvard in the early 1950’s.  He had Geoff Wilkinson for inorganic chemistry at MIT as an undergrad and later did his PhD with Wilkinson at Harvard.  Curiously, Wilkinson did radiochemistry in the Manhattan Project prior to joining academia. His radiochemistry experience compelled him to work fast and in test tubes, according to my friend.

My friend’s lab mate in Wilkinson’s group was Al Cotton. They started grad school together ca 1952 or so. This was shortly after the sandwich structure of ferrocene was proposed by Wilkinson’s fellow Harvard prof R. B. Woodward. Woodwards basis for this structure was on symmetry and a single IR stretch absorption. Spectroscopically, the original sigma bonding model didn’t fit the data.  Just prior to this, Wilkinson had begun work on a variety of organometallic Cp compounds. As the story goes, when Woodward expressed interest in making more Cp compounds, Wilkinson went to his office and “had words” with Woodward. Afterwards, Woodward moved on to other things.

My friend laughingly recalls the time he was chewed out by his P-Chem prof, the great George Kistiakowski and earlier, by Arthur Cope at MIT. He recalls being summoned to Cope’s office. Cope was wearing pink slacks which contrasted with his red hair. He was displeased about the impertinent back channel invitation my friend pitched to Linus Pauling to speak to the chemistry club. (I haven’t verified the color of Cope’s hair)

My friend recalls having E. J. Corey as a lab assistant while in an undergraduate lab at MIT. He joked that he saw Corey once at the beginning of the term and once at the end. My PhD advisor, Al Meyers, did his post doc with Corey some years later. Small world.

 

Preparation of Iodonium Tetrafluoroborates

An interesting bit of chemistry was published by Berit Olofsson at Stockholm University in a recent JOC. The Olofsson lab has previously produced a method for the one-pot preparation of diaryliodonium triflates. This latest work provides diaryliodonium tetrafluoroborates (JOC, 2008, 73, 4602-4607). 

The preparation of I(III) compounds usually starts with an Ar-I compound undergoing oxidation followed by an electrophilic addition/substitution to another arene. Regioselectivity is obtained by choosing a donor with a leaving group such as a boronic acid, stannane, or silane.

What is clever about this process is the fact that a BF4 salt is directly produced. Two equivalents of boron trifluoride etherate are used in the reaction which evidently results in some kind of disproportionation producing the BF4 counter-anion. 

It is known that the reactivity of iodonium compounds is somewhat sensitive to the coordinating ability of the counter-anion, so BF4 is less undesirable than other choices (like chloride). Solubility is greatly influenced by the choice of counter-anion as well. This is particularly true in photo-initiator applications where the choice of carrier fluid may be limited.

A statue celebrating the bronze enema bulb

According to the Novosti News Agency, the Zheleznovodsk spa center recently unveiled a statue celebrating its emphasis in hydraulics.

Photo Credit- AP

“As gastroenterology is the main treatment area at the Zheleznovodsk spa center, it was decided to create such a unique monument, which is both funny and vital,” said Alexander Kharchenko, the director of the center.

“There is no kitsch or obscenity, it is a successful work of art,” Alexander Kharchenko told The Associated Press. “An enema is almost a symbol of our region.”

Lordy. I thought some town in Tejas owned the rights to that symbol!

In case you’re sketchy about the location, it’s just off the M-29 north of Pyatigorsk. Looks like there is an airport in nearby Mineral’nye Vody. It’d be a good reason to burn up those Aeroflot frequent flyer miles.

The juxtaposition of children, balloons, and shapely nurses in a celebration of the enema bulb seems most peculiar and is a major source of conflict for my brain at many levels.