Category Archives: CounterCurrent

Gaussling’s (n+1)th Epistle to the Bohemians: Biden’s Student Loan Assistance

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Wow. There is a whole lot of pissin’ and moanin’ out there about Biden’s student loan payment program. A lot of it is bubbling to the surface like rotten egg gas in the mud pots of Facebook and Twitter. That wriggling libertarian tapeworm is deeply and firmly attached to the innards of a great many people.

I’m not going to waste precious heart beats trying to explain why a civilization should aid and encourage higher education. It should be obvious.

In an earlier chapter of American history, I graduated with a BA in chemistry owing $265 back in 1984. The whole time I had at least 2 jobs simultaneously and in two cities for part of that time. It is what I had to do to graduate without accumulating a lot of student loan debt. Later, in grad school, I received tuition remission and a stipend to study for a PhD. This is/was common for chemistry graduate students. The only cost for the ordeal was time, a divorce and my sanity.

Since that time tuition, student housing/rent, fees and other expenses have grown astronomically while wages and grants have not. State funding of colleges and universities has shifted from grants in favor of guaranteed student loans. The reprobates in congress have also passed laws that make escape from student loan payments through bankruptcy impossible.

As it has turned out, my generation of Baby Boomers has benefitted immensely from lower tuition in our time. Today, the picture for students is quite different. Student loan debts are drowning a great many people. We lived in a time that funded student aid with grants and scholarships that are either not available now or they didn’t grow with tuition increases. Today’s students are unable to save for house down payments or otherwise spend on other goods and services. It might even affect who you marry. Why marry into enormous long-term debt?

For many students, not signing the loan papers was equivalent to giving up on their dream of a better life. There are indeed plenty of jobs not requiring a college degree that can lead to a comfortable life. Starting your own business is not for everyone. We can’t all be a Bill Gates because ground fertile enough for a paradigm shift is fairly scarce.

Now, there is a chorus of indignant voices hissing that “I paid my debts- why shouldn’t you? Why should I pay for your debt?” I can’t argue with that except to say that canceling some fraction of student loan debt is reimbursement of what should have been tuition assistance in the first place. The situation shouldn’t have arisen to trigger people. The sum of $10,000 amounts to $2500 per year for 4 years. This is a reimbursement for a modest yearly tuition grant.

Simple PFAS Destruction Process Disclosed

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An article titled Low-temperature mineralization of perfluorocarboxylic acids, Dichtel and Houk, et al., Science, 18 August 2022, Vol 377, Issue 6608, pp. 839-845, DOI: 10.1126/science.abm8868, came out yesterday with a method for defluorination and chain scission of per- and polyfluoroalkyl substances (PFAS). Blessedly, the article is available without charge.

The article describes the mineralization of reactive perfluorocarboxylic anions with NaOH in water and dimethylsulfoxide, DMSO, at 80 to 120 C and ambient pressure.

Ok. If the prefixes “per” and “poly” are unknown to you, read below, otherwise skip ahead.

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First, some clarification of the name “PFAS” for you non-chemists out there. The “P” in PFAS stands for either prefix “poly” or “per”. Both prefixes appear in common use. The prefix “per” is used to abbreviate the name when some atom or fragment is attached at every possible alkyl (see below) carbon connection point in a molecule or specified fragment of the molecule. The much lengthier proper name would have a number of the position of each separate fluorine atom on the molecule. “Per” and “poly” saves everyone from having to trip over a great many tongue-twisting syllables.

Hydrocarbons consist of only hydrogen atoms on a carbon skeleton. Hydrocarbon carbon atoms can have 0 to 3 hydrogen atoms attached to each skeleton atom. The exception would be methane, CH4, which has 4 hydrogen atoms attached. “Alkyl” refers to a subclass of hydrocarbon fragments or molecules that are absent multiple bonds between atoms of a carbon skeleton. A molecule with a carbon skeleton having no multiple bonds between carbon atoms and linked to hydrogen atoms only is called an “alkane”. An alkane fragment that is connected to something else is called an “alkyl” group.

Gasp! So, a perfluoroalkyl molecule or fragment would have 2 or more of its hydrogen atoms replaced with 2 or more fluorine atoms on a given carbon atom (see definition below).

From Wikipedia “According to the Organisation for Economic Co-operation and Development (OECD): “PFASs are defined as fluorinated substances that contain at least one fully fluorinated methyl or methylene carbon atom (without any H/Cl/Br/I atom attached to it), i.e. with a few noted exceptions, any chemical with at least a perfluorinated methyl group (–CF3) or a perfluorinated methylene group (–CF2–) is a PFAS.“

The prefix “poly” is much simpler. It is meant to indicate that the word it is attached to has many units of something, as in polyfluoroalkyl, which means many fluorine atoms attached to alkyl carbon atoms. Or it could refer to a string of repeating units as in a polymer.

Outside of the narrow PFAS world, the prefix per in “perfluoroalkyl” would indicate in common usage that the alkyl fragment is completely saturated with fluorine atoms.

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If we were at the bar during happy hour slamming well drinks after a long day of shaking separatory funnels, washing glassware and trying to vacuum distill something useful out of tar, someone might have groused that the PFAS destruction process is simply a process where you heat the piss out of a DMSO/water mixture of NaOH and PFAS to destruction. Ok, the word they used is “mineralization” rather than the more chaotic sounding words “destruction” or “digestion”. Everyone has thermally decomposed a reaction mixture in the past. We would pause for a moment, shrug our shoulders and say “well, of course that works”. DMSO is a highly polar, high-boiling solvent which supports the formation of ionic decomposition products at elevated temperature. Kendall Houk even did some snazzy DFT calculations on decomposition mechanisms. Now, that is how to develop a new approach to decomposition! Get out the big stick of quantum mechanical computing power and swing it around! The rascals Dichtel and Houk worked it out first so we’d raise our glasses and drink in their honor. Here’s to you, boys and girls!

As we stagger out to the Uber for the ride home, somebody mutters “I wonder how far along the patent application is and who will be the assignee?”

Whoa there Texas, simmer down big fella

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So, it turns out that I did time in Texas- 22 months to be exact. As a postdoc in a large central Texas city with the initials S.A. The natives were friendly, if not a little obsessed with the daily level of the Edwards Aquafer. If you absolutely have to live in Texas, SA is a decent choice. I do have to fault them on their choice of US Rep. Louie Gomert. An actual gibbering dunce if there ever was one. Imagine what kind of people were passed over in making that choice? But I digress.

On to the point. The Texas State Board of Educators recently made the news regarding their decision NOT to replace the word “slavery” with “involuntary relocation”. Evidently this antiseptic language was floated by a curriculum study group. The board, to their credit, unanimously directed the work group to revisit the language. Astute choice, folks.

According to the article in the San Antonio Current, GOP lawmakers (are there any other kind in Tejas?) are trying to shield students from discomfort in the classroom as with the mercurial issue of Critical Race Theory. Previously, in 2015, headlines were made when it was discovered that enslaved Africans brought to the US by the slave trade were described as “workers” in a social studies textbook. Sanitizing language on slavery is the first step to eliminating its tragic history altogether.

Replacement Theory on Ice

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I’ve been marveling at the current social phenomenon of “Replacement Theory” and all of the fear and loathing these words can generate. Anything that could plausibly rile up white folks is being scooped up and slung at the wall to see what sticks. The Republican fear machine needs and thrives on this kind of stuff. Fox News “Speaker to Animals” Tucker Carlson has been slopping it around the swill bucket lately as is customary for him to do. It’s become a meme with news coverage like a new Disney on Ice show.

Peering out from under my rock along the riverbank, it appears to me that there are a great many citizens in the U.S. of A. who enjoy nothing more than to get lathered up and vent their rage at the bogyman of the month. Some folks seem happiest and most alive when they are really hacked off.

I wonder how these folks will react when someone reminds them that social replacement is not new. After all, what happened in the forced removal of the Native Americans over the last 400 years? How many countries have we attempted to reconfigure to something more politically subservient by force or subterfuge? History is one long, highly blemished series of one people replacing another. Notice the irony? Historically, most change has been quite violent. Many nations have been complicit in the forced swapping of ethnic groups in the social and economic order in someone else’s land. It seems to be a natural turn of events.

If it is happening to the US right now, it seems to be relatively peaceful and quiet, except for the angry white nationalists out shooting people. More than a little change going on is merit-based selection in job placement and by the hard work of immigrants. If you are angry about being replaced by non-whites, first try not to murder people. Murder is the answer to a whole slew of poorly formed questions.

The Idiot and Poststructuralism

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ANNOUNCEMENT

Colloquium at The Center for Contemporary Idiocy, Rand Paul Auditorium

Poltroon University, Guapo AZ

The Center for Contemporary Idiocy is pleased to announce a lecture and panel discussion on “The Demise of Roe v Wade: Will Anti-Abortion Single Issue Voters Continue to Vote Republican?”

The Idjota Award for Graduate Studies in Western Idiocracy will be given after the speaker.

Guest Speaker: Dr. Horst Statek van Klingenn, Distinguished Fellow, The Institute for Poststructuralism and Malign Idiocy, Pan Handle College, OK.

6:30 PM Refreshments

7:00 PM Speaker

8:06 PM Panel Discussion

From PC to Woke-ness

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Linked here is an earlier essay on the evolution of political correctness (PC) as I have witnessed it. Before the epithet of “woke-ness” came along there was PC. In the early 2000’s rancid and cynical criticism of PC was trotted out and displayed as some kind of analysis by ultraconservative broadcasters and Christian evangelicals. PC as an epithet was useful for casting fuzzy accusations and to infer a kind of pathetic naivety to the mindset of progressive people. The accusation was difficult to counter and it gained wide spread use.

To counter the accusation of PC as a negative, one had to convince the accuser that fair treatment for all was a good thing and that the use of racial and ethnic slurs was a bad thing, not an unconstitutional imposition on free speech or an implied slur on white people. Defending PC in practice meant holding the accuser’s attention long enough to step through the morals and logic of PC- a tough exercise in listening for some people. It is another example of how it is easier to destroy than to build.

Zoning and Hard Times, Again

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I’m recirculating a few posts from long ago because I think they raise interesting points. This link relates to a problem with local zoning ordinances. The issue came to me after a trip to Bangkok, Thailand, some years ago where I got hopelessly lost on foot. I hope that reposting certain essays isn’t too tedious to the gentle reader.

Toxic News. Lamentations of a Liberal.

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Warning. I’m hammering on Trump. If this bothers you, please move along.

I really have to back off on the consumption of news. My attitude has become far more misanthropic than usual. Between the savage war in Ukraine, Trump’s traitorous boy crush on Putin and bills signed by that demon-seed governor of Florida, my head is throbbing from the noise of all the dissonant waves coming in. Surely, something is going right in the world, isn’t it? Maybe?

Part of what is stressful is the inability to intervene personally, to make a positive difference. Oh, to have 2 minutes to yell at #45. Or to remind DeSantis and the Florida legislature that their elementary schools have never taught sex education and have never given kids instruction on how to choose alternative genders or lifestyles. It would be disastrous for any teacher’s career and they know it. This LGBTQ instruction “issue” in K thru 3rd grade is entirely invented to agitate the excitable and poorly informed on a certain side of the bell curve. This is social conservative engineering boldly executed in plain view and vastly amplified by instant distribution on social media. DeSantis is maneuvering to be an alternative to Trump in 2024, which is a choice between bad and awful.

Trump is morally bankrupt. This should be obvious to any high school graduate who paid attention is school. He is a real estate developer who banks on his special gift of persuasion. His speaking style is well suited to that of an after dinner speaker. He teases his audience by saying naughty things and mugs and poses behind a false modesty, all of this while he is not making outrageous claims about his abilities. And many people eat it up. It is a very effective rhetorical style polished by years of practice. His time on reality TV has helped hone an air of authority and expertise in organizational management.

He learned that if you are going to exaggerate, make it big and repeat as often as possible. Throw great gobs of it and see what sticks to the wall. This is propaganda 101: Political persuasion through any means available.

As corrosive to American democracy as Trump is, there is a bigger problem. That would be the matter of his large crowd of eager voters. They seem to be of a disposition that instinctively distrusts government and lays a large part of the blame of alleged government malfeasance on liberalism. Since the days of Reagan, the word “liberal” has come to be an epithet through repeated encouragement by Republicans. Blame for societies ills on liberalism was further exaggerated by Newt Gingrich in the 1990’s. Unfortunately, this guy has reappeared and is frequently interviewed in conservative (Fox) news today.

I can remember stopping by a booth at the Boulder County fair in the mid 70’s which was occupied by the John Birch Society. They are ultraconservative, staunchly antigovernment and libertarian in orientation. I see many similar traits in the earlier Tea Party and in the current MAGA crowd. Unfortunately, once someone embraces this kind of mind-set, they rarely come back towards the middle in my experience. Distrust, fear and paranoia are things the human brain does very well.

Never in the history of humanity have so many people had a platform for the instant broadcast and receipt of political information. It is a challenge to the stability of a democratic nation when fringe ideas spread and are adopted across the population in a matter of days. Not everyone remembers history or has a grasp of basic political and economic concepts. In prior times, there were limits to the accessibility, reach and variety of news and opinion. There was also editorial control over what got published. Fringe letters to the editor or op-eds were published once and that was it. The reach was often limited to where the paperboy went.

With most of social media in much of the world there is no editorial control. Any brilliant or stupid post gets broad circulation with equal ease. The volume knob has been turned up for individuals who wish to practice the art of persuasion. Unfortunately for the Chinese and Russian people, their governments are clamping down on the content of both received and sent information.

Back to toxic news. Broadcast companies are businesses. Broadcast news has a job to do. It is to deliver as many eyeballs to ad messages as possible. It’s the same with social media. What gets aired is that which is compelling to the eyes and heart. And “compelling” draws eyeballs. To expect to get an education or a balanced view from commercial TV is a fools errand. Some people believe that “balanced” means that all views are equal. Well, some views are based upon a false premise and are unworthy of consideration. Also, the old saying “if it bleeds, it leads” still applies no matter what pious talk you may hear about journalism.

Civilization and CRT

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With the birth of every child, civilization must start anew. Parents and other adults are the major actors in rebuilding civilization and their first duties are to teach the child how care and fend for themselves in an often hostile world. Wariness is critical to surviving potential threats out in the open or those that lurk in the shadows. Adults must encourage wariness but not to the point of freezing solid in fear. Nuance is required in order to balance the threat/benefit relationship with the main goal of living as long as possible. In more precise terms, children must be educated and given examples of how to use that gained knowledge to not only live longer, but better as well. Seems obvious.

Today we see a movement in US civilization towards the disassembly of K-12 public education in favor of throwing those resources to conservative private and parochial education. Here in Colorado there is a silent group with out-of-state funding methodically getting far right, like-minded school board members elected. And it’s working. These groups wrap themselves in the flag playing Yankee Doodle, while often carrying a cross, and blow popular rightwing dog whistles as loud and often as they can. Currently, Critical Race Theory (CRT) is the most popular generator of dread fear among a great many in the population.

The fear that the CRT “threat” seems to be aimed at is the American liberal arts education taught in the public schools and in universities. First, some clarity. A liberal arts education is not about indoctrinating kids to be a democrat. The word “liberal” has come to be an epithet in common usage by many. A liberal education is actually meant to learn about a variety of topics and ways of thinking- to be less dogmatic and narrow. It encourages open minds. It tries to be neutral on the religiosity scale as well. And it has been quite successful for generations. Look around and you’ll see an endless assortment of objects and systems whose invention was by people educated under the liberal arts education.

Definition from Wikipedia: “Usually global and pluralistic in scope, it can include a general education curriculum which provides broad exposure to multiple disciplines and learning strategies in addition to in-depth study in at least one academic area.”

It seems that encouraging open mindedness or broad knowledge is exactly what they don’t want. What they want is actually indoctrination into “their” knowledge and thinking using their narrow definitions. It is about a narrow form of mind control, not objective facts and analysis. There is a fear that an accurate study of actual US and world history or science leads kids astray, away from God and country, to a world of anti-Americanism and to eventual eternal damnation. But, an accurate accounting of US history must eventually come to grips with the moral issues of slavery and the origins of the Civil War or the long, unfinished story of racism. To paint it over with heroic tales of settlers on the Oregon Trail while ignoring details of the slaughter and confinement of Native American to the reservation is an affront to reality and in all likelihood will eventually be made known to students anyway. Hiding the truth is a fools errand.

In my estimation, the American liberal arts education in the public schools, while flawed, has been a success. It has helped to provide a vast store of knowledge and skill that has lead to inventions and systems that have extended and improved our lives. Yes, the story is not perfect, but it is not over yet. To place the education of our young in the hands of politically partisan actors peddling extreme conservative views and possibly into corporate control is to steer our civilization into a less democratic, darker future.

See the comments section for more elaboration on this topic.

Donny and Vlad

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Yet another mournful lamentation on Putin and Trump.

Yesterday, 2/22/22, Trump had words of praise for Putin’s move into Ukraine with “peace keeping” forces. He used the word “savvy” in his praise of the tactic. This is in addition to his spoken admiration of Putin in past years. But he also said that if he were in office this wouldn’t have happened. Trump’s acolyte, Tucker Carlson, seems to be issuing forth the same kind of spew. So, what is Trump really saying?

During Trump’s term he proved to be cool on NATO and America’s place in it. So much so that he spooked EU countries. By most accounts, he had little if any recognizable foreign policy and left a great many important posts unfilled in the State Department. Foreign affairs just didn’t capture his interest. Yet, he says he could have prevented Putin’s invasion if he hadn’t been cheated out of the presidency. I guess the invasion is maybe the fault of Biden supporters.

I have come think of Trump as a wannabe despot who admires Putin the despot (and others) as one professional may admire the work of another. Putin as leader is accustomed to having considerable control of Russia. Trump was in control of numerous private companies and thus not accountable to public shareholders. Both characters are used to the exercise of unquestioned power. Maybe it’s not surprising that there is mutual admiration.

Will Trump followers be disappointed by his open admiration of Putin? It seems doubtful. His supporters have an evangelical zeal for the man. A great many of his followers are conservative evangelical Christians who believe that Trump’s appearance on the scene meshes with their end-times theology. His appearance is related to the beginning of the apocalypse of prophesy. These supporters believe that the man is here due to supernatural forces that must play out and cannot be dissuaded.

If this is your belief, then it must be comforting for you. For the rest of us, it is an incoherent and destructive kind of nonsense. How can it be that the same religion that preaches love and gave us the Beatitudes would also give us a leader the likes of the ethically disabled Trump. Somehow the creator of the universe, the one who set the galaxies spinning and knows the movements of every flea in the tail feathers of every sparrow, gave us a malignant narcissist like Trump. It is not a question shrouded in religious mystery. It is what it appears to be- absurd. Ambitious and destructive characters like Putin and Trump have appeared regularly throughout history. And through the lens of history we can make some good guesses as to what they can do. Both are threats to democratic civilization in their own way and must be contained.

As to the original question, what did Trump mean by his comments, I don’t know. He makes things up as he goes and lies profusely. I don’t think that even he knows what he means.