Fear and Loathing

One of my favorite writers is Hunter S. Thompson.  His trademark acid-trip style of writing always dazzles.  Here is a piece from the Nixon years, 1973-

 “What we are looking at on all our TV sets is a man who finally, after 24 years of frenzied effort, became the President of the United States with a personal salary of $200,000 a year and an unlimited expense account including a fleet of private helicopters, jetliners, armored cars, personal mansions and estates on both coasts and control over a budget beyond the wildest dream of King Midas . . . and all the dumb bastard can show us, after five years of total freedom to do anything he wants with all this power, is a shattered national economy, disastrous defeat in a war we could have ended four years ago on far better terms than he finally came around to, and a hand-picked personal staff put together through five years of screening, whose collective criminal record will blow the minds of high-school American History students for the next 100 years. “

  • Rolling Stone #144 (September 27, 1973)

Clearly, HST despised Nixon.  But in his last years he would have preferred Nixon to Bush II.

“This is going to be a very expensive war, and Victory is not guaranteed— for anyone, and certainly not for anyone as baffled as George W. Bush. All he knows is that his father started the war a long time ago, and that he, the goofy child-President, has been chosen by Fate and the global Oil industry to finish it Now. “

  • “When War Drums Roll” (September 17, 2001)

That was the political side of HST.  What I most appreciate are the outrageous  and surrealistic descriptions, seemingly jotted down while in a lysergic mania.  From Fear and Loathing in Las Vegas (1971)-

 “The sporting editors had also given me $300 in cash, most of which was already spent on extremely dangerous drugs. The trunk of the car looked like a mobile police narcotics lab. We had two bags of grass, seventy-five pellets of mescaline, five sheets of high-powered blotter acid, a salt shaker half full of cocaine, and a whole galaxy of multi-colored uppers, downers, screamers, laughers and also a quart of tequila, a quart of rum, a case of Budweiser, a pint of raw ether and two dozen amyls. All this had been rounded up the night before, in a frenzy of high-speed driving all over Los Angeles County — from Topanga to Watts, we picked up everything we could get our hands on. Not that we needed all that for the trip, but once you get locked into a serious drug-collection, the tendency is to push it as far as you can.
The only thing that really worried me was the ether. There is nothing in the world more helpless and irresponsible and depraved than a man in the depths of an ether binge. And I knew we’d get into that rotten stuff pretty soon.”

It is hard to tell if HST’s perceptions were shaped by the psychedelic experience or sharpened by it.  I suspect the latter. 

Wingnuts

Another far right-wing character bites the dust.  Seems that Colorado Springs preacher-man Ted Haggard, mullah of the New Life Church, commander of the “Spiritual NORAD”, weekly advisor to George Bush II, and PT Barnum of the New Testament, has been leading a double life.  Seems he has a private taste for what he publically condemns.  Holy revelations, Batman. 

This is a tragic comedy.  There is some smug satisfaction in seeing a prominent theocrat get tangled in a web of his own construction. A most humiliating experience it must be, to be caught indulging in the most forbidden pleasures of the flesh.  But the fall of Ted Haggard is only the tragic part. 

The comedy part relates to the mechanics of operating theocracy.  Theocracy is governance by revelation.  Self-appointed persons claiming to have received special instructions by, or have special sensitivity to, a supernatural being are the governors of a theocracy.  There are no checks and balances. There can be only unblinking obedience.  This event forces us to pause and think about the pragmatics of operating a theocratic state. How divine is the leaders inspiration? How can you discern the direction from God vs the directions from people? This mode of governance is fundamentally flawed because people are forced to interpret nuance and testamonials as opposed to objective, measurable, reality.

Ted Haggard is (was) a prominent leader of a nascent conservative theocratic movement in America.  See for yourself. Look it up.

Soon we’ll see the obligatory sobbing plea for forgiveness and the posturing.  In 5 years he’ll be back preaching from Arkansas or Indiana on the DayStar network. His fall from grace will be the basis of a book and a CD set.  Maybe this is part of the cycle that the Hindu’s talk about.

Pissin’ and a moanin’, part deux

So, I get an email from some cheerleading functionary from SOCMA, Synthetic Organic Chemical Manufacturers Association.  In it, the sending party gushes that they are endorsing a program to assist public school chemistry teachers in cleaning out their collection of “dangerous chemicals” from school stockrooms.  I promptly replied that I thought it was a terrible idea.  There has been no reply.

Well, I said a bit more than “I think it’s a terrible idea”. 

But how could a rational person conclude it’s a terrible idea? Here it is.  If I thought that the proposed clean-out orgy was limited to ancient bottles of peroxidized ether, great steaming heaps of calomel, or dried out picric acid leftovers, the I agree, let’s get rid of it.  But I know safety people.  Safety people do not like chemicals. They would prefer that we limit our chemical handling to baking soda and vinegar, and even at that, we need full protective garb.

Safety people will clear any stockroom of all of the interesting and useful chemicals from the shelves if given the chance.  Safety people will dress up in bunny suits with respirators and tape off the area in order to do this clean out. I can just see it.  The chemistry lab barracaded with red cones and yellow tape behind which the “hazardous material team” carefully packing jars of copper sulfate and ferric chloride into blue plastic drums filled with vermiculite. The school principal, a former kinesiology major with an administrators certificate, just stands there shaking his head at the prospect of what horrific things could have happened. Another school saved from certain tragedy.

As I’ve said before, reactive chemicals are useful chemicals. If we banish reactive chemicals from our stockrooms, we’re left with petrolatum and NaCl.  It is all part of a tragic dumbing down in the name of safety.  Just because safety staff feel insecure about chemicals, do the rest of us need to have our hands tied? Handling a chemical is like handling a knife. A knifes very utility is manifested in its sharpness. Yeah, you can get cut. But we recognize that the usefulness outweighs the risk.

We should all be skeptical of this trend to replace authentic experiences with virtual experiences.  All students should witness how tiny bits of sodium or potassium react with water. Limiting such real experiences to video experiences is wrong. Students should get to see and do the real thing.

Outbreak of good news

There has been a stunning outbreak of sensibility in the past few days. KFC has decided to move away from partially hydrogenated vegetable oils and the unhealthy stereochemistry situated therein.  This is a good thing.  I’ve always been partial to cis-fats anyway … Now we can picnic with a clear conscience. One day, funnel cakes and corn dogs will be safe to eat.

The second hopeful news item is the decision by NASA to do another mission to refurbish Hubble.  This is one of the worlds great observatories and the notion of letting it expire while we have the capability to service it was just absurd.  Observations from this telescope have changed our understanding of the cosmos.  Good choice, NASA!

The 80/20 Rule

Having done my tour of duty in chemical sales and having travelled over a good bit of the northern hemisphere buying & selling, I’ve picked up a few insights into the B2B and “retail” chemical business.   Everyone has the major chemical catalogs on their desk. You know, the thick tomes from Aldrich, Spectrum, TCI, Matrix, Strem, GFS, Gelest, Fisher, etc.  There is considerable overlap in content, though some specialize in their chosen niches. While Aldrich makes no bones about total world domination, others are pleased just to dominate certain cul de sacs of chemistry. 

SAF is clearly the colossus of international catalog companies.  The Aldrich wing was started by Alfred Bader, now a retired art collector. To hear him tell it, Bader was frustrated by the limited availability of reagent chemicals and spotty service (by Eastman Chemical, if I am not mistaken).   Anyway, Bader was the right character at the right time.  He had a single-minded drive to give chemists what they needed and make a few bucks doing so. The slogan “Chemists Helping Chemists” was a the result of a sincere calling.  Bader visited university chemistry departments and asked professors what they needed.  Over time the Aldrich catalog collection grew and so did the company. Eventually, Bader was quietly forced out of the organization.  Founders can become “problematic” evidently.

Today SAF offers a vast collection of products and makes a sizeable fraction of what they offer.  Most professors don’t know it, but interesting materials from the lab might be saleable to a catalog company. If a prof has developed a new reagent or some useful fragment or pharmacophore, for instance, it might be worth contacting a catalog company to see if they want to stock it. You never know until you ask.

But we business types know that dealing with professors can be sticky, so Herr Doktor Professor, don’t get too high handed or greedy!  Academics are often missing the merchant gene and as a result badly price their wares.  The typical mistake is to over-estimate the demand and hike the price up to the astronomical numbers that you see in the catalogs. 

Here are the problems. Catalog companies do not pay the prices that you see in the catalogs. Buying material for inventory is equivalent to putting a stack of money on the shelf.  They have to pay lots of money up front before the first purchase order for your wonder product is faxed in. They have to pay for those damned fat catalogs, the inventory, salaries, the facility, regulatory compliance, certification, labeling, packaging, the time value of money, taxes, and they have to make a profit for the shareholders. So if the catalog price of something is $10 per gram, figure that they’re likely to keep their costs to $2 to $3 per gram for it, tops.  Obviously, this is subject to variation due the type of material or special negotiated deals.  But a 3x to 5x markup is not uncommon and is necessary to stay in business.

Then, after you ship the product to the catalog house and they put it into the collection, it might not sell.  It could be a dog.  The rule of thumb is that 20 % of your inventory will do 80 % of the business.  So, one of the ways to grow is to increase the number of products. Their interest in your product may be of a statistical nature rather than a firm belief in it’s viability.

I’ve heard many people go off about high catalog prices. I don’t like to pay the high prices either. But it is the cost of convenience.  If you need some obscure material, chances are that you can order it and have it in a few days. That is worth something and the catalog companies know it.  Hell, I’d do the same thing.

UV/Vis Spectrum of Bromine in Water

We have a Cecil CE 2041 UV/Vis spectrometer.  Data is collected by the DataStream CE2000 software package. The instrument has 4 nm of resolution, not the best, but still quite usable. To quote the famous British philosopher- “You can’t always get what you want!” (M. Jagger).

This posting is an experiment on how to upload data to the web. The graphic below is a jpeg conversion of a pdf conversion of an Excel chart. Seems like an awkward way to do this. Undoubtedly someone out there can offer a suggestion of how to upload an Excel graphic to the blogosphere.

 uv-vis-of-br2-in-water-rev-2.jpg

It looks like prior to an upload the graphic has to be beefed up a bit.   I’m gonna have to monkey with it some more. Maybe someone has a suggestion.

Pissin’ and a moanin’

On occasion I am overcome with episodes of extreme clarity. It can happen anywhere- driving to work or standing in the 104 degree Fahrenheit shower water.  One such episode has recently come and gone. The realization was that for as much as I dearly love my chosen field of chemistry for the employment and multitude of Aha! moments it has given me, I am faced with the stark reality: Some of the most profound and pernicious a**h***s I have ever known have been fellow chemists. Shocking, isn’t it?

For the love of God, man, can it be true? Is this too dark of a subject to blog about? Can we talk about this? Maybe it is a dirty little professional secret that should be kept under wraps.  Maybe I am some sort of chaotic attractor that funnels these people into my local space?  Seems unlikely.  It’s probably just a proximity effect.  If I took up grocery bagging, the same realization would probably happen. 

How did people deal with a**h***s like this 40,000 years ago? If the troublesome Neanderthal who lived a few klicks up Olduvai Creek got out of control, we’d settle it the caveman way. With a club or that newfangled imported Folsom point. Today we are expected to use our words.  Well, here are some words- Damn and blast!

Some lab jerks are petulant turds who, if it weren’t for a wealthy grandmother, might be managing a Denny’s on the interstate. Others are true alpha males- tall, articulate, athletic, and sycophantic. These characters are especially loathesome.  It has been my experience that many sycophants have no immunity to the enchantments of other sycophants. Some cluster and form cells. Others collect clients or something like courtiers– grinning, pasty-faced trolls who lock onto the teat.  It is most distasteful.

(*End of Scorn Routine*)

Organic Qualitative Analysis. RIP.

One of the chemistry classes I took as an undergrad continues to assist me in my synthetic endeavors mid-career.  The class was organic qual.  It was designed to take the student through the determination of an unknown organic compound , or mixture, with the aid of qualitative tests and derivitization to figure out the compound. We did small visual tests to guage acidity, basicity, water solubility, etc. We did sodium fusions to look for halides, 2,4-DNP hydrazones for carbonyls, picrates of amines, and flame tests to make a guess at saturation. We were given just so many grams of unknown and we had to perform several tests to support a claim of identity. It was an excellent experience because an organic prof taught the actual lab section.  We had access to the lab during the week to work on the unknowns. 

We used derivitization to determine some of the more difficult unknowns. CRC Press had a book of physical properties of a large range of known compounds that were derivatized, so you’d compare mp’s, color, bp, solubility, etc., to make a case for identity.

I would be interested to hear if this is still in the curriculum out there. I fear that it has passed along into history in the face of the hyphenated cryptozoology of todays analytical instruments.  That’s a pity.  Organic qual gave me the chance to handle chemicals, perform reactions, deal with ambiguity,  and do tests that might be hard to work into the rest of the curriculum.   Part of being a good organic chemist is racking up lots of time in the lab doing stuff, polishing up the physical intuition and mechanical skills.

I am embarrassed to admit that at one time I embraced the idea that the organic microlab experience was good pedagogy.  I now see it as more of a phenomenon meant to stretch department budgets. The idea of giving students barely enough reagents to make 100 mg of something is pretty dubious.  If the student goofs and spills something or makes a mismeasure, they might end up with 25 mg of product. The isolation of this amount of mass is problematic for fresh learners.  I miss the days when the organic lab kit had 25, 50, 100, and 250 mL flasks in it (19/22 ST joints, of course). 

The argument goes something like this: Our conversion to microlab equipment is justified because of the cost saving gained by going to a lower scale. We buy fewer grams of expensive reagents and we lower waste generation for the department. Well, this is a bunch of self-serving crap. I can just see the department chair’s pointed head nodding in agreement as some tenured Poindexter drones on about minimizing the negative impact on the environment.  

For Christ’s sake, we’re talking about chemistry, not church camp.  Minimally, chem majors should not be cheated by limiting them to the microscale experiments.

If you want to save the environment, stop driving your SUV down to 7-11 to get cigarettes.  Or, don’t bring home so much cheap plastic crap from Big Box Mart.

Colleges should be giving their chemistry majors more synthesis experience, not less.  In industry it can be a real problem finding fresh BS/BA graduates that have lab experience beyond sophomore organic lab.  Schools that promote lab-based synthesis research for undergrads (as opposed to computation) are doing their students a bigger favor than they may realize. 

The Road to Reconstructionism

There is a web site that has been keeping track of a movement in America. It is a quiet movement. It’s purpose is to implement a reconstruction of American values to suit their world view.  The website is the Yurica Report.  It is a movement that seeks nothing less than the establishment of a theocratic form of government in America.  It is also called Theocratic Dominionism or Christian Reconstructionism.  But see for yourself.  Google these terms and browse the websites.

For myself, I have been watching Christian fundamentalism since the early 1970’s.  I recall stopping at a booth at the county fair as a high school student and listening to members of the John Birch Society. I thought at the time that they were Looney Toons, or just a Christian libertarian group.  I guessed that they were mostly harmless.   Well, I was wrong.

Frederick Clarkson at PublicEye.org writes-

“Reconstructionist leaders seem to have two consistent characteristics: a background in conservative Presbyterianism, and connections to the John Birch Society (JBS).”

He goes on to say-

“In 1973, R. J. Rushdoony compared the structure of the JBS to the “early church.” He wrote in Institutes: “The key to the John Birch Society’s effectiveness has been a plan of operation which has a strong resemblance to the early church; have meetings, local `lay’ leaders, area supervisors or `bishops.'”

The JBS connection does not stop there. Most leading Reconstructionists have either been JBS members or have close ties to the organization. Reconstructionist literature can be found in JBS-affiliated American Opinion bookstores. “

But what is reconstructionism about? Again, Clarkson puts it succinctly-

“Reconstructionism is a theology that arose out of conservative Presbyterianism (Reformed and Orthodox), which proposes that contemporary application of the laws of Old Testament Israel, or “Biblical Law,” is the basis for reconstructing society toward the Kingdom of God on earth. “

“Reconstructionism argues that the Bible is to be the governing text for all areas of life–such as government, education, law, and the arts, not merely “social” or “moral” issues like pornography, homosexuality, and abortion. Reconstructionists have formulated a “Biblical world view” and “Biblical principles” by which to examine contemporary matters. Reconstructionist theologian David Chilton succinctly describes this view: “The Christian goal for the world is the universal development of Biblical theocratic republics, in which every area of life is redeemed and placed under the Lordship of Jesus Christ and the rule of God’s law.”

I agree. It is easy to dismiss this as a bunch of paranoid ranting. But if you’re paying attention to things, you might also conclude that we have been in the midst of this movement for some time.  How do you think GW Bush got elected in Tejas? His boyish charm or war record?

I don’t want to give it all away. The reader should see for her/himself.  Let my friend, Mr. Google be your guide on this disturbing journey.

(*fade to black*)

GWII- Gulf War II

To say that there is a lot of antipathy for the Bush regime would be an understatement. I was vaguely aware of similar dissent during the 1960’s, but I was too young to understand it then.  I do recall family elders dismissing Viet Nam war protesters and “hippies” as communists.  In those days, the word “communist” was an epithet that was used with genuine scorn and derision.  Like the pixelated photo of Lincoln, with distance the image begins to form.  Vague similarities between the times are gradually being recognized. Today you hear Bush conservatives spitting the word “liberal”, often with the phrase “cut and run”.  The allusion, of course, is that liberals will spontaneously take “French Leave” when in power, abandoning the Iraqi people and thereby soiling the memories of soldiers who have fallen in Iraq.  So the theory goes.

There is some interesting content at VDARE.com concerning Gulf War II (GWII).  The author is Paul Craig Roberts.  He was Assistant Secretary of the Treasury in the Reagan Administration.  Mr. Roberts apparently had some sort of epiphany as a political insider and has come out against how the Bush cabal has prosecuted GWII.  Anyway, he makes some interesting points-

“To date more than 100,000 US troops who are veterans of these wars have been granted disability compensation. Although the US cannot put on the ground in Iraq more than 150,000 troops at one time, 1.5 million troops have served so far and 567,000 have been discharged of which 100,000 are receiving disability payments.

Paul Sullivan, director of programs for Veterans for America, says that the current rate of injuries will produce 400,000 American veterans suffering 30% to 100% disability. Apparently, one of the severe forms of disability is post-traumatic stress, which does not count as a physical wound.”

As a news junkie, I’m at least average in attentiveness to such things and I’ve heard precious little about US casualties. If the above is true, then it needs to be announced morfrom every hill top.

Or, consider this unsavory comparison-

Americans are too inattentive and distracted to be aware of the grave danger that the neoconservative Bush regime presents to American liberty and to world stability. The neoconservative drive to achieve hegemony over the American people and the entire world is similar to Hitler’s drive for hegemony. Hitler used racial superiority to justify Germany’s right to ride roughshod over other peoples and the right of the Nazi elite to rule over the German people. Neoconservatives use “American exceptionalism” and “the war on terror.” There is no practical difference. Hitler cared no more about the peoples he mowed down in his drive for supremacy than the neoconservatives care about 655,000 dead Iraqis, 100,000 disabled American soldiers and 2,747 dead ones.

When Bush, the Decider, claims unconstitutional powers and uses “signing statements” to negate US law whenever he feels the rule of law is in the way of his leadership, he is remarkably similar to Hitler, the Fuhrer, who told the Reichstag on February 20, 1938: “A man who feels it his duty at such an hour to assume the leadership of his people is not responsible to the laws of parliamentary usage or to a particular democratic conception, but solely to the mission placed upon him. And anyone who interferes with this mission is an enemy of the people.”

“You are with us or against us.”

Here, Roberts may be going a bit non-linear on us.  Read “Rise and Fall of the Third Reich” by William Shirer.  While Bush II is clearly not on the same philosophical or moral plane as Adolph Hitler, nor as cunning for that matter, the fact is that his handlers are using rhetorical tools from an age-old playbook.  That is, whipping up public fear as a means to concentrate power.  Really, the Bush cabal is mythologizing a foe to achieve an unprecedented concentration of power for the executive branch.  The point of the Hitler comparison is that this kind of consolidation of power has precedent. 

Finally, I’ll agree with those who say that Bush II isn’t smart enough to do this on his own. I’ve seen nothing to indicate that this fellow is much more than a frat boy with a golden name.  Bush and his merry men have managed to make a mess of things and it will take generations of other people to smooth it out.  Recall that we still have troops in Japan and Korea and the veterans of those wars are now passing of old age.