Contrarian Views on Corn-Based Ethanol

If you travel through the American midwest, you cannot help but notice that corn-based ethanol is in the news. Over at the Oil Drum blog there is a good post on the merits of corn-derived ethanol (EtOH).  One of the important points that was made is that EtOH will be replacing MTBE as an oxygenating additive. This is an important point. For the near term, as MTBE is phased out EtOH is taking its place.  Therefore, the net effect on imported oil volumes may be nil. 

Then there is the matter of the energy balance for EtOH production.  There is no clear consensus on whether or not corn EtOH production is a net gain in BTU’s.  And then there is the matter of unintended consequences in shunting large mass flows of corn into energy production.

Modern agriculture has been characterized as the process of converting diesel fuel into food. High yield crop production also requires large machinery for efficient cultivation, soil amendments, advanced corn breeding, crop rotation, and specialized pesticides.  And this is just the farming part. Modern grain production requires substantial distribution infrastructure as well as financing for the upfront seed and fuel costs.

By unintended consequences the writer of the Oil Drum post means the possibility of ecological insult resulting from intensification of corn production.  Intensified corn production may result in reduced soybean production in the US, resulting in increased production in Brazil. US farmers may simply choose to grow fewer soybean acres. Increased soybean production in Brazil could result in accelerated deforestation to meet the demand uptick. 

What the writer did not mention is that reduced US soybean production could mean reduced crop rotation, placing increased demand on synthetic ammonia (NH3) production to make up the demand for fixed nitrogen.  Ammonia production uses natural gas (CH4) as the source of hydrogen, and the carbon is lost as CO2.  Increased nitrogen fertilizer use may result in greater run-off into the watershed, placing the aquatic ecosystem under increased stress and polluting drinking water supplies. 

Increased ammonia demand will stress the natural gas market to some extent and result in increased greenhouse gas emissions. 

In addition to ecological insult, there will be a shift of wealth associated with increased diversion of corn to fuels.  If corn yields and acreage cannot be increased to make up for increased fuels demand on corn supplies, the food product chain could be subject to greater scarcity with an increase cost to consumers for everything associated with corn- corn oil, high fructose corn syrup, starch, beer production (!!) with corn starch, cereal products, animal feeds and the associated price uptick that would cause for meat products. 

It is worth remembering that corn is one of the major inputs to our food manufacturing complex. It enters directly as whole corn or as separated corn germ and corn starch, and indirectly as food for hogs, cattle, and poultry.

Many of the choices we have in the supermarket are largely based on what you can do cheaply and on a continuous process basis with grain products.  Stress on this supply will be passed along to the consumer.

One fresh approach is from a start-up company called Zeachem who aims to produce cellulosic ethanol from biomass other than just the corn kernel.  In this process, all fermentable sugars as well as cellulosic hydrolyzates can be converted to acetic acid by fermentation and the lignin sidestream can be processed to yield hydrogen.  Esterification with process ethanol to afford ethyl acetate followed by hydrogenation yields EtOH.  This process is currently in scaleup and may prove to be a major improvement in the otherwise anemic economics of EtOH. 

Adventures with Chemical Customer Service

For novelty I like to do raw material sourcing from time to time.  Trying to find exotic materials, equipment, or services is a sort of treasure hunt.  Like everyone else, I enjoy the thrill of the hunt and the satisfaction of finding a good buy.  What is striking is the great variation in helpfulness among customer service people.  Just today I encountered a customer service rep who was most helpful (Company W), and one who was, how shall I say, a miserable and unhelpful little snit (Company A). 

I’ll do a compare and contrast.  The helpful rep from Company W listened to my recitation of requirements and offered the best fit from their extensive collection of products.  We discussed the parameters and came to a conclusion. The rep offered to send a free test sample of product which will arrive by mail in a few days.  I’ll do a benchtop test and we’ll see if it works.

The insufferable snit from Company A listened to my requirements and, because I didn’t have a specific particle size to offer, just a SWAG (Scientific Wild-Assed Guess), was unable to make any kind of suggestion at all.  Because I did not input exact information so this person could go to an specific location in the table, the entire collection of products from Company A were made unavailable to me. 

I was shopping for filter media.  I’m interested in coarse, medium, or fine.  Because Company A offered 20 products specified to the nearest 0.1 micron, and because I could not offer an exact match, the Company A snit rep was unwilling (unable, perhaps) to help me make some educated guesses as to which product was most satisfactory.  What really irritated me was that there was not a smidgeon of help.  Just silence interrupted with staccato bursts of “I can’t help you if I don’t know the particle size…” from the other end.  Sigh.

You know, I have been filtering things since the early Disco Epoch, and until just today I did not know that ignorance of particle size was a show stopper.  

Thus begins the take-home lesson. I’ve spent many hours doing customer service, so here are some observations.  Very often a potential customer does not know what they really need.  Remember, there are wants and there are needs. They’ll call with some vague notion of what they want, but it might be very superficial.  They’ll pose and swagger like they know what they want, but chances are that they are fishing for clues from you, the customer service rep.

A good customer service rep has to know a great deal about the products and their typical use. A good rep will ask probing questions that drill into the customers knowledge and begin to find patterns and show stoppers. the good rep helps the customer sort between wants and needs. 

A customer service rep is also a sales person, whether that is openly acknowledged or not. The rep should try to find the best fit for the customer from the company selection of products. But now and then, the company may not be able to offer exactly what the customer needs and should just say so at that point.  The customer will leave with a good impression of the company and may return one day with a spec that matches your products. 

The rep from Company A did a disservice to his/her company by prematurely cutting off the shopping phase of my query.  It boils down to simple ignorance and the lack of basic curiosity.  There was no offer to ask someone else nor was there an offer of a reasonable substitute. They will miss out on a sale and will never know that their loss was self imposed.

Manson Impact Structure

Visited the town of Manson, Iowa, today.  This is a farm community nestled in the flat, corn-carpeted central Iowa countryside. Manson is situated over an extraordinary geological formation that is completely invisible from the surface.  Also called the “Manson Anomaly”, this location is the site of a meteor impact ca 74 million years ago. The Manson site was originally thought to be the source of the K-T boundary, but now it is recognized to have been formed ca 9 million years prior to the K-T event. Approximately 130 distinct impact craters have been identified.

The formation contains many of the classic features attributed to an impact crater and it has been studied at length.  Fortunately, the library in Manson has a collection of literature on the formation as well as a collection of core samples from about 10 bore locations. 

The impactor is thought to be a stoney meteor approximately 2 km in diameter.  According to the Iowa Geologic Survey, the crater structure is 37 km in diameter and sits under 20 to 70 m of glacial till.  It is believed that the terrain was covered by seawater at the time of impact and that the crater was filled with water fairly soon after the impact. 

What is interesting for this writer is that the Manson Crater is directly under the place I lived as a child.  Who knew that under the plain, flat, farmland were the remains of a large-scale calamity.  Things are never as they seem.  That’s what I really dig about science.

Rootin’ Tootin’ Putin

We’re approaching full circle from cold war to Perestrioka and collapse of the Soviet Union to re-ignition of cold war fires.  News sources are reporting bluster of the most serious kind issuing from Vlad Putin in response to plans by the US to place ballistic missile interceptors in eastern Europe. 

What motivates the Bush II administration to place anti-ballistic missiles and radar near the eastern frontier of Russia is a perceived ballistic missile threat from so-called rogue states.  The reality of ballistic flight is that missiles launched from the region of Iran will fly over southwestern states of the former Soviet Union (FSU).  In order to best detect and intercept such missiles heading for the EU, equipment would optimally be set up along the trajectory.  Within the logic of strategic planning, the site placement seems consistent with the goal. 

What is less than clear is the excuse for our ham fisted diplomacy with Russia.  Yes, obviously Putin is escalating the bluster and the tensions in a manner that is less than rational. But the decision makers in the Bush administration appear to have been asleep during the cold war.  Evidently the Bush administration didn’t consult with Russia in the run-up to missile site selection.  It was felt that as members of the EU, Poland and the Czech Republic were no longer part of the eastern bloc and therefore Russia’s input was irrelevent.  This was a whopper of a blunder.

The predictable result is that Russia is behaving like Russia, and, outwardly at least, the Bush people seemed slow to pick up on this.  Finally, Bush Jr. is getting some on-the-job-training in eastern bloc politics.

The confrontation with Putin and Russia has begun to spin into something that will force Russia to vigorously protect and promote its interests.  Putin is a lame duck and has to make some kind of stand to satisfy the quiet power brokers behind him.  They can’t accept the placement of ABM systems in Poland anymore than we could allow it in Cuba or Alberta. Doesn’t matter if the initial placement consists of “smart rocks”.  Any missile site can be quietly modified quickly.

There has been a disturbing lack of cultural and economic engagement between the United States and the FSU following the dissolution of the CCCP and the communist party.  This is unfortunate.  Western states should have made a more concerted effort to engage the FSU economically and socially.   

For its part, the US has been curiously lacking in interaction with or even simple curiosity in regard to the progress of the FSU states in their difficult period of reconstruction.  But I think that Russia has been characteristically distrustful of western intentions as well.  Historians will ponder this transition period in world political history and wonder how it could be that even though a society got to push the reset button, the best it could come up with was Putin and the best that the other states could muster was benign neglect.

Gaussling Off-line for a spell

Th’ Gaussling will be spending a few days in a midwestern flyover state bounded in longitude by two rivers beginning with the letter M and in latitude by two states beginning with the letter M. This state’s name derives from the Ioway Indian word for “corn-fed” and produced a president named after a dam.   

J.Org. Chem. Git ‘er done!

Citations taken from JOC, 2007, 72, 3981-3987, by Bruce Ganem and Roland R. Franke.

Where observation is concerned, chance favors only the prepared mind.  -Louis Pasteur

Necessity is the mother of invention.  -Anonymous Latin saying

Git ‘er done!  -Southern country male expression (recently popularized by Larry, the Cable Guy)

That’s hilarious!  I’m not sure, but this may be the first reference to a Comedy Central character in an ACS publication.  Well, I’m fairly sure.

Beilstein vs SciFinder? Vote Here!!

OK, it’s time to poll the thundering masses. If you had to make a choice between subscribing to Beilstein or SciFinder for general access to the chemical literature, which would you take?? Let’s say that you needed to find compounds, articles, procedures, or see what the IP picture looked like.  Forget TSCA registry and nomenclature services for purposes of this query.

Obviously, each has strengths.  But if you had to take a side, what service would you take and why??  

Chemical Batch Process Scale-up

A few of us took the course offered by Scientific Update called Secrets of Batch Process Scale-up.  It is a 2 1/2 day whirlwind of slides and class exercises.  In my estimation it is a very worthwhile course for process chemists and I certainly got a lot out of it. It is taught by Francis X. McConville who is a gifted teacher as well as experienced process guy.  He is the author of “The Pilot Plant Real Book“. Th’ Gaussling is pleased to toot this horn because this class is a great example of how such things should be done.

Most chemists know that the changes that occur in scale-up come in large part from differences in heat transfer and mixing.  There are certainly other contributions, but these are the big issues. The parameter that is viewed as most useful in mixing is the mixing energy parameter, Ei, which has units of watts/kg soln. Many of the parameters are subject to large exponents, so one needs to be cautious about how well your intuition works in this non-linear space.  The point is, eyeballing the mixing speed in your benchtop apparatus is almost certainly inadequate in comparing conditions in scaleup.

Ei=(Np*N^3*d^5)/V, where Np = impeller power number (contains density and power units), N = rotational speed (1/sec), d = impeller diameter (m), and V = volume (cubic meters).  Because the mixing energy varies as the 5th power of the impeller diameter and the cube of the rotation speed, small changes in agitator speed or impeller diameter can result in large changes in power demands on the agitator motor.  Obviously,  one should be cautious in hand waving comparisons between your 1 liter kettle and that baffled 500 gallon pot in the plant. 

The latest hiss from Jupiter

The 20.1 MHz radio receiver kit we ordered from Radio Jove arrived last week.  Lots of tiny components to solder onto the PC board.  I seem to have forgotten the color code for resistors. 

The kit comes with conductors and fittings for a dual dipole antenna. I’ll have to go to Home Depot and buy parts for the support structure.  The antenna is going to take a bit of real estate to set up.  Given that Jupiter is low in the sky for a few years, it is desirable to contrive a means for narrowing the antenna beam to help with some noise rejection.  A properly configured dual dipole 15 or 20 ft off the ground helps a bit. 

A powerful station already broadcasts at 20 MHz (WWV), out of Ft. Collins, CO, so the receiver is offset at 20.1 MHz.  Jupiters cyclotron radio emissions are strongest between 18 and 24 MHz.  For locations distant from Ft. Collins, the broadcast at 20 MHz may be irrelevent. The ionosphere is mostly transparent to 20 MHz radiation on the night side of the earth, so transmissions from interfering sources in this band tend to propagate into space at night rather than reflect off the ionosphere and go beyond the horizon.

Th’ Gaussling has been busy studying the basics of antenna theory.  It’s quite interesting, really.  An antenna is basically a transducer, converting energy from one form into another.  The knowledge of antennae is something of a dark art.  I have had to scrounge to find resources that explain without too much forgotten calculus. 

Once you have antennae on your brain, you begin to notice them everywhere. All sorts of them. Yagi’s, dipoles, dishes, mast antennas, and folded dipoles jutting off of every imaginable high spot. I have one bolted to my house. 

The side benefit for yours truly is that it has forced me to have a hard rethink about electromagnetic radiation and the mechanism for its generation. We organikkers generally don’t spend a lot of time thinking about radiation emission and propagation. 

There could be some pedagogical advantages to introducing students to electromagnetic radiation in the radio spectrum rather than the visible range. The acceleration of charges in an antenna element and the subsequent perturbation in the charge field around the charged particle seems to be conceptually easier to reach than the usual abstractions showing the 3-D rendering of a sinusoidal wave in most textbooks. In fact, I have never seen a good representation of visible photon emission beyond arrow pushing on an energy diagram.   Who knows, maybe a student would learn something about electricity as well?

Hey. Check out the Quantum Slacks by Haggar.  The first of their Non-Newtonian line.