Category Archives: Science

Cresson Gold Mine, Part 1.

Early saturday morning 50 intrepid geotouristas packed into vans and drove to the CC&V mine in the Cripple Creek district of Colorado. Most of the group were professional geologists- professors, teachers, and geological survey folks. There were only a few interlopers like myself who were interested but untrained in geology. Not surprisingly, a background in chemistry is nearly useless when the discussion turns to stratigraphy and rock morphology.

The Cripple Creek gold district consists of an extinct volcanic structure called a diatreme. A diatreme is characterized by the presence of a volcanic pipe structure filled with brecciated rock. It is thought that the combination of shallow hot rock and ground water lead to violent explosions that resulted in fractured rock. Cripple Creek breccia has rounded clasts, indicating the rock fragments were exposed to rough, erosive treatment leading to attrition and rounding of the clasts prior to consolidation of the breccia.

In the past, gold mining at Cripple Creek was a underground activity. The district contains an extensive network of remnant subsurface works of drifts and shafts. Today, CC&V’s mining activity is limited to high throughput open pit excavation supplying pulverized rock to a cyanide heap leach field. A constant flow of ca 100 ppm aqueous sodium cyanide solution is leached from the top down through as much as 800 vertical ft of gold bearing rubble.

Abandoned Drift and Blue Bird Dike

Abandoned Drift and Blue Bird Dike

Columnar formations can be seen in certain locations of the mine (See photo: some features are enhanced with lines to show the margins). As the pit expands, drifts and shafts are exposed as seen in the photo above. The Blue Bird dike is an igneous intrusion into the surrounding formation. It is no coincidence that the drift in the photo is near the dike. It is common to see disturbed zones along the intrusion where gold can be found in higher abundance. The goal of the drift miner was to follow the enriched rock for more efficient reclamation of value.
Exposed Drifts During Pit Operations

Exposed Drifts During Pit Operations

A feature seen in the pit is a Lamprophyre, or igneous dike comprised of ultramafic, silica-poor, magnesium-rich rock. Biotite phenocrysts can be seen in samples. This is regarded as an unusual feature.

Lamprophyre formation in Cresson Mine

Lamprophyre formation in Cresson Mine

 The big haul trucks carry 300 tons of rock from the mine to the crusher. The crusher is actually a series of crushers that reduce the ore to pieces roughly 3/4 inch in diameter.

Haul Truck Carrying Rock from Blasting Site to Crusher

Haul truck carrying rock from blasting site to crusher The crushed rock is blended with lime and then driven to the leach pile for extraction. Another load for the leach heap.

 

A Massive Au/AuTe Deposit

Th’ Gaussling attended a geology seminar thursday evening at the Colorado School of Mines. It was given by the chief geologist at the Cripple Creek & Victor gold mine (now AngloGold Ashanti) and was concerned with 3-D modeling of the volcanic formation that forms the center of the deposit.

What is unusual about the CC&V mine is the extent to which tellurium is present. There are a dozen or more tellurium minerals and many of them are present in the ore body. The CC&V load was discovered relatively late- about 1891. Due to the extensive fraction of AuTe and AuAgTe minerals, the presence of the ore body was not detected by placer prospecting. 

Prospectors panning for gold in local streams had no way of knowing that extensive gold was present because AuTe(Ag) minerals do not have a gold-like appearance.  Legend has it that it was discovered by a drunken cowboy who noticed some native gold in an outcropping in the area and took a sample down for assay. As I have mentioned before, the Cripple Creek district has produced about half of all the g0ld to come out of Colorado.

What is key to the formation is the fact that it has zones of extensively altered volcanic rock disturbed both mechanically in the form of fractures and faulting, and chemically in the form of its potassic-alkali nature. The formation has strongly brecciated zones and is desribed as “vuggy”, meaning that there are extensive voids. Native gold and gold telluride mineralization can be found on the surfaces of the vugs. The mineralization was deposited by hydrothermal streams extracting Au and Te from unknown source rock.

Presently the operation is surface mining which feeds to a cyanide leach field for gold extraction. The surface pit mine is working downward, digging through the extensive network of mineshafts. In the early days at Cripple Creek the mining was limited to underground activity. Miners would follow the extensive subsurface network of gold-rich veins in whatever direction they might go. The result is a very complex and extensive matrix of tunnels and shafts that extend downward to as low as 3000 ft. In the early days, the economics of subsurface vein mining were attractive enough to sustain the operation. Today, the economy of scale dominates and pit mining with heap leaching of the lower grade ore is what sustains the operation.

The gold is recovered by a cyanide leach field that is 800 ft thick in places. This method produces ca 300,000 toz/yr. The process does not recover Au from AuTe. It is left untouched in the leach heap and constitutes ca 1/3 of the total gold present.

Curiously, during the many eruption cycles in the distant past (~32 ma), debris from the surface has washed back deep into the formation. Bits of woody debris have been recovered within cementitious rock hundreds of feet below the surface. The CC&V geologist showed a core sample with a wood fragment imbedded within it. For a time reference, the current episode of Rocky Mountains (the Laramide Orogeny) began ~65 ma.

Chemist Gaussling will blend in with a group of geologists tomorrow morning and take an extensive geology tour of the mine site. Hopefully, there will be pictures to share. We’ll be going up to ~10,000 ft, so it will be chilly.

LC Dreamin’

When I get to work this morning I’ll be greeted with a brand spankin’ new Agilent 1200 HPLC sitting on the bench in my lab. It has a diode array detector (no flippin’ MS this time). Pretty sweet.  Gosh, early 1990’s LC capability- already!

It is interesting how the installer assumed I’d be doing reverse phase work. Must be what most of the weenies in pharma are using. Carbon-heteroatom-carbon-heteroatom-carbon-heteroatom-carbon=heteroatom-carbon-heteroatom- … maleate.

A hot little number

hot-load-on-the-interstate1

I see these shipping casks on the highway at least once a month.  This time I had a Canon with me (Powershot A470, you know, a camera). While sitting at the off-ramp stop light next to this container I began to wonder how much activity shines through the shielding. I began to daydream … if I could see in the gamma spectrum, would this thing be bright or dim?

Then, in the blink of an eye the spell was broken. The light turned green and I parted company with this hot little number.

Green Propellants

Notes from the Field-

There appears to be a movement in the gun and rocket propellant field away from perchlorates.  Propellants that are comprised of substances that pose minimal potential for the dispersal of adverse and environmentally persistant substances are referred to as “green propellants”.  Substances that qualify as adverse include arylamines, perchlorates, and certain rheology modifiers. Substances that are thought to be endocrine disrupters have been specially targeted for replacement.

While it may seem absurd to attempt to produce a weapon system having a reduced toxic signature, the  fact is that between practice projectiles and warshots, a good deal of hazardous residues are released in the use of these devices. Reducing the chemical environmental insult is a step in the direction of reduced collateral damage.

One expert in the area of perchlorates said that people with adequate iodine intake shouldn’t worry about perchlorate contamination of water. Hmmm. While that may be true, it sounds like a poor basis for policy.

Mea Culpa

Today I found myself attending a talk on mortar propellants. It was delivered by a shy young woman who looked to be no older than a high school senior- she looked like a babysitter you’d hire to stay at home with the kid while you treated the wife unit to a night out on the town. Yet she was an expert in mortar shell propellants.

Next, I attended a talk on flare compositions delivered by a tiny woman who could barely see above the podium.

I rounded the day off by attending a talk by a woman who presented her results on igniter design and in developing a new explosive propellant manufacturing process. During the Q&A, my questions on ignition mechanisms were answered by yet another woman who was exceedingly knowlegeable in this field.

What I have noticed is that the gun and rocket propellant R&D field is populated with women to a much greater degree than the industrial organic or organometallic chemistry waters in which I normally swim.

Before you fire a rude comment alleging some sexist malfeasance, please understand that I was raised by a single mother as the eldest of 5 kids. That, and having witnessed the birth of my child, I have no doubt whatsoever about the robustness and Ability of women.

That women do this isn’t news. What is noteworthy is the extent to which my ignorance remains so great at age 51. My caveman misconception was that explosives chemistry would not appeal to women. I had mistakenly and foolishly assumed that a career with explosives was largely a male domain and driven by male fascination with power. Holy cats. I was quite mistaken.

I seem to be wrong about  a lot of things these days.

A Nevada Cinder Cone

Whilst doing a survey of Lithium mining in North America, I blundered into a small cinder cone. It is found in the Clayton Valley of western Nevada south and west of Tonopah.

A link from the University of Nevada, Reno, gives some details on this cone as well as some interesting photographs.

Just to the south of this cinder cone is the Chemetall Foote Corporation Silver Peak brine facility. Lithium rich brines are pumped into evaporation ponds for concentration of the lithium salts. US 7390466 says that the Silver Peak brines contain 0.02 wt % Li.  The richest Li brine can be found in the Salar de Atacama brines in Chile. The Atacama brines contain from 0.15 to 0.193 wt % Li.

Research and Playfulness

As a kid I noticed that many cats seemed to lose their playfulness as they matured. What were once playful kittens would mature into rather less playful adult animals with irritability issues. Many humans I know seem to have “matured” away from a general disposition to playfulness in a similar way. It is a shame. Playfulness is an important expression of brain vitality.

Play can be manifested in many ways. One form is where one teases out a response from a stimulus. It can be done for simple joy, as in the case of teasing your sister. Or it can be directed to somewhat more useful and enduring outcomes as in the case of research.

As I look back on my meager list of useful developments in the laboratory, I can see that most were the result of play. I was just curious as to a particular outcome. If I had simply paid more attention to my boss and focused on getting expected results (a production activity), it is unlikely that I would have fallen into some interesting and useful insights. No doubt almost every scientist can make the same claim.

On the other hand, if I had paid more attention to my boss, perhaps I’d be  a tenured prof at a decent university or a mid-career manager at Pfizer. Hmmm.

What happens to many people when they age is the same thing that happens to cats. They settle into comfortable patterns and try to exclude surprises from their lives. Just like it takes discipline to get regular exercise, it also takes some discipline to keep imagination and playfulness a central part of your consciousness.  Go out there and try something that has been on your mind all these many months! See if it works.

Redoubt Volcano Continues to Show Activity

The Redoubt volcano is making its presence known. It has played havoc with some petroleum infrastructure (Drift River Oil Terminal) and has begun to dump ash. Lahar activity has flooded a runway and generally made a mess. The photos below do not show the volcano in a major eruption. Most of the AVO/USGS close up shots seem to be taken when the mountain is quiet.

Mud & debris flows from Redoubt (Photo AVO/USGS)

Mud & debris flows from Redoubt (Photo AVO/USGS)

North Flank of Redoubt 1-31-09 (Photo AVO/USGS)

North Flank of Redoubt 1-31-09 (Photo AVO/USGS)

Redoubt Eruption Plume from MTSAT (photo National Weather Service)

Redoubt Eruption Plume from MTSAT (photo National Weather Service)

Redoubt Fumaroles 1-31-09 (Photo AVO/USGS)
Redoubt Fumaroles 1-31-09 (Photo AVO/USGS)

For detailed information on the Redoubt Volcano and it’s ashfalls and other activity, click to the Alaska Volcano Observatory (AVO).

The lab as a shop

Just sent multiple kgs of a rare earth reagent out the door. It may have been one of the larger scaleups of this stuff. I hope it does the job for the customer. Meeting certain specs turned out to be more difficult and time consuming that I had anticipated. But getting it certed and shipped is quite satisfying.

Lots of new projects in the shop for examination and custom synthesis. Some process safety tests, some analytical development, and some synthesis. It’s a good mix and quite diverse in chemical elements.